1-Aminooxy-hexadecan | 109498-49-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-Aminooxy-hexadecan
• 英文别名: n-Hexadecyloxyamin；O-hexadecyl-hydroxylamine；O-hexadecylhydroxylamine
• CAS: 109498-49-9
• 化学式: C₁₆H₃₅NO
• 分子量: 257.46
• InChiKey: LFEDBDWFFNNYNT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  18
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  35.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-Aminooxy-hexadecan 在 盐酸 作用下， 以 乙醇 为溶剂， 反应 72.0h， 生成 O-hexadecyl-hydroxylamine; hydrochloride
  参考文献：
  名称：

  Synthesis and Fungicidal Activity of Macrolactams and Macrolactones with an Oxime Ether Side Chain

  摘要：

  Three series of novel macrolactams and macrolactones - 12-alkoxyimino-tetradecanlactam, 12-alkoxyiminopentadecanlactam, and 12-alkoxyiminodecanlactone derivatives (7A, 7B, and 7C) - were synthesized from corresponding 12-oxomacrolactams and 12-oxomacrolactone. Their structures were confirmed by H-1 NMR and elemental analysis. The Z and E isomers of 7A and 7B were separated, and their configurations were determined by H-1 NMR. These compounds showed fair to excellent fungicidal activities against Rhizoctonia solani Kuhn. It is interesting that the Z and E isomers of most of the compounds have quite different fungicidal activities. The fact that the compounds have a gradual increase of fungicidal activity in the order of 7A, 7C, and 7B indicated that the macrocyclic derivatives with a hydrogen-bonding acceptor (=N-O-) and a hydrogen-bonding donor (-CONH-) on the ring, and a three methylenes distance (CH2CH2CH2) between these two functional groups, exhibited the best fungicidal activity. The bioassay also showed that 7B not only has good fungicidal activity but also may have a broad spectrum of fungicidal activities.

  DOI：

  10.1021/jf072733+
• 作为产物：
  描述：

  hexadecyloxy-carbamic acid ethyl ester 生成 1-Aminooxy-hexadecan
  参考文献：
  名称：

  45.氨基氧基衍生物。第二部分 N-羟基二胍的一些衍生物

  摘要：

  DOI：

  10.1039/jr9600000229

文献信息

• Lubricating oil compositions and concentrates and the use thereof
  申请人：ETHYL PETROLEUM ADDITIVES, INC.

  公开号：EP0492934A1

  公开（公告）日：1992-07-01

  Oleaginous compositions and additive concentrates therefor having enhanced performance characteristics comprise at least a) one or more oil-soluble overbased alkali or alkaline earth metal-containing detergents having a TBN of at least 200; and b) one or more oil-soluble additive compositions formed by heating concurrently or in any sequence at least one ashless dispersant which contains basic nitrogen and/or at least one hydroxyl group with (i) at least one inorganic phosphorus acid or anhydride, or at least one partial or total sulfur analog thereof, or any combination of the foregoing; or (ii) at least one water-hydrolyzable organic phosphorus-containing compounds and water; and (iii) at least one boron compound; such that a liquid composition containing both phosphorus and boron is formed. The weight ratio of metal as component a) to phosphorus as component b) is in the range of 0.15:1 to 10:1.

  具有增强性能特征的油性组合物及其添加剂浓缩物至少包括 a) 一种或多种油溶性过基碱金属或碱土金属洗涤剂，其 TBN 至少为 200；(b) 一种或多种油溶性添加剂组合物，通过同时或任意顺序加热至少一种无 灰分散剂而形成，该分散剂含有碱性氮和/或至少一个羟基与 (i) 至少一种无机磷酸或磷酸酐，或至少一种其部分或全部硫类似物， 或上述物质的任意组合；或 (ii) 至少一种可水解的有机含磷化合物和水；以及 (iii) 至少一种硼化合物；从而形成一种既含磷又含硼的液体组合物。作为 a)组分的金属与作为 b)组分的磷的重量比范围为 0.15:1 至 10:1。
• Lubricating oil compositions, concentrates and the use thereof
  申请人：ETHYL PETROLEUM ADDITIVES, INC.

  公开号：EP0493928A1

  公开（公告）日：1992-07-08

  Oleaginous compositions and additive concentrates therefor having enhanced performance characteristics comprise at least a) one or more oil-soluble metal dihydrocarbyl dithiophosphates or dithiocarbamates; and b) one or more oil-soluble additive compositions formed by heating concurrently or in any sequence at least one ashless dispersant which contains basic nitrogen and/or at least one hydroxyl group with (i) at least one inorganic phosphorus acid or anhydride, or at least one partial or total sulfur analog thereof, or any combination of the foregoing; or (ii) at least one water-hydrolyzable organic phosphorus compound and water; and (iii) at least one boron compound; such that a phosphorus- and boron-containing liquid composition is formed, and from which excessive water, if present, has been removed at least during or after heating with (ii), if used.

  具有增强性能特征的油胶组合物及其添加剂浓缩物至少包括 a) 一种或多种油溶性金属二氢羰基二硫代磷酸酯或二硫代氨基甲酸酯；(b) 一种或多种油溶性添加剂组合物，通过同时或任意顺序加热至少一种无 灰分散剂而形成，该分散剂含有碱性氮和/或至少一个羟基与 (i) 至少一种无机磷酸或磷酸酐，或至少一种其部分或全部硫类似物， 或上述物质的任意组合；或 (ii) 至少一种可水解的有机磷化合物和水；以及 (iii) 至少一种硼化合物；这样就形成了一种含磷和硼的液体组合物，如果使用了(ii)，在加热过程中或加热后，过量的水分（如果存在）已被去除。
• Oil additive concentrates and lubricants of enhanced performance capabilities
  申请人：ETHYL PETROLEUM ADDITIVES, INC.

