((S)-4,6,6-Trimethyl-cyclohex-3-enyl)-acetaldehyde | 138039-74-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: ((S)-4,6,6-Trimethyl-cyclohex-3-enyl)-acetaldehyde
• 英文别名: 2-[(1S)-4,6,6-trimethylcyclohex-3-en-1-yl]acetaldehyde
• CAS: 138039-74-4
• 化学式: C₁₁H₁₈O
• 分子量: 166.263
• InChiKey: NWDMCIXTDCIBAQ-JTQLQIEISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  (-)-α-蒎烯 、 alkaline earth salt of/the/ methylsulfuric acid 在 溶剂黄146 作用下， 生成 ((S)-4,6,6-Trimethyl-cyclohex-3-enyl)-acetaldehyde 、 ((S)-2,2,4-Trimethyl-cyclohex-3-enyl)-acetaldehyde
  参考文献：
  名称：

  Synthetic use of a σ-alkyl-π-allyl iron complex obtained by stereospecific ring opening of α-pinene

  摘要：

  Insertion of iron carbonyl into the four-membered ring of alpha-pinene produces a versatile iron complex exhibiting an iron-carbon sigma-bond. Reaction of this complex with various reagents, i.e. dimethyl butynedioate, produces the bicyclic ketones 2, 7, and 8 with moderate to high regioselectivity and full conservation of the optical purity of the starting terpene.

  DOI：

  10.1016/0040-4039(91)80763-v

文献信息

• Synthetic use of a σ-alkyl-π-allyl iron complex obtained by stereospecific ring opening of α-pinene
  作者：Titus A. Jenny、Liqian Ma

  DOI：10.1016/0040-4039(91)80763-v

  日期：1991.10

  Insertion of iron carbonyl into the four-membered ring of alpha-pinene produces a versatile iron complex exhibiting an iron-carbon sigma-bond. Reaction of this complex with various reagents, i.e. dimethyl butynedioate, produces the bicyclic ketones 2, 7, and 8 with moderate to high regioselectivity and full conservation of the optical purity of the starting terpene.