1,4-dimethylcyclohexane-1,4-diol | 90414-69-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,4-dimethylcyclohexane-1,4-diol
• CAS: 90414-69-0
• 化学式: C₈H₁₆O₂
• 分子量: 144.214
• InChiKey: HYQVJTPIWPMTLK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,4-dimethylcyclohexane-1,4-diol 在 氯氟磺酰 、 五氟化锑 作用下， 生成 1,4-dimethylcyclohexane
  参考文献：
  名称：

  Stable carbocations. 230. 2,5-Diphenyl-2,5-norbornyl dications

  摘要：

  DOI：

  10.1021/ja00539a026

文献信息

• Iron-catalyzed cross-coupling of methanol with secondary or tertiary alcohols to produce formate esters
  申请人：Eastman Chemical Company

  公开号：US10435349B2

  公开（公告）日：2019-10-08

  A process for preparing a variety of secondary and tertiary alkyl formate esters via the coupling of methanol and secondary (or tertiary) alcohols. Iron-based catalysts, supported by pincer ligands, are employed to produce these formate esters in high yields and unprecedentedly high selectivities (>99%). Remarkably, the coupling strategy is also applicable to bulkier tertiary alcohols, which afford corresponding tertiary formate esters in moderately high yields and high selectivities.

  一种通过甲醇和仲醇（或叔醇）偶联制备各种仲烷基和叔烷基甲酸酯的工艺。铁基催化剂在钳形配体的支持下，以高产率和前所未有的高选择性（大于 99%）制备这些甲酸酯。值得注意的是，这种偶联策略也适用于体积较大的叔醇，它们能以中等高产率和高选择性生成相应的甲酸叔酯。
• OLAH G. A.; PRAKASH G. K. S.; RAWDAH T. N., J. AMER. CHEM. SOC., 1980, 102, NO 19, 6127-6130
  作者：OLAH G. A.、 PRAKASH G. K. S.、 RAWDAH T. N.

  DOI：——

  日期：——
• IRON-CATALYZED CROSS-COUPLING OF METHHANOL WITH SECONDARY OR TERTIARY ALCOHOLS TO PRODUCE FORMATE ESTERS
  申请人：Eastman Chemical Company

  公开号：EP3661906A1

  公开（公告）日：2020-06-10
• IRON-CATALYZED CROSS-COUPLING OF METHANOL WITH SECONDARY OR TERTIARY ALCOHOLS TO PRODUCE FORMATE ESTERS
  申请人：Eastman Chemical Company

  公开号：US20190039992A1

  公开（公告）日：2019-02-07

  A process for preparing a variety of secondary and tertiary alkyl formate esters via the coupling of methanol and secondary (or tertiary) alcohols. Iron-based catalysts, supported by pincer ligands, are employed to produce these formate esters in high yields and unprecedentedly high selectivities (>99%). Remarkably, the coupling strategy is also applicable to bulkier tertiary alcohols, which afford corresponding tertiary formate esters in moderately high yields and high selectivities.
• US4521486A
  申请人：——

  公开号：US4521486A

  公开（公告）日：1985-06-04