9-乙基咔唑-3-甲醛-二苯腙 | 73276-70-7

• 物质功能分类: 化学试剂 - 有机试剂 - 腙
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 中文名称: 9-乙基咔唑-3-甲醛-二苯腙
• 中文别名: 9-乙基咔唑-3-甲醛二苯腙；9-乙基-3-(N,N-二苯腙)甲醛咔唑；3-(二苯基亚肼基甲基)-9-乙基咔唑
• 英文名称: N-Ethylcarbazole-3-carbaldehyde diphenylhydrazone
• 英文别名: N-[(9-ethylcarbazol-3-yl)methylideneamino]-N-phenylaniline
• CAS: 73276-70-7
• 化学式: C₂₇H₂₃N₃
• 分子量: 389.5
• InChiKey: CEAPHJPESODIQL-UHFFFAOYSA-N

物化性质

• 熔点：
  156-158 °C(lit.)
• 溶解度：
  溶于甲苯

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  30
• 可旋转键数：
  5
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  20.5
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 危险品标志：
  C
• 安全说明：
  S26,S36/37/39
• 危险类别码：
  R36/37/38

反应信息

• 作为产物：
  描述：

  N,N-二苯基肼 、 N-乙基咔唑-3-甲醛 在 hydrazone 作用下， 以 乙醇 为溶剂， 以to obtain N-ethylcarbazole-3-carbaldehyde diphenylhydrazone with melting point of 160.2°-160.5° C., and 60 parts of this hydrazone compound and 100 parts of a polyester (Vylon 200 by Toyobo Co., Ltd.)的产率得到9-乙基咔唑-3-甲醛-二苯腙
  参考文献：
  名称：

  Electrophotographic plate comprising a conductive substrate and a

  摘要：

  一种电子照相版，包括一个导电基板和一个包含有机光导体层的感光层，所述有机光导体层由通式（I）所表示的腙类化合物组成：##STR1##（其中R.sup.1和R.sup.2是一个可以或不可以有取代基的烷基、芳基烷基或芳基，n是1或2，A是一个可以或不可以有取代基的芳香族碳氢基或芳香族杂环基），以及一个粘合剂。

  公开号：

  US04367273A1

文献信息

• Electrophotographic photoconductor, process for forming an image, image forming apparatus and a process cartridge for the same
  申请人：——

  公开号：US20030190540A1

  公开（公告）日：2003-10-09

  Providing an electrophotographic photoconductor comprising a conductive support and a photoconductive layer disposed on the photoconductive support; wherein the photoconductive layer contains an azo compound expressed by a general formula <<1>>. Ar &Parenopenst;N═N—Cp) n general formula <<1>> (in the general formula <<1>>, Ar expresses one of a substituted or non-substituted aromatic carbon hydride group and heterocyclic ring aromatic series group which can be combined by way of a bond group; Cp expresses a coupler residual group; n expresses an integer of one of 1, 2, 3, and 4; at least one of the Cp is a coupler residual group selected from one of the following general formulae <<2>>, <<3>>, and <<4>>.) 1

  提供一种电照相光导体，包括导电支持和设置在光导支承上的光导层；其中，所述光导层含有一种由下式表示的偶氮化合物。
• [EN] SPIROBIFLUORENE DERIVATIVES HAVING NITROGEN-CONTAINING HETEROARYL RINGS AND THEIR USE IN ORGANIC ELECTRONICS<br/>[FR] DÉRIVÉS DE SPIROBIFLUORÈNE CONTENANT DES CYCLES HÉTÉROARYLE AZOTÉS ET LEUR UTILISATION EN ÉLECTRONIQUE ORGANIQUE
  申请人：SOLVAY USA INC

  公开号：WO2017116625A1

  公开（公告）日：2017-07-06

  The present disclosure relates to emissive films comprising at least one emitter compound having a LUMO energy of at least 1.8 eV and spirobifluorene derivatives having nitrogen-containing heteroaryl rings. The present disclosure also relates to their use in the emissive layer of organic electronic devices, such as, for example, organic light-emitting devices.

