potassium perfluorooctanoate | 2395-00-8

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: potassium perfluorooctanoate
• 英文别名: potassium;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoate
• CAS: 2395-00-8
• 化学式: C₈F₁₅O₂*K
• 分子量: 452.161
• InChiKey: WPDDXKNWUVLZMQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.11
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  17

安全信息

• 海关编码：
  2915900090

反应信息

• 作为反应物：
  描述：

  potassium perfluorooctanoate 生成 全氟辛酸
  参考文献：
  名称：

  ARAMAKI, MINORU;SAKAGUCHI, HIROAKI;NAKAMURA, TAMIO

  摘要：

  DOI：
• 作为产物：
  描述：

  N,N-diethyl-3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-hexadecafluorodec-2-en-1-amine 在 potassium permanganate 作用下， 以 丙酮 为溶剂， 反应 2.0h， 生成 potassium perfluorooctanoate
  参考文献：
  名称：

  含フッ素カルボン酸または含フッ素カルボン酸塩の製造方法

  摘要：

  需要翻译的文本： PROBLEM TO BE SOLVED: To provide a method for producing fluorine-containing carboxylic acid or fluorine-containing carboxylate. SOLUTION: The fluorine-containing carboxylic acid [when M in formula (II) is H] or the fluorine-containing carboxylate [when M in formula (II) is a metal], represented by general formula (II) Rf-COOM [wherein Rf is a 1-20C fluoroalkyl; and M is H or the metal], is produced by reacting a fluorine-containing alkene of general formula (I) Rf-CF=CH-R [wherein Rf is the same as represented in formula (II); and R is a (substituted) alkyl] with an oxidizer. COPYRIGHT: (C)2006,JPO&NCIPI 翻译结果： 解决的问题：提供一种生产含氟羧酸或含氟羧酸盐的方法。 解决方案：通过将一般式（I）Rf-CF=CH-R（其中Rf与一般式（II）中所代表的相同；R为（取代）烷基）的含氟烯烃与氧化剂反应，制备一般式（II）Rf-COOM（其中Rf为1-20C氟烷基；M为H或金属）所代表的含氟羧酸（当公式（II）中的M为H）或含氟羧酸盐（当公式（II）中的M为金属）。 版权所有：（C）2006，JPO＆NCIPI

  公开号：

  JP2005350377A
• 作为试剂：
  描述：

  3,4-dihydronaphthalen-1-yl acetate 在 potassium perfluorooctanoate 、 fluorine 作用下， 以 二氯甲烷 为溶剂， 反应 0.03h， 以85%的产率得到2-氟-3,4-二氢-1(2H)-萘酮
  参考文献：
  名称：

  Stable long-chain fluoroxy compounds and their chemistry

  摘要：

  DOI：

  10.1021/jo00220a004

文献信息

• The effect of chemical structure on the tribological performance of perfluorosulfonate ILs as lubricants for Ti-6Al-4V tribopairs
  作者：Mingjin Fan、Yaying Jin、Yunyan Han、Lin Ma、Wenqian Li、Yu Lu、Feng Zhou、Weimin Liu

  DOI：10.1016/j.molliq.2020.114286

  日期：2021.1

  physicochemically adsorbed films and tribochemical reaction films were produced on Ti alloy tribopair surfaces during sliding when lubricated with the TPP ILs. The formation of physicochemically adsorbed films between the TPP ILs and the friction surfaces were mainly responsible for the superior tribological properties compared to the reference samples. By comparing the tribological properties of TPP ILs with

  系统研究了各种四烷基鏻全氟磺酸盐离子液体（TPP ILs、C6F13SO3P4444、C8F17SO3P4444 和 C8F17SO3P8888）对 Ti-6Al-4V 摩擦对的润滑，并与基于 BF4− 或 PF6− 和 TFSI− 阴离子的常规 ILs 润滑剂进行了比较。结果表明，TPP ILs 在 Ti-6Al-4V 上具有优于现有 IL 润滑剂的润滑性能。润滑机理分析表明，当使用 TPP ILs 润滑时，Ti 合金 tribopair 表面在滑动过程中会产生物理化学吸附膜和摩擦化学反应膜。与参考样品相比，TPP ILs 和摩擦表面之间物理化学吸附膜的形成是优越的摩擦学性能的主要原因。通过比较 TPP ILs 与全氟磺酸四丁基铵 IL C8F17SO3N4444 和羧酸四丁基膦 IL C8F15O2P4444 的摩擦学特性，发现全氟磺酸盐 ILs 的化学结构对润滑能力有显着影响。磺酸盐基团和含
• Fluoroxy compound solutions
  申请人：E. I. Dupont de Nemours and Company

  公开号：US04568478A1

  公开（公告）日：1986-02-04

  There is disclosed a solution of at least one fluoroxy compound, wherein said solution has a fluoroxy compound concentration of at least 0.5 meq/liter; said concentration containing about 35 to 100% of an acyl hypofluorite, based on the total number of equivalents of fluoroxy compounds present. The acyl hypofluorite has the formula X(CF.sub.2).sub.n COOF wherein X is H or F and n is 5 to 16. The solution is prepared by treating a suspension of a corresponding specified alkali salt with excess F.sub.2, and is useful as a selective fluorinating agent.

