3,5-bis(trimethylsilyl)triphenyleno[1,12-bcd]thiophene | 1009069-68-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 3,5-bis(trimethylsilyl)triphenyleno[1,12-bcd]thiophene
• 英文别名: 3,5-Bis(trimethylsilyl)triphenyleno[1,12-bcd]thiophene；trimethyl-(15-trimethylsilyl-19-thiapentacyclo[14.2.1.05,18.06,11.012,17]nonadeca-1,3,5(18),6,8,10,12(17),13,15-nonaen-2-yl)silane
• CAS: 1009069-68-4
• 化学式: C₂₄H₂₆SSi₂
• 分子量: 402.707
• InChiKey: RPMWXRKLGMMIJG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.89
• 重原子数：
  27
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3,5-bis(trimethylsilyl)triphenyleno[1,12-bcd]thiophene 在 正丁基锂 、 四甲基乙二胺 、 重水 作用下， 以 正己烷 为溶剂， 反应 3.5h， 以30%的产率得到(4,7-Dideuterio-15-trimethylsilyl-19-thiapentacyclo[14.2.1.05,18.06,11.012,17]nonadeca-1,3,5(18),6,8,10,12(17),13,15-nonaen-2-yl)-trimethylsilane
  参考文献：
  名称：

  Synthesis and structures of heterasumanenes having different heteroatom functionalities

  摘要：

  After the protection of two alpha-carbons of the dibenzothiophene moiety in triphenylenothiophene 1 by trimethylsilyl groups, the resulting compound 4 reacted with butyllithium followed by dichlorodimethylsilane to afford 10H-silolo[2',3',4',5':4,5]triphenyleno[1,12-bcd]thiophene 8, which reacted with butyllithium followed by dichlorodimethylsilane to afford novel heterasumanene 11. Using dichlorodimethylstannane instead of dichlorodimethylsilane afforded heterasumanene 12, which is the first example of a heterasumanene having three different heteroatom functionalities. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.11.102
• 作为产物：
  描述：

  三甲基氯硅烷 、 苯并菲并[4,5-bcd]噻吩 在 正丁基锂 、 四甲基乙二胺 作用下， 以 正己烷 、 四氢呋喃 为溶剂， 反应 15.0h， 以71%的产率得到3,5-bis(trimethylsilyl)triphenyleno[1,12-bcd]thiophene
  参考文献：
  名称：

  Arching a bay area of triphenyleno[1,12-bcd]thiophene with group 14 functionalities: Synthesis of the first triphenylene derivatives having thiophene and metallafluorene moieties

  摘要：

  Arching a bay area of triphenyleno[1,12-bcd]thiophene with group 14 functionalities gave the first triphenylene derivatives whose two pairs of bay carbons are connected by two different heteroatom functionalities. Triphenyleno[1,12-bcd:4,5-b'c'd']dithiophene, which had been only accessible through the very severe reaction conditions, was synthesized under the mild reaction conditions. Photophysical properties of newly-obtained heterolotriphenylene derivatives are discussed with theoretical calculations. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.11.039

文献信息

• Arching a bay area of triphenyleno[1,12-bcd]thiophene with group 14 functionalities: Synthesis of the first triphenylene derivatives having thiophene and metallafluorene moieties
  作者：Masaichi Saito、Tomoharu Tanikawa、Tomoyuki Tajima、Jing Dong Guo、Shigeru Nagase

  DOI：10.1016/j.jorganchem.2009.11.039

  日期：2010.4

  Arching a bay area of triphenyleno[1,12-bcd]thiophene with group 14 functionalities gave the first triphenylene derivatives whose two pairs of bay carbons are connected by two different heteroatom functionalities. Triphenyleno[1,12-bcd:4,5-b'c'd']dithiophene, which had been only accessible through the very severe reaction conditions, was synthesized under the mild reaction conditions. Photophysical properties of newly-obtained heterolotriphenylene derivatives are discussed with theoretical calculations. (C) 2009 Elsevier B. V. All rights reserved.
• Synthesis and structures of heterasumanenes having different heteroatom functionalities
  作者：Masaichi Saito、Tomoharu Tanikawa、Tomoyuki Tajima、Jing Dong Guo、Shigeru Nagase

  DOI：10.1016/j.tetlet.2009.11.102

  日期：2010.1

  After the protection of two alpha-carbons of the dibenzothiophene moiety in triphenylenothiophene 1 by trimethylsilyl groups, the resulting compound 4 reacted with butyllithium followed by dichlorodimethylsilane to afford 10H-silolo[2',3',4',5':4,5]triphenyleno[1,12-bcd]thiophene 8, which reacted with butyllithium followed by dichlorodimethylsilane to afford novel heterasumanene 11. Using dichlorodimethylstannane instead of dichlorodimethylsilane afforded heterasumanene 12, which is the first example of a heterasumanene having three different heteroatom functionalities. (C) 2009 Elsevier Ltd. All rights reserved.