3-ethylnonane-2,4-dione | 81838-80-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-ethylnonane-2,4-dione
• 英文别名: 3-Ethyl-2,4-nonandione
• CAS: 81838-80-4
• 化学式: C₁₁H₂₀O₂
• 分子量: 184.279
• InChiKey: OEDNKOZDCXQOCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,4-壬烷二酮 、 碘乙烷 在 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 17.5h， 以42%的产率得到3-ethylnonane-2,4-dione
  参考文献：
  名称：

  Ethyl-Branched Aldehydes, Ketones, and Diketones from Caimans (Caiman and Paleosuchus; Crocodylia, Reptilia)

  摘要：

  Secretions from the paracloacal glands of alligators (Alligator spp.) and caimans (Caiman spp., Melanosuchus niger, and Paleosuchus spp.) were examined by GC-MS. The secretions of the common caiman (C. crocodilus), the broadsnouted caiman (C. latirostris), the yacare caiman (C. yacare), the dwarf caiman (P. palpebrosus), and the smooth-fronted caiman (P. trigonatus) yielded a new family of 43 aliphatic carbonyl compounds that includes aldehydes, ketones, and beta-diketones with an ethyl branch adjacent to the carbonyl group. The identification of these glandular components and the syntheses and stereochemical investigations of selected compounds are described.

  DOI：

  10.1021/np0600797

文献信息

• Palladium(ii)- and platinum(ii)-catalyzed addition of stabilized carbon nucleophiles to ethylene and propyleneElectronic supplementary information (ESI) available: experimental procedures, analytical and spectroscopic data for new compounds. See http://www.rsc.org/suppdata/cc/b3/b316734h/
  作者：Xiang Wang、Ross A. Widenhoefer

  DOI：10.1039/b316734h

  日期：——

  PdCl(2)(CH(3)CN)(2) and [PtCl(2)(H(2)C[double bond]CH(2))](2) catalyze the addition of beta-dicarbonyl compounds to ethylene and propylene.

  PdCl（2）（CH（3）CN）（2）和[PtCl（2）（H（2）C [双键] CH（2））]（2）催化将β-二羰基化合物添加到乙烯中并丙烯。
• Hooz, John; Oudenes, Jan, Synthetic Communications, 1982, vol. 12, # 3, p. 189 - 194
  作者：Hooz, John、Oudenes, Jan

  DOI：——

  日期：——
• Ethyl-Branched Aldehydes, Ketones, and Diketones from Caimans (<i>Caiman</i> and <i>Paleosuchus</i>; Crocodylia, Reptilia)
  作者：Karsten Krückert、Birte Flachsbarth、Stefan Schulz、Ute Hentschel、Paul J. Weldon

  DOI：10.1021/np0600797

  日期：2006.6.1

  Secretions from the paracloacal glands of alligators (Alligator spp.) and caimans (Caiman spp., Melanosuchus niger, and Paleosuchus spp.) were examined by GC-MS. The secretions of the common caiman (C. crocodilus), the broadsnouted caiman (C. latirostris), the yacare caiman (C. yacare), the dwarf caiman (P. palpebrosus), and the smooth-fronted caiman (P. trigonatus) yielded a new family of 43 aliphatic carbonyl compounds that includes aldehydes, ketones, and beta-diketones with an ethyl branch adjacent to the carbonyl group. The identification of these glandular components and the syntheses and stereochemical investigations of selected compounds are described.