1,3-diallylimidazolium acetate | 1245620-09-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1,3-diallylimidazolium acetate
• 英文别名: 1,3-Bis(prop-2-enyl)imidazol-1-ium;acetate；1,3-bis(prop-2-enyl)imidazol-1-ium;acetate
• CAS: 1245620-09-0
• 化学式: C₂H₃O₂*C₉H₁₃N₂
• 分子量: 208.26
• InChiKey: BHZOMYBRSKSTOE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.1
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  48.9
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  聚合甲醛 、 草酸醛 、 溶剂黄146 、 丙烯胺 以 甲醇 、 水 为溶剂， 反应 6.5h， 生成 1,3-diallylimidazolium acetate
  参考文献：
  名称：

  Efficient Synthesis of 1,3-Dialkylimidazolium-Based Ionic Liquids: The Modified Continuous Radziszewski Reaction in a Microreactor Setup

  摘要：

  By making use of a modified Radziszewski reaction, it is demonstrated that water-soluble 1,3-dialkylimidazolium-based ionic liquids can be produced in good yields (70-90%) and purities (>95%) starting from readily available, cost-effective monoalkyl-amines, glyoxal, formaldehyde, and mineral or organic acids. The homosubstituted 1,3-dialkylimidazolium salts feature high thermal stabilities similar to those of their heterosubstituted counterparts, and relatively low viscosities, thus fulfilling the requirements for solvent application. The effect of various parameters has been studied with the goal of improving yields for both the batchwise and continuous synthesis (making use of a microreactor setup), allowing for the production of a wide variety of ionic liquids and the introduction of functionalities. The applicability of these ionic liquids is demonstrated on the example of cellulose dissolution and the dehydration of fructose to 5-hydroxymethylfurfural.

  DOI：

  10.1021/op100055f

文献信息

• CATALYTIC CONVERSION OF CELLULOSE TO FUELS AND CHEMICALS USING BORONIC ACIDS
  申请人：Raines Ronald

  公开号：US20130178617A1

  公开（公告）日：2013-07-11

  Methods and catalyst compositions for formation of furans from carbohydrates. A carbohydrate substrate is heating in the presence of a 2-substituted phenylboronic acid (or salt or hydrate thereof) and optionally a magnesium or calcium halide salt. The reaction is carried out in a polar aprotic solvent other than an ionic liquid, an ionic liquid or a mixture thereof. Additional of a selected amount of water to the reaction can enhance the yield of furans.

  从碳水化合物中形成呋喃的方法和催化剂组合物。在存在2-取代苯硼酸（或其盐或水合物）以及可选的镁或钙卤化物盐的情况下，加热碳水化合物底物。反应在极性非质子溶剂中进行，该溶剂不是离子液体、离子液体或二者的混合物。向反应中添加适量的水可以增加呋喃的产量。
• Processes Employing Cyclodextrin Derivative Quaternary Salts
  申请人：MATOS Jose R.

  公开号：US20140046061A1

  公开（公告）日：2014-02-13

  Chiral salts comprising anionic cyclodextrin derivatives with particular types of non-metal cations are provided. The anionic CD derivative salts can serve as ionic liquids and can possess substantial advantages over currently commercially available ionic liquids particularly for use as chiral phase transfer catalyst, chiral reaction medium, chiral extraction medium, and/or as chiral additive to a chemical process. Methods of preparing the same are provided.

  提供了包含特定类型非金属阳离子的阴离子环糊精衍生物的手性盐。这些阴离子CD衍生物盐可以作为离子液体，并且在用作手性相转移催化剂、手性反应介质、手性萃取介质和/或作为化学过程的手性添加剂方面，可以比目前商业上可用的离子液体具有显著的优势。提供了制备这些手性盐的方法。
• Ionic liquids for selective sulfur dioxide absorption
  申请人：LENZING AKTIENGESELLSCHAFT

  公开号：EP2692413B1

  公开（公告）日：2015-02-25
• VERFAHREN ZUR HERSTELLUNG VON FORMKÖRPERN AUS PROTEINEN MIT IONISCHEN FLÜSSIGKEITEN
  申请人：THÜRINGISCHES INSTITUT FÜR TEXTIL- UND KUNSTSTOFF-FORSCHUNG e.V.

  公开号：EP2108065A1

  公开（公告）日：2009-10-14
• Method for Producing Molded Bodies from Proteins
  申请人：Brauer Silke

  公开号：US20090051068A1

  公开（公告）日：2009-02-26

  The invention relates to a method for producing molded bodies from proteins by ionic liquids, in particular in 1,3-dialkyl-imidazolium-acetates or 1,3-dialkyl-imidazolium-chloride as solvents in which the protein is dissolved, the solution is formed into fibers and foils, or membranes, respectively, the protein is regenerated by precipitation in protide solutions, the solvent is separated by washing and the molded bodies are tried. Furthermore the invention relates to molded bodies produced by said method.