  本公开涉及包含至少一种具有至少1.8电子伏特的LUMO能量和含氮杂环芳基环的螺双芴衍生物的发射膜。本公开还涉及它们在有机电子器件的发射层中的使用，例如有机发光器件。
• Reversible electro-optic device employing aprotic molten salts and method
  申请人：Warner P. Benjamin

  公开号：US20060012293A1

  公开（公告）日：2006-01-19

  A reversible electro-optic device includes a medium of variable transmittance to light. The medium includes a soluble redox couple of a first soluble metal containing species and a second soluble metal containing species. The metal of the soluble redox couple is capable of being electrodeposited. The medium also includes one or more anodic compound(s) capable of being oxidized. An alternate medium includes a soluble metal-containing species and a soluble anodic compound, where the soluble metal-containing species includes metal capable of being electrodeposited, and the anodic compound is capable of being oxidized to a soluble oxidized anodic compound. Another electro-optic device includes a medium of variable reflection to light.

  一种可逆的电光器件包括具有可变透光性的介质。该介质包括第一可溶性金属含物种和第二可溶性金属含物种的可溶性氧化还原偶。可溶性氧化还原偶的金属能够被电沉积。该介质还包括一个或多个能够被氧化的阳极化合物。另一种介质包括可溶性金属含物种和可溶性阳极化合物，其中可溶性金属含物种包括能够被电沉积的金属，而阳极化合物能够被氧化为可溶性氧化的阳极化合物。另一种电光器件包括具有可变反射性的介质。
• Aromatic heterocyclic-based charge transport materials having two amino groups
  申请人：Matoliukstyte Ausra

  公开号：US20060051690A1

  公开（公告）日：2006-03-09

  Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Y comprises an aromatic heterocyclic group; X is a bond or a linking group; E comprises a reactive ring group or a reactive functional group; and R 1 , R 2 , R 3 , and R 4 comprise, each independently, H, an alkyl group, an acyl group, an ether group, an alkenyl group, an alkynyl group, a heterocyclic group, an aromatic group, or a part of a ring group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, electrophotographic imaging methods, and bridged charge transport materials derived form the charge transport material above are also described.

  改进的有机光受体包括一个电导基底和一个位于电导基底上的光电传导元件，光电传导元件包括：(a) 具有以下结构的电荷传输材料，其中Y包括芳香杂环基团；X是一个键或一个连接基团；E包括一个反应性环基团或一个反应性官能基团；以及R1、R2、R3和R4，每个独立地包括H、烷基基团、酰基、醚基、烯基基团、炔基基团、杂环基团、芳香基团或环基的一部分；以及(b) 一个电荷生成化合物。还描述了相应的静电复印设备、静电复印成像方法和由上述电荷传输材料衍生的桥接电荷传输材料。
• Organophotoreceptors with a charge transport material having multiple vinyl-containing hydrazone groups
  申请人：Grazulevicius V. Juozas

  公开号：US20060078351A1

  公开（公告）日：2006-04-13

  Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Y comprises an aromatic group; V 1 and V 2 comprise, each independently, a vinyl containing group; and R 1 , R 2 , R 3 , and R 4 comprise, each independently, H, an alkyl group, an acyl group, an ether group, an ester group, an alkenyl group, an alkynyl group, a heterocyclic group, an aromatic group, or a part of a ring group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, electrophotographic imaging methods, and charge transport materials are also described.

  改进的有机光接收器包括一个电导底板和位于电导底板上的光电导元件，光电导元件包括：（a）具有下述结构的电荷传输材料，其中Y包括芳香族基团；V1和V2分别独立地包括含乙烯基团的基团；R1、R2、R3和R4分别独立地包括H、烷基、酰基、醚基、酯基、烯基、炔基、杂环基、芳香族基团或环基的一部分；以及（b）一个电荷生成化合物。还描述了相应的静电复印设备、静电复印成像方法和电荷传输材料。