1-(3-chloropentyl)imidazole | 1097807-13-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-(3-chloropentyl)imidazole
• 英文别名: ImC5Cl；1-(5-chloropentyl)-1H-imidazole；1-(5-chloropentyl)imidazole
• CAS: 1097807-13-0
• 化学式: C₈H₁₃ClN₂
• mdl: MFCD11644959
• 分子量: 172.658
• InChiKey: XXFGBEKTDJMLNJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.625
• 拓扑面积：
  17.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  咪唑 、 1-溴-5-氯戊烷 在 lithium hydride 作用下， 以 四氢呋喃 为溶剂， 生成 1-(3-chloropentyl)imidazole
  参考文献：
  名称：

  Facile synthesis of polymerized ionic liquids with high thermal stability

  摘要：

  Twelve main-chain-type polymerized ionic liquids that have alkylimidazolium cation units were prepared using simple synthetic processes. The polymers were prepared using the self-polymerization of a single monomer; no polymerization initiators were required. The thermal stability and solvent miscibility of these polymers were studied. Results show that the combined anions greatly influence the solubility and thermal stability of the polymers. Among these polymers, poly-alkylimidazolium bis(trifluoromethylsulfonyl)imide polymers exhibited the highest thermal stability (>400 degrees C), which makes them candidates for many applications. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.05.038

文献信息

• Facile synthesis of polymerized ionic liquids with high thermal stability
  作者：Yu-Nung Hsieh、Chun-Hsiung Kuei、Yu-Kai Chou、Chia-Chyuan Liu、Kuen-Lin Leu、Tasi-Hsiu Yang、Mei-Ying Wang、Wen-Yueh Ho

  DOI：10.1016/j.tetlet.2010.05.038

  日期：2010.7

  Twelve main-chain-type polymerized ionic liquids that have alkylimidazolium cation units were prepared using simple synthetic processes. The polymers were prepared using the self-polymerization of a single monomer; no polymerization initiators were required. The thermal stability and solvent miscibility of these polymers were studied. Results show that the combined anions greatly influence the solubility and thermal stability of the polymers. Among these polymers, poly-alkylimidazolium bis(trifluoromethylsulfonyl)imide polymers exhibited the highest thermal stability (>400 degrees C), which makes them candidates for many applications. (C) 2010 Elsevier Ltd. All rights reserved.