N,N'-di(2-ethylhexyl)-1,6,7,12-tetrabromoperylene-3,4,9,10-tetracarboxylic acid bisimide | 881662-35-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N'-di(2-ethylhexyl)-1,6,7,12-tetrabromoperylene-3,4,9,10-tetracarboxylic acid bisimide
• 英文别名: 11,14,22,26-Tetrabromo-7,18-bis(2-ethylhexyl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2(26),3,5(25),9,11,13,15,20,23-decaene-6,8,17,19-tetrone
• CAS: 881662-35-7
• 化学式: C₄₀H₃₈Br₄N₂O₄
• 分子量: 930.369
• InChiKey: ODGZCVGYRBEQDQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.7
• 重原子数：
  50
• 可旋转键数：
  12
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N,N'-di(2-ethylhexyl)-1,6,7,12-tetrabromoperylene-3,4,9,10-tetracarboxylic acid bisimide 、 4-(三氟乙烯基氧基苯基)硼酸 在 2-双环己基膦-2',6'-二甲氧基联苯 、 tris(dibenzylideneacetone)dipalladium(0) chloroform complex 、 potassium phosphate 作用下， 以 乙二醇二甲醚 为溶剂， 反应 12.0h， 以50%的产率得到7,18-Bis(2-ethylhexyl)-11,14,22,26-tetrakis[4-(1,2,2-trifluoroethenoxy)phenyl]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2(26),3(12),4(9),5(25),10,13(23),14,16(24),20-decaene-6,8,17,19-tetrone
  参考文献：
  名称：

  Thermally Polymerized Rylene Nanoparticles

  摘要：

  Rylene dyes functionalized with varying numbers of phenyl trifluorovinyl ether (TFVE) moieties were subjected to a thermal emulsion polymerization to yield shape-persistent, water-soluble chromophore nanoparticles. Perylene and terrylene diimide derivatives containing either two or four phenyl TFVE functional groups were synthesized and subjected to thermal emulsion polymerization in tetraglyme. Dynamic light scattering measurements indicated that particles with sizes ranging from 70 to 100 nm were obtained in tetraglyme, depending on monomer concentration. The photophysical properties of individual monomers were preserved in the nanoemulsions, and emission colors could be tuned between yellow, orange, red, and deep red. The nanoparticles were found to retain their shape upon dissolution into water, and the resulting water suspensions displayed moderate to high fluorescence quantum yield:

  DOI：

  10.1021/ma2000866
• 作为产物：
  描述：

  3,4,9,10-苝四羧酸二酐 在 碘 硫酸 、 三氧化硫 、 溴 、 丙酸 作用下， 反应 4.0h， 生成 N,N'-di(2-ethylhexyl)-1,6,7,12-tetrabromoperylene-3,4,9,10-tetracarboxylic acid bisimide
  参考文献：
  名称：

  1,6,7,12-四溴联苯双酰亚胺的Suzuki偶联反应。

  摘要：

  首先以高收率合成了1,6,7,12-四溴代-3-3,4,9,10-四羧酸二氢酐和相应的四溴化bi双酰亚胺。研究了新型四溴联苯双酰亚胺与苯甲酸的Suzuki偶联反应。per核的海湾位置的四个溴被成功取代，得到1,6,7,12-四苯基per联亚酰亚胺。研究并提出了新型per双酰亚胺的光化学性质。

