(2-(4-(phenylethynyl)phenyl)ethene-1,1,2-triyl)tribenzene | 1215028-63-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: (2-(4-(phenylethynyl)phenyl)ethene-1,1,2-triyl)tribenzene
• 英文别名: 1-[4-(2-phenylethynyl)phenyl]-1,2,2-triphenylethene；1-(2-Phenylethynyl)-4-(1,2,2-triphenylethenyl)benzene；1-(2-phenylethynyl)-4-(1,2,2-triphenylethenyl)benzene
• CAS: 1215028-63-9
• 化学式: C₃₄H₂₄
• 分子量: 432.565
• InChiKey: IBTXPGVQZYIRSY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10
• 重原子数：
  34
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (2-(4-(phenylethynyl)phenyl)ethene-1,1,2-triyl)tribenzene 、 以 甲苯 为溶剂， 反应 72.0h， 以65%的产率得到
  参考文献：
  名称：

  邻甲硼烷官能化的四苯乙烯发光体的聚集诱导发射特性：甲硼烷笼对光致发光的影响

  摘要：

  构建了四苯乙烯（TPE）-碳烷杂化物，并研究了碳硼烷取代基对TPE核的聚集诱导发射（AIE）特性的影响。当用-H，-CH 3或苯基改变碳硼烷单元上的2-R-基团时，相应的TPE衍生物在固态下的发光量子产率可以从0.18调节到0.63。发射颜色表现出明显的100 nm偏移（从蓝色到黄色）。

  DOI：

  10.1002/asia.201700922
• 作为产物：
  描述：

  4-溴苯甲酰苯 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 正丁基锂 、 对甲苯磺酸 、 三乙胺 、 三苯基膦 作用下， 以 四氢呋喃 、 正己烷 、 甲苯 为溶剂， 反应 22.5h， 生成 (2-(4-(phenylethynyl)phenyl)ethene-1,1,2-triyl)tribenzene
  参考文献：
  名称：

  Synthesis, Light Emission, Explosive Detection, Fluorescent Photopatterning, and Optical Limiting of Disubstituted Polyacetylenes Carrying Tetraphenylethene Luminogens

  摘要：

  Tetraphenylethene-functionalized acetylenes [(C6H5)(2)C=C(C6H5)(C6H4C equivalent to CR), R = C8H17 and C6H5] were synthesized, and their polymerizations were effected by WCl6Ph4Sn at elevated temperatures in toluene under nitrogen, furnishing polymers P1 and P2. The polymers possessed good solubility and degraded at high temperatures of up to similar to 400 degrees C under nitrogen. Both polymers emitted weakly in the solution state. Whereas the emission of P1 was enhanced when aggregated, that of P2 was quenched, demonstrating that the light emission of polyacetylenes could be varied readily by changing their molecular structure. The polymers could serve as fluorescent chemosensors for explosive detection with an amplification effect. UV irradiation of their films in air photo-oxidized and bleached the fluorescence of the exposed parts, generating fluorescent photopatterns. The polymers exhibited optical nonlinearity and could limit laser pulses.

  DOI：

  10.1021/ma502341j

文献信息

• Preparation of Potassium Alkynylaryltrifluoroborates from Haloaryltrifluoroborates via Sonogashira Coupling Reaction
  作者：Dong-Su Kim、Jungyeob Ham

  DOI：10.1021/ol100081v

  日期：2010.3.5

  A novel series of alkyne-containing potassium organotrifluoroborates were prepared in good yields from the corresponding haloaryltrifluoroborates and various alkynes via Sonogashira coupling reaction. Also, the Suzuki−Miyaura cross-coupling reaction of alkynylaryltrifluoroborates with aryl and alkenyl bromides was achieved in the presence of 5 mol % of Pd(TPP)4 and 3.0 equiv of Cs2CO3 in aqueous 1

  通过Sonogashira偶联反应，由相应的卤代芳基三氟硼酸酯和各种炔烃以高收率制备了一系列新的含炔烃的有机三氟硼酸钾。同样，在150° C的1,4-二恶烷水溶液中存在5 mol％的Pd（TPP）4和3.0当量的Cs 2 CO 3存在下，实现了炔基芳基三氟硼酸酯与芳基和烯基溴化物的Suzuki-Miyaura交叉偶联反应。C通过微波辐照。
• Synthesis, Light Emission, Explosive Detection, Fluorescent Photopatterning, and Optical Limiting of Disubstituted Polyacetylenes Carrying Tetraphenylethene Luminogens
  作者：Carrie Y. K. Chan、Jacky W. Y. Lam、Chunmei Deng、Xiaojun Chen、Kam Sing Wong、Ben Zhong Tang

  DOI：10.1021/ma502341j

  日期：2015.2.24

  Tetraphenylethene-functionalized acetylenes [(C6H5)(2)C=C(C6H5)(C6H4C equivalent to CR), R = C8H17 and C6H5] were synthesized, and their polymerizations were effected by WCl6Ph4Sn at elevated temperatures in toluene under nitrogen, furnishing polymers P1 and P2. The polymers possessed good solubility and degraded at high temperatures of up to similar to 400 degrees C under nitrogen. Both polymers emitted weakly in the solution state. Whereas the emission of P1 was enhanced when aggregated, that of P2 was quenched, demonstrating that the light emission of polyacetylenes could be varied readily by changing their molecular structure. The polymers could serve as fluorescent chemosensors for explosive detection with an amplification effect. UV irradiation of their films in air photo-oxidized and bleached the fluorescence of the exposed parts, generating fluorescent photopatterns. The polymers exhibited optical nonlinearity and could limit laser pulses.
• Aggregation-Induced Emission Characteristics of <i>o</i> -Carborane-Functionalized Tetraphenylethylene Luminogens: The Influence of Carborane Cages on Photoluminescence
  作者：Xiang Li、Yongheng Yin、Hong Yan、Changsheng Lu

  DOI：10.1002/asia.201700922

  日期：2017.9.5

  Tetraphenylethylene (TPE)–carborane hybrids are constructed, and the impact of carborane substituents on the aggregation‐induced emission (AIE) characteristics of TPE‐cores has been investigated. When altering the 2‐R‐group on the carborane unit with ‐H, ‐CH3 or phenyl group, the luminescent quantum yield of the corresponding TPE derivatives can be manipulated from 0.18 to 0.63 in the solid state.

  构建了四苯乙烯（TPE）-碳烷杂化物，并研究了碳硼烷取代基对TPE核的聚集诱导发射（AIE）特性的影响。当用-H，-CH 3或苯基改变碳硼烷单元上的2-R-基团时，相应的TPE衍生物在固态下的发光量子产率可以从0.18调节到0.63。发射颜色表现出明显的100 nm偏移（从蓝色到黄色）。