1-amino-6,7-O-cyclohexylidene-4-azaheptane | 207348-63-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-amino-6,7-O-cyclohexylidene-4-azaheptane
• 英文别名: N~1~-[(1,4-Dioxaspiro[4.5]decan-2-yl)methyl]propane-1,3-diamine；N'-(1,4-dioxaspiro[4.5]decan-3-ylmethyl)propane-1,3-diamine
• CAS: 207348-63-8
• 化学式: C₁₂H₂₄N₂O₂
• 分子量: 228.335
• InChiKey: UTFONDPKLKJUJW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  56.5
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  copper(II) acetate monohydrate 、 1-amino-6,7-O-cyclohexylidene-4-azaheptane 以 乙醇 、 氯仿 为溶剂， 以75%的产率得到[Cu(1-amino-6,7-O-cyclohexylidene-4-azaheptane)2(OAc)2]
  参考文献：
  名称：

  Preparation of complexes of 1-amino-6,7-O-cyclohexylidene-4-azaheptane with transition metal acetates

  摘要：

  1-Amino-6,7-O-cyclohexylidene-4-azaheptane (L) has been synthesized starting from 1-chloro-2,3-O-cyclohexylidenepropane prepared by the reaction of epichlorohydrin with cyclohexanone, catalyzed by BF3OEt2, Complexes of this ligand with Co(II), Ni(II) and Cu(II) acetates were prepared. The structures of the ligand and its complexes are proposed based on the elemental analyses, IR, UV-VIS, and H-1 and C-13 NMR spectra, magnetic susceptibilities, and conductomety data.

  DOI：

  10.1134/s1070363206010075
• 作为产物：
  描述：

  2-氯甲基-1,4-二哑螺[4.5]癸烷 、 1,3-丙二胺 在 三乙胺 作用下， 以 xylene 为溶剂， 反应 30.0h， 以65%的产率得到1-amino-6,7-O-cyclohexylidene-4-azaheptane
  参考文献：
  名称：

  Preparation of complexes of 1-amino-6,7-O-cyclohexylidene-4-azaheptane with transition metal acetates

  摘要：

  1-Amino-6,7-O-cyclohexylidene-4-azaheptane (L) has been synthesized starting from 1-chloro-2,3-O-cyclohexylidenepropane prepared by the reaction of epichlorohydrin with cyclohexanone, catalyzed by BF3OEt2, Complexes of this ligand with Co(II), Ni(II) and Cu(II) acetates were prepared. The structures of the ligand and its complexes are proposed based on the elemental analyses, IR, UV-VIS, and H-1 and C-13 NMR spectra, magnetic susceptibilities, and conductomety data.

  DOI：

  10.1134/s1070363206010075

文献信息

• Preparation of complexes of 1-amino-6,7-O-cyclohexylidene-4-azaheptane with transition metal acetates
  作者：Ö. F. Öztirk、M. Şekerci、E. Özdemir

  DOI：10.1134/s1070363206010075

  日期：2006.1

  1-Amino-6,7-O-cyclohexylidene-4-azaheptane (L) has been synthesized starting from 1-chloro-2,3-O-cyclohexylidenepropane prepared by the reaction of epichlorohydrin with cyclohexanone, catalyzed by BF3OEt2, Complexes of this ligand with Co(II), Ni(II) and Cu(II) acetates were prepared. The structures of the ligand and its complexes are proposed based on the elemental analyses, IR, UV-VIS, and H-1 and C-13 NMR spectra, magnetic susceptibilities, and conductomety data.