  本发明公开了至少一种氟氧化合物的溶液，其中所述溶液的氟氧化合物浓度至少为0.5毫当量/升；所述浓度含有基于存在的氟氧化合物总当量数约35至100％的酰基次氟酸盐。酰基次氟酸盐的化学式为X(CF.sub.2).sub.n COOF，其中X为H或F，n为5至16。该溶液是通过用过量的F.sub.2处理相应指定碱盐的悬浮液制备而成，并可用作选择性氟化试剂。
• Aqueous fluororesin coating composition and process for producing same
  申请人：TOAGOSEI CO., LTD.

  公开号：EP0675182A1

  公开（公告）日：1995-10-04

  An aqueous fluororesin coating composition and a process for producing the same, the coating composition comprising a core/shell fluorine-containing copolymer dispersed in an aqueous medium, the core/shell fluorine-containing copolymer comprising a core comprising a fluorine-containing copolymer comprising a repeating unit derived from a fluoroolefin monomer and a repeating unit derived from a vinyl carboxylate monomer and having a glass transition point Tg of 40°C or more, and a shell comprising a fluorine-containing copolymer comprising a repeating unit derived from a fluoroolefin monomer and a repeating unit derived from a vinyl carboxylate monomer and having a glass transition point Tg of from -10 to 30°C, the weight ratio of the core to the shell being from 20/1 to 1/2.

  一种水性氟树脂涂料组合物及其生产工艺，该涂料组合物包括分散在水性介质中的芯/壳含氟共聚物，芯/壳含氟共聚物包括芯，该芯由含氟共聚物组成，该含氟共聚物由氟烯烃单体衍生的重复单元和乙烯基羧酸酯单体衍生的重复单元组成，其玻璃化转变点Tg为40℃或更高、和外壳，外壳由含氟共聚物组成，含氟共聚物由氟烯烃单体衍生的重复单元和乙烯基羧酸酯单体衍生的重复单元组成，玻璃化转变点 Tg 为 -10 至 30°C，内核与外壳的重量比为 20/1 至 1/2 之间。
• Method for absorbing and recovering fluorine-containing emulsifier
  申请人：ASAHI GLASS COMPANY LTD.

  公开号：EP1314700A1

  公开（公告）日：2003-05-28

  A method for adsorbing and recovering a fluorine-containing emulsifier at a high recovery from coagulation waste water of a fluoropolymer, is presented. An inorganic acid is added to coagulation waste water of a fluoropolymer containing a fluorine-containing emulsifier, to adjust the pH of the waste water to a level of at least 1 and less than 6, then a metal chloride having a solubility of at least 5 mass% in water at 25°C, or a hydrate of the metal chloride, is added to the waste water, to coagulate and remove a solid content and/or a substance convertible to a solid content, contained in the waste water, and then the waste water is contacted to a weakly basic anion exchange resin.

  本发明提出了一种从含氟聚合物的混凝废水中以高回收率吸附和回收含氟乳化剂的方法。在含有含氟乳化剂的含氟聚合物的混凝废水中加入一种无机酸，将废水的 pH 值调节到至少为 1 但小于 6 的水平，然后在 25°C 的水中加入一种溶解度至少为 5 质量％的金属氯化物或金属氯化物的水合物、或该金属氯化物的水合物，使废水中含有的固体成分和/或可转化为固体成分的物质凝结并去除，然后将废水与弱碱性阴离子交换树脂接触。
• PROCESS FOR THE RECOVERY OF FLUORINE-CONTAINING EMULSIFIERS
  申请人：Sasakura Engineering Co. Ltd.

  公开号：EP1514848A1

  公开（公告）日：2005-03-16

  An aqueous solution containing a fluorine-containing emulsifier in a low concentration of at least 1 ppm by mass and at most 1% by mass (e.g., coagulation waste water after an emulsion polymerization of a fluoropolymer and/or an aqueous solution obtained by washing with an aqueous solution a waste gas from a drying process and/or a heat treating process of the fluoropolymer) is subjected to vacuum concentration under a pressure of at most 100 kPa and a temperature of the aqueous solution of at most 100°C by means of a heating tube surface evaporation type concentrator equipped with a heat pump or the like, and the fluorine-containing emulsifier is recovered from a highly concentrated aqueous solution containing the fluorine-containing emulsifier in a higher concentration of at least 5% by mass. According to the present method, the fluorine-containing emulsifier can be recovered with a high yield from a low-concentration liquid such as coagulation waste water of a fluoropolymer.

  含有含氟乳化剂的低浓度水溶液，其质量浓度至少为 1 ppm，最多不超过 1%（例如：含氟聚合物乳液聚合后的凝结废水和/或用水溶液洗涤含氟聚合物干燥过程和/或热处理过程中产生的废气而得到的水溶液）、含氟聚合物乳液聚合后的凝结废水和/或用水溶液洗涤含氟聚合物干燥工序和/或热处理工序产生的废气后得到的水溶液），在压力不超过 100 kPa 和水溶液温度不超过 100°C 的条件下，通过配备热泵或类似装置的加热管表面蒸发型浓缩器进行真空浓缩、从高浓度水溶液中回收含氟乳化剂，高浓度含氟乳化剂的质量浓度至少为 5%。根据本方法，可从低浓度液体（如含氟聚合物的凝结废水）中高产率地回收含氟乳化剂。