N,N-六亚甲基-1,6-二(1-氮丙啶酰胺) | 2271-93-4

• 物质功能分类: 有机原料 - 氨基化合物 - 酰胺类化合物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 中文名称: N,N-六亚甲基-1,6-二(1-氮丙啶酰胺)
• 中文别名: N,N’-1,6-己二基双(1-氮丙啶酰胺)；N,N-五亚甲基-1,6-双(1-氮丙啶羧酰胺；N,N"-1,6-己二基双(1-氮丙啶酰胺)
• 英文名称: N,N'-bis-(aziridine-1-carbonyl)-hexanediyldiamine
• 英文别名: N,N'-Bis-(aziridin-1-carbonyl)-hexandiyldiamin；N,N'-hexane-1,6-diylbis(aziridine-1-carboxamide)；1,6-hexamethylene di(N,N-ethyleneurea)；1-Aziridinecarboxamide, N,N'-1,6-hexanediylbis-；N-[6-(aziridine-1-carbonylamino)hexyl]aziridine-1-carboxamide
• CAS: 2271-93-4
• 化学式: C₁₂H₂₂N₄O₂
• 分子量: 254.332
• InChiKey: YVOQADGLLJCMOE-UHFFFAOYSA-N

物化性质

• 熔点：
  106℃ (acetone )
• 沸点：
  397.54°C (rough estimate)
• 密度：
  1.233±0.06 g/cm3 (20 ºC 760 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.1
• 重原子数：
  18
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  64.2
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2933990090

反应信息

• 作为反应物：
  描述：

  N,N-六亚甲基-1,6-二(1-氮丙啶酰胺) 、 正丁胺 在 乙醇 作用下， 生成 N',N'''-bis-(2-butylamino-ethyl)-N,N''-hexanediyl-di-urea
  参考文献：
  名称：

  Bestian, Justus Liebigs Annalen der Chemie, 1950, vol. 566, p. 210,231

  摘要：

  DOI：
• 作为产物：
  描述：

  乙烯亚胺 、 1,6-己二异氰酸酯 在 丙酮 作用下， 生成 N,N-六亚甲基-1,6-二(1-氮丙啶酰胺)
  参考文献：
  名称：

  Bestian, Justus Liebigs Annalen der Chemie, 1950, vol. 566, p. 210,231

  摘要：

  DOI：

文献信息

• Dicing Die-Bonding Film
  申请人：Nitto Denko Corporation

  公开号：EP2090633A1

  公开（公告）日：2009-08-19

  The present invention provides a dicing die-bonding film (10, 11) including a dicing film having a pressure sensitive adhesive layer (2) provided on a base material (1) and a die-bonding film (3, 3') provided on the pressure sensitive adhesive layer (2), and having excellent storage stability of a product even at room temperature. The dicing die-bonding film (10, 11) in the present invention is a dicing die-bonding film having a dicing film including a radiation curable pressure sensitive adhesive layer (2) provided onto a base material (1) and a die-bonding film (3, 3') provided on the pressure sensitive adhesive layer (2), in which a pressure sensitive adhesive in the pressure sensitive adhesive layer (2) is constituted by containing an acryl polymer, and in which the acid value of the acryl polymer is in a range of 0.01 to 1 and the iodine value is in a range of 5 to 10.

  本发明提供了一种切割模粘合膜（10，11），包括在基材（1）上设置有压敏胶层（2）的切割膜和在压敏胶层（2）上设置有模粘合膜（3，3'）的模粘合膜，该模粘合膜即使在室温下也具有优异的产品储存稳定性。本发明中的切割模粘合膜（10，11）是一种切割模粘合膜，其切割膜包括设置在基材（1）上的辐射固化压敏胶层（2）和设置在压敏胶层（2）上的模粘合膜（3，3'），其中压敏胶层（2）中的压敏胶由含有丙烯酸聚合物的压敏胶构成，丙烯酸聚合物的酸值范围为 0.01至1，碘值范围为5至10。
• LIQUID CRYSTAL LIGHT CONTROL ELEMENT AND PROCESS FOR PRODUCING THE LIQUID CRYSTAL LIGHT CONTROL ELEMENT
  申请人：Nippon Sheet Glass Company Limited

