1,2-di-sec-butoxy-ethane | 99868-09-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,2-di-sec-butoxy-ethane
• 英文别名: Aethylenglykol-di-sek.-butylaether；1,2-Di-sec-butoxy-aethan；2-(2-Butan-2-yloxyethoxy)butane
• CAS: 99868-09-4
• 化学式: C₁₀H₂₂O₂
• 分子量: 174.283
• InChiKey: GDKBMZHEWBEYRO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,2-Bis-<1-chlor-aethoxy>aethan 、 乙基溴化镁 在 乙醚 作用下， 生成 1,2-di-sec-butoxy-ethane
  参考文献：
  名称：

  Lichtenberger; Martin, Bulletin de la Societe Chimique de France, 1947, p. 474

  摘要：

  DOI：

文献信息

• POLYOL ETHERS AND PROCESS FOR MAKING THEM
  申请人：Tulchinsky Michael L.

  公开号：US20100048940A1

  公开（公告）日：2010-02-25

  New polyol ether compounds and a process for their preparation. The process comprises reacting a polyol, a carbonyl compound, and hydrogen in the presence of hydrogenation catalyst, to provide the polyol ether. The molar ratio of polyol to carbonyl compound in the process is greater than 5:1.

  新的聚醚醇化合物及其制备方法。该方法包括在氢化催化剂存在下，使聚醇、羰基化合物和氢发生反应，从而提供聚醚醇。在该过程中，聚醇与羰基化合物的摩尔比大于5:1。
• Cyanopyrimidinones
  申请人：Hendrix Martin

  公开号：US20080255118A1

  公开（公告）日：2008-10-16

  The invention relates to novel cyanopyrimidinones, process for their preparation, and the use thereof for producing medicaments for improving perception, concentration, learning and/or memory.

  本发明涉及新型的氰基嘧啶酮类化合物，其制备方法，以及将其用于生产改善感知、注意力、学习和/或记忆的药物的用途。
• METHOD FOR PURIFYING TETRAKIS(FLUOROARYL) BORATE/MAGNESIUM HALIDE, TETRAKIS(FLUOROARYL) BORATE/ETHER COMPLEX AND PROCESS FOR PREPARING THE SAME, AND PROCESS FOR PREPARING TETRAKIS(FLUOROARYL) BORATE DERIVATIVE
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP0913400A1

  公开（公告）日：1999-05-06

  A method for purifying Ar4 BMgX which comprises treating a tetrakis(fluoroaryl) borate/magnesium halide (Ar4BMgX) with (1) an alkaline (earth) metal salt of carboxylic acid