  公开号：EP0531000A1

  公开（公告）日：1993-03-10

  Additive concentrates and lubricant compositions containing a combination of additives which result in enhanced performance particularly as regards extreme pressure and antiwear performance. The combination of additives so utilized comprise a-1) at least one oil-soluble additive composition formed by heating concurrently or in any sequence at least one ashless dispersant which contains basic nitrogen and/or at least one hydroxyl group with (i) at least one inorganic phosphorus acid or anhydride, or at least one partial or total sulfur analog thereof, or any combination of the foregoing, and (ii) at least one boron compound; such that a liquid composition is formed; or a-2) at least one oil-soluble boron-free additive composition formed by heating (i) at least one boron-free oil-soluble ashless dispersant containing basic nitrogen and/or at least one hydroxyl group, with (ii) at least one inorganic phosphorus acid such that a liquid boron-free phosphorus-containing composition is formed; or a-3) one or more oil-soluble additive compositions formed by heating concurrently or in any sequence at least one ashless dispersant which contains basic nitrogen and/or at least one hydroxyl group with (i) at least one water-hydrolyzable organic phosphorus compound and water; and (ii) at least one boron compound; such that a liquid phosphorus- and boron-containing composition is formed; or a-4) one or more oil-soluble boron-free additive compositions formed by heating concurrently or in any sequence (i) at least one boron-free oil-soluble ashless dispersant which contains basic nitrogen and/or at least one hydroxyl group, with (ii) -at least one water-hydrolyzable organic phosphorus compound and water; such that a liquid boron-free phosphorus-containing composition is formed; and b) at least one oil-soluble metal-free sulfur-containing antiwear and/or extreme pressure agent having a sulfur content of at least 20% by weight; components a-1), a-2), a-3) or a-4) and b) being proportioned such that the mass ratio (wt:wt) of sulfur in component b) to phosphorus in component a-1), a-2), a-3) or a-4) is in the range of 8:1 to 30:1.

  添加剂浓缩物和润滑剂组合物含有添加剂组合，可提高性能，特别是在极压和抗磨损性能方面。添加剂组合包括 a-1) 至少一种油溶性添加剂组合物，通过同时或任意顺序加热至少一种含碱式氮和/或至少一个羟基的无灰分散剂与(i) 至少一种无机磷酸或磷酸酐，或至少一种其部分或全部硫类似物，或上述物质的任意组合，以及(ii) 至少一种硼化合物，从而形成液体组合物；或 a-2) 至少一种油溶性无硼添加剂组合物，通过加热 (i) 至少一种含碱式氮和/或至少一个羟基的无硼油溶性无灰分散剂，与 (ii) 至少一种无机磷酸，从而形成液态无硼含磷组合物；或 a-3) 一种或多种油溶性添加剂组合物，通过同时或任意顺序加热至少一种含 碱式氮和/或至少一个羟基的无灰分散剂与(i)至少一种可水解的有机磷化 合物和水；和(ii) 至少一种硼化合物；从而形成一种液态含磷和硼的组合物；或 a-4) 一种或多种油溶性无硼添加剂组合物，通过同时或任意顺序加热(i) 至少一种含碱性氮和/或至少一种羟基的无硼油溶性无灰分散剂与(ii) 至少一种可水解的有机磷化合物和水；从而形成一种液态无硼含磷组合物；及 b) 至少一种油溶性无金属含硫抗磨剂和/或极压剂，其硫含量至少为 20%（重量比）；组分 a-1)、a-2)、a-3)或 a-4) 和 b) 的比例为：组分 b) 中硫与组分 a-1)、a-2)、a-3)或 a-4) 中磷的质量比（重量比）在 8:1 至 30:1 之间。
• Lubricating Oil Composition comprising a hydrogenated imide derived from a Diels-Alder adduct of maleic anhydride and a furan
  申请人：Infineum International Limited

  公开号：EP2453000A1

  公开（公告）日：2012-05-16

  A crankcase lubricating oil composition for an internal combustion engine comprising (A) an oil of lubricating viscosity in a major amount; and, (B) as an additive component in a minor amount one or more, oil-soluble imides derived from a hydrogenated Diels-Alder adduct of a maleic anhydride and a furan, where the imide group has the formula >NR, where R is an aliphatic hydrocarbyl group having 4 to 8 carbon atoms.

  一种用于内燃机的曲轴箱润滑油组合物，包括：(A) 主要量的润滑粘度油；以及，(B) 作为添加剂成分的少量一种或多种油溶性酰亚胺，这些酰亚胺来自马来酸酐和呋喃的氢化 Diels-Alder 加合物，其中酰亚胺基团的式子为 >NR，其中 R 是具有 4 至 8 个碳原子的脂肪族烃基。
• Oil-soluble phosphorus antiwear additives for lubricants
  申请人：ETHYL PETROLEUM ADDITIVES, INC.

  公开号：EP0359522B1

  公开（公告）日：1992-06-24