  公开号：EP2224279A1

  公开（公告）日：2010-09-01

  In the production method of the present invention, an emulsion including a copolymer with a glass transition temperature (Tg) of -50 to 20°C is obtained by the emulsion polymerization of a monomer group including a monomer A that is a (meth)acrylic acid alkyl ester (where the alkyl group is an open chain group with 1 to 20 carbon atoms or a cyclic group with 5 to 20 carbon atoms) as the main monomer and a monomer B having a carbon-carbon double bond and a nonionic hydrophilic group such as a polyoxyalkylene group, an amide group, and a hydroxyl group. Liquid crystals are dispersed in this emulsion, which is applied onto a conductive film-coated substrate. Another conductive film-coated substrate is laminated thereto, and thus a liquid crystal light control device is obtained. A monomer C having a carboxyl group and/or an amino group and a carbon-carbon double bond may be used in combination with a crosslinking agent so that a crosslinked structure is introduced into the copolymer. The present invention provides a liquid crystal light control device in which the transparency with a voltage applied and the shielding property with no voltage applied are compatible at high level.

  在本发明的生产方法中一种包括玻璃化转变温度（Tg）为 -50 至 20°C 的共聚物的乳液，是由包括作为主单体的（甲基）丙烯酸烷基酯（其中烷基是具有 1 至 20 个碳原子的开链基团或具有 5 至 20 个碳原子的环状基团）的单体 A 和具有碳碳双键和非离子亲水基团（如聚氧烷基、酰胺基和羟基）的单体 B 的乳液聚合而成。液晶分散在这种乳液中，然后涂在涂有导电薄膜的基底上。将另一种涂有导电薄膜的基底层压在上面，就得到了液晶光控制装置。具有羧基和/或氨基以及碳碳双键的单体 C 可与交联剂结合使用，从而在共聚物中引入交联结构。本发明提供了一种液晶光控制装置，在该装置中，加电压时的透明性和不加电压时的屏蔽性在高水平上兼容。
• DICING/DIE BONDING FILM
  申请人：Nitto Denko Corporation

  公开号：EP2242089A1

  公开（公告）日：2010-10-20

  The present invention provides a dicing die-bonding film which is excellent in balance between holding strength of a semiconductor wafer upon dicing and peeling property upon picking up. A dicing die-bonding film comprising a dicing film having a pressure-sensitive adhesive layer on a base material, and a die-bonding film formed on the dicing film,, wherein the pressure-sensitive adhesive layer contains a polymer obtained by the addition reaction of an acrylic polymer containing 10 to 40 mol% of a hydroxyl group-containing monomer with 70 to 90 mol% of an isocyanate compound having a radical reactive carbon-carbon double bond based on the hydroxyl group-containing monomer, and 2 to 20 parts by weight of a crosslinking agent including in the molecule two or more functional groups having reactivity with a hydroxyl group based on 100 parts by weight of the polymer, and the pressure-sensitive adhesive layer is also cured by irradiation with ultraviolet rays under predetermined conditions, and wherein the die-bonding film comprises an epoxy resin, and is also bonded on the pressure-sensitive adhesive layer after irradiation with ultraviolet rays.

  本发明提供了一种在切割半导体晶片时的固定强度和拾取时的剥离性能之间具有良好平衡的切割晶片粘合膜。一种切割粘接膜，包括在基材上具有压敏粘合层的切割膜和在切割膜上形成的粘接膜，其中压敏粘合层含有一种聚合物，该聚合物是由含羟基单体 10 至 40 摩尔%的丙烯酸聚合物与含羟基单体 70 至 90 摩尔%的具有自由基反应碳碳双键的异氰酸酯化合物加成反应得到的、和 2 至 20 份（按聚合物 100 份重量计）的交联剂，交联剂分子中包括两个或两个以上与羟基有反应性的官能团，压敏胶层也在预定条件下通过紫外线照射固化，其中模塑粘合膜包括环氧树脂，在紫外线照射后也粘合在压敏胶层上。
• ACRYLIC POLYMER FOR USE IN PRESSURE-SENSITIVE ADHESIVE COMPOSITION FOR TOUCH PANEL
  申请人：Daido Chemical Corporation