  DOI：

  10.1021/ol052923a

文献信息

• 一种苝二酰亚胺溴取代物及基于其制备炭疽杆菌标识物气相传感薄膜的方法和应用
  申请人：陕西理工大学

  公开号：CN110862393B

  公开（公告）日：2022-08-09

  本发明公开了一种苝二酰亚胺溴取代物及基于其制备炭疽杆菌标识物气相传感薄膜的方法和应用，属于有机半导体材料技术领域。本发明的传感器薄膜主要包括有机活性组装体材料，该有机活性层材料为苝二酰亚胺溴代物PBI‑1Br、PBI‑2Br、PBI‑3Br和PBI‑4Br，其通过溶液滴涂技术负载于玻璃、硅胶或多孔阳极氧化铝基板上，并且涂覆浓度为0.1～0.5uL/cm2。本发明的吡啶二酸传感器制备便捷，操作简单，对吡啶及其衍生物的区分检测效果明显，对于气相吡啶二酸的传感强度最低检测限可达2.8ppt。另外，本发明的吡啶及其衍生物传感器稳定性高，响应时间快。
• Synthesis and Photoinduced Electron Transfer of Phthalocyanine−Perylenebisimide Pentameric Arrays
  作者：F. Javier Céspedes-Guirao、Kei Ohkubo、Shunichi Fukuzumi、Ángela Sastre-Santos、Fernando Fernández-Lázaro

  DOI：10.1021/jo900672j

  日期：2009.8.21

  PDI moieties, affords the charge-separated (CS) state, which was clearly detected by its transient absorption spectrum in femtosecond laser flash photolysis measurements. The CS lifetime was determined to be 26 ps. The addition of Mg(ClO4)2 to a benzonitrile solution of 2 and the photoexcitation affords the long-lived CS state with the lifetime of 480 μs, whereas no such long-lived CS state was formed

  已合成了酞菁锌-per双酰亚胺锌五聚体阵列ZnPc（PDI）4 1和2。ZnPc（PDI）4 1在PDI的间隔位置上没有取代基，而ZnPc（PDI）4 2在每个per的间隔位置上具有四个苯氧基。在这两种情况下，PDI部分都直接连接到ZnPc。由于聚集的结果，光激发1会提供分子间的激基复合物，而不是电荷分离的状态。与1相反，对2进行光激发，其在PDI部分中包含空间要求的取代基，可提供电荷分离（CS）状态，这在飞秒激光闪光光解测量中可通过其瞬态吸收光谱清楚地检测到。CS寿命确定为26 ps。添加Mg（CLO的4）2到的苄腈溶液2和光激发得到具有480微秒的寿命的长寿命的CS的状态，而在的情况下，不形成这样的长寿命的CS状态1在这种条件下。CS寿命的显着延长是由于Mg 2+在CS态下与PDI •-部分的强结合所致。
• Suzuki Coupling Reaction of 1,6,7,12-Tetrabromoperylene Bisimide
  作者：Wenfeng Qiu、Shiyan Chen、Xiaobo Sun、Yunqi Liu、Daoben Zhu

  DOI：10.1021/ol052923a

  日期：2006.3.2

  corresponding tetrabrominated perylene bisimide were first synthesized with high yields. The Suzuki coupling reaction of novel tetrabromoperylene bisimide with phenylbonoric acid was studied. The four bromines in the bay position of the perylene core were substituted successfully to yield 1,6,7,12-teraphenylperylene bisimide. The photochemical properties of the novel perylene bisimides were studied and presented

  首先以高收率合成了1,6,7,12-四溴代-3-3,4,9,10-四羧酸二氢酐和相应的四溴化bi双酰亚胺。研究了新型四溴联苯双酰亚胺与苯甲酸的Suzuki偶联反应。per核的海湾位置的四个溴被成功取代，得到1,6,7,12-四苯基per联亚酰亚胺。研究并提出了新型per双酰亚胺的光化学性质。
• ORGANIC SEMICONDUCTOR COMPOSITION COMPRISING LIQUID MEDIUM
  申请人：CLAP Co., Ltd.

  公开号：EP3183757B1

  公开（公告）日：2022-05-04
• ORGANIC SEMICONDUCTOR COMPOSITION COMPRISING A LIQUID MEDIUM
  申请人：BASF SE

  公开号：US20170250347A1

  公开（公告）日：2017-08-31

  Disclosed are a novel semiconductor composition comprising at least one organic semiconductor in a liquid medium and the use thereof the production of organic semiconductor devices, in particular organic field effect transistors, organic solar cells, light-emitting diodes and sensors.