1-(2-{2-[2-(2-{2-[2-(2-Decyloxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-ethoxy}-ethoxy)-propan-2-one | 833446-65-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(2-{2-[2-(2-{2-[2-(2-Decyloxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-ethoxy}-ethoxy)-propan-2-one
• 英文别名: 4,7,10,13,16,19,22,25-Octaoxapentatriacontan-2-one；1-[2-[2-[2-[2-[2-[2-(2-decoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]propan-2-one
• CAS: 833446-65-4
• 化学式: C₂₇H₅₄O₉
• 分子量: 522.72
• InChiKey: KLZFNMUICDMPJX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  36
• 可旋转键数：
  32
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.96
• 拓扑面积：
  90.9
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  1-(2-{2-[2-(2-{2-[2-(2-Decyloxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-ethoxy}-ethoxy)-propan-2-one 在 Oxone 作用下， 以 重水 为溶剂， 生成 Acetic acid 2-{2-[2-(2-{2-[2-(2-decyloxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-ethoxy}-ethoxymethyl ester
  参考文献：
  名称：

  Alternative protocol for oxidation in water: an effective epoxidation system promoted by the combination of Oxone® and an amphiphilic ketone

  摘要：

  Epoxidation of cyclooctene and other alkenes with Oxone(R) was promoted effectively in an aqueous micellar solution of an amphiphilic ketone, which was easily derived from hepta(ethylene glycol) monodecyl ether. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.11.069
• 作为产物：
  描述：

  1-氯-2-(氯甲基)-3,5-二氧杂己烷 、 聚庚乙二醇单癸醚 在 sodium hydroxide 、 硫酸 作用下， 反应 48.0h， 以62%的产率得到1-(2-{2-[2-(2-{2-[2-(2-Decyloxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-ethoxy}-ethoxy)-propan-2-one
  参考文献：
  名称：

  Alternative protocol for oxidation in water: an effective epoxidation system promoted by the combination of Oxone® and an amphiphilic ketone

  摘要：

  Epoxidation of cyclooctene and other alkenes with Oxone(R) was promoted effectively in an aqueous micellar solution of an amphiphilic ketone, which was easily derived from hepta(ethylene glycol) monodecyl ether. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.11.069

文献信息

• Alternative protocol for oxidation in water: an effective epoxidation system promoted by the combination of Oxone® and an amphiphilic ketone
  作者：Araki Masuyama、Takashi Yamaguchi、Manabu Abe、Masatomo Nojima

  DOI：10.1016/j.tetlet.2004.11.069

  日期：2005.1

  Epoxidation of cyclooctene and other alkenes with Oxone(R) was promoted effectively in an aqueous micellar solution of an amphiphilic ketone, which was easily derived from hepta(ethylene glycol) monodecyl ether. (C) 2004 Elsevier Ltd. All rights reserved.