  公开号：EP2607443A1

  公开（公告）日：2013-06-26

  An object of the present invention is to solve the above-mentioned problem of the prior art and provide a pressure-sensitive adhesive composition that has high transparency, excellent adhesion to various substrates such as glass, acrylic, polycarbonate, and PET, as well as having satisfactory high-temperature durability and moist-heat resistance, that is non-corrosive to transparent conductive thin films such as ITO, and to thin metal films, the non-corrosiveness being an important property required of pressure-sensitive adhesives especially for capacitive touch screen panels, and that has excellent gap-filling ability and has high permittivity. Another object of the invention is to provide a pressure-sensitive adhesive sheet. Provided is an acrylic polymer for use in a pressure-sensitive adhesive composition for a touch screen panel, the acrylic polymer being obtained by copolymerizing monomer components comprising (a) a (meth)acrylic acid ester monomer having a C1-12 hydrocarbon group, (b) a hydroxy group-containing (meth)acrylic acid ester monomer, (c) an amide group-containing monomer, and (d) a vinyl ester monomer. The acrylic polymer has an acid value of 0.1 mg KOH/g or less, a weight-average molecular weight of 400,000 to 2,000,000, a Tg of -80 to 0ºC, and a permittivity of 3 to 6.

  本发明的目的是解决现有技术中存在的上述问题，提供一种压敏胶组合物，该组合物具有高透明度，对玻璃、丙烯酸、聚碳酸酯和 PET 等各种基材具有优异的粘附性，并具有令人满意的高温耐久性和耐湿热性、对透明导电薄膜（如 ITO）和金属薄膜无腐蚀性，无腐蚀性是压敏粘合剂（尤其是用于电容式触摸屏面板的压敏粘合剂）所需的重要特性；具有优异的间隙填充能力和高介电常数。本发明的另一个目的是提供一种压敏胶片。本发明提供了一种用于触摸屏面板压敏胶组合物的丙烯酸聚合物，该丙烯酸聚合物是通过共聚单体组分获得的，单体组分包括：(a) 具有 C1-12 碳氢基的（甲基）丙烯酸酯单体；(b) 含羟基的（甲基）丙烯酸酯单体；(c) 含酰胺基的单体；以及 (d) 乙烯基酯单体。丙烯酸聚合物的酸值为 0.1 毫克 KOH/g 或更低，重量平均分子量为 400,000 至 2,000,000，Tg 为 -80 至 0ºC，透射率为 3 至 6。
• AQUEOUS-LIQUID-ABSORBABLE RESIN, AQUEOUS-LIQUID-ABSORBABLE COMPOSITION, AND ABSORBER MATERIAL AND ABSORBABLE OBJECT EACH PRODUCED USING SAME
  申请人：Sanyo Chemical Industries, Ltd.

  公开号：EP2690133A1

  公开（公告）日：2014-01-29

  An absorbable resin, for which a large amount of a plant-derived raw material can be used, and which has an excellent capability of absorbing an aqueous liquid, and has a good gel modulus and therefore can exhibit an excellent absorbing capability under pressurized conditions; and an absorbable composition. An absorbable resin produced by binding an oxidized polysaccharide (A1) having a carboxyl group which may be neutralized with a neutralizing agent and/or a crosslinked product thereof (A2) to a poly(meth)acrylic acid (B1) in which at least one carboxyl group may be neutralized with a neutralizing agent and/or a crosslinked product thereof (B2); or an absorbable composition produced by mixing the component (A1) and/or the component (A2) with the component (B1) and/or the component (B2). The component (A1) has a weight average molecular weight of 2,000-10,000,000. The component (A1) has an acid value of 65-850 mgKOH/g. When the component (A1) has a carboxyl group which is neutralized with a neutralizing agent, the acid value of the component (A1) before the neutralization is 65-850 mgKOH/g.

  一种可吸收树脂，可使用大量植物提取原料，具有极佳的吸收水性液体的能力，并具有良好的凝胶模量，因此可在加压条件下表现出极佳的吸收能力；以及一种可吸收组合物。将具有可被中和剂和/或其交联产物（A2）中和的羧基的氧化多糖（A1）与至少一个羧基可被中和剂和/或其交联产物（B2）中和的聚（甲基）丙烯酸（B1）结合而制得的可吸收树脂；或将组分（A1）和/或组分（A2）与组分（B1）和/或组分（B2）混合而制得的可吸收组合物。组分（A1）的重量平均分子量为 2,000-10,000,000 。组分（A1）的酸值为 65-850 mgKOH/g。当组分（A1）具有用中和剂中和的羧基时，中和前组分（A1）的酸值为 65-850 mgKOH/g。