D16-4,7-diphenyl-1,10-phenanthroline | 457096-96-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: D16-4,7-diphenyl-1,10-phenanthroline
• 英文别名: 2,3,5,6,8,9-Hexadeuterio-4,7-bis(2,3,4,5,6-pentadeuteriophenyl)-1,10-phenanthroline；2,3,5,6,8,9-hexadeuterio-4,7-bis(2,3,4,5,6-pentadeuteriophenyl)-1,10-phenanthroline
• CAS: 457096-96-7
• 化学式: C₂₄H₁₆N₂
• 分子量: 348.277
• InChiKey: DHDHJYNTEFLIHY-NYCJPCIFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  26
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 cis-[bis(D8-2,2'-bipyridine)dichlororuthenium(II)] dihydrate 、 D16-4,7-diphenyl-1,10-phenanthroline 、 水 以 乙醇 、 水 为溶剂， 以80%的产率得到[bis(D8-2,2'-bipyridine)(D16-4,7-diphenyl-1,10-phenanthroline)ruthenium(II)] hexafluorophosphate monohydrate
  参考文献：
  名称：

  Probing inter-ligand excited state interaction in homo and heteroleptic ruthenium(II) polypyridyl complexes using selective deuteriation

  摘要：

  The effect of deuteriation on the photophysical properties of two series of regioselectively deuteriated Ru(II) complexes ([Ru(bipy)(x)(ph(2)phen)(3-x)](2+), where x = 0-3 and ph(2)phen is 4,7-diphenyt-1,10-phenanthroline and [Ru(biPY)(2)(dcbipy(2-))], where H(2)dcbipy is 4,4'-dicarboxy-2,2'-bipyridyl) is reported. Although overall, deuteriation results in an increase in emission lifetime for all complexes, the effect of substitution of hydrogen for deuterium shows strong regioselectivity both in terms of the ligand and the position on individual ligands that are exchanged. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.08.049

文献信息

• Probing inter-ligand excited state interaction in homo and heteroleptic ruthenium(II) polypyridyl complexes using selective deuteriation
  作者：Wesley R. Browne、Paolo Passaniti、Maria Teresa Gandolfi、Roberto Ballardini、William Henry、Adrian Guckian、Noel O’Boyle、John J. McGarvey、Johannes G. Vos

  DOI：10.1016/j.ica.2006.08.049

  日期：2007.2

  The effect of deuteriation on the photophysical properties of two series of regioselectively deuteriated Ru(II) complexes ([Ru(bipy)(x)(ph(2)phen)(3-x)](2+), where x = 0-3 and ph(2)phen is 4,7-diphenyt-1,10-phenanthroline and [Ru(biPY)(2)(dcbipy(2-))], where H(2)dcbipy is 4,4'-dicarboxy-2,2'-bipyridyl) is reported. Although overall, deuteriation results in an increase in emission lifetime for all complexes, the effect of substitution of hydrogen for deuterium shows strong regioselectivity both in terms of the ligand and the position on individual ligands that are exchanged. (c) 2006 Elsevier B.V. All rights reserved.