3,3-diethyl-octan-4-one | 18295-58-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3,3-diethyl-octan-4-one
• 英文别名: Triethylhexanone；3,3-diethyloctan-4-one
• CAS: 18295-58-4
• 化学式: C₁₂H₂₄O
• 分子量: 184.322
• InChiKey: DCIFKIIQMLNANC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1,1-二乙基丙基氯化镁 、 戊酰氯 在 copper(I) chloride 作用下， 以 乙醚 为溶剂， 生成 3,3-diethyl-octan-4-one
  参考文献：
  名称：

  硫化氯-有机酰胺的存在与卤素的存在：异质竞争和同质竞争。合成丙酮混合物

  摘要：

  研究了在氯化亚铜存在下七种位阻酰基氯RCOCl对乙基溴化镁的反应性。除酮RCOEt外，还通过自由基反应生成化合物RCOCOR，RCOR，RR，RH和R（= H）。在卤化亚铜存在下，R'MgX与iPr 2 CHCOCl的缩合反应通过烷基铜物质R'Cu.MgXX'与酰氯反应生成酮RCOR'。自由基过程是通过烷基铜中间体的分解而引发的。研究了在最佳酮化条件下温度，溶剂和结构对烷基铜稳定性的影响。通过合成9种受阻酮iPr 2 CHCOR'可以具体证明这一点，其中Me⩽R'⩽Et 3C和Tr。

  DOI：

  10.1016/0040-4020(73)80220-0

文献信息

• COMPOSITION FOR WASHING AGENT, AND WASHING AGENT
  申请人：The Nisshin OilliO Group, Ltd.

  公开号：EP2778217A1

  公开（公告）日：2014-09-17

  The present invention relates to a composition for a cleansing agent comprising a component (A) in the form of an ionic surfactant and a component (B) in the form of one or more types of compounds selected from the group consisting of a hydroxystearic acid polymer and an esterification reaction product of a hydroxystearic acid polymer. According to the present invention, a composition for a cleansing agent can be provided that has favorable foaming power and foam quality, is easily rinsed during cleansing, is free of stickiness after cleansing and allows the obtaining of a moist feeling.

  本发明涉及一种清洁剂组合物，该组合物包含离子表面活性剂形式的组分（A）和选自羟基硬脂酸聚合物和羟基硬脂酸聚合物的酯化反应产物组成的组中的一种或多种化合物形式的组分（B）。根据本发明，可以提供一种清洁剂组合物，该组合物具有良好的发泡力和泡沫质量，在清洁过程中易于冲洗，清洁后无粘性，并可获得湿润感。
• Composition for cleansing agent and cleansing agent
  申请人：The Nisshin OilliO Group, Ltd.

  公开号：EP2778217B1

  公开（公告）日：2020-07-01
• SKIN-LIGHTENING COMPOSITIONS WITH AN IMPROVED ACTION
  申请人：DOERING Thomas

  公开号：US20080152604A1

  公开（公告）日：2008-06-26

  Cosmetic or dermatological preparations are comprised of from 0.01 to 5% by weight of a dicarboxylic acid selected from the group consisting of 8-hexadecene-1,16-dicarboxylic acid decanedioic acid nonanedioic acid and combinations thereof and from 0.01 to 5% by weight of ascorbic acid, salts of ascorbic acid, ascorbic acid derivatives and combinations thereof. These preparations provide skin-lightening and/or hair-lightening preparations which inhibit melanin biosynthesis and do not damage hair and/or skin.
• COMPOSITION FOR CLEANSING AGENT AND CLEANSING AGENT
  申请人：The Nisshin Oillio Group, Ltd.

  公开号：US20140323386A1

  公开（公告）日：2014-10-30

  The present invention relates to a composition for a cleansing agent comprising a component (A) in the form of an ionic surfactant and a component (B) in the form of one or more types of compounds selected from the group consisting of a hydroxystearic acid polymer and an esterification reaction product of a hydroxystearic acid polymer. According to the present invention, a composition for a cleansing agent can be provided that has favorable foaming power and foam quality, is easily rinsed during cleansing, is free of stickiness after cleansing and allows the obtaining of a moist feeling.
• US9428715B2
  申请人：——

  公开号：US9428715B2

  公开（公告）日：2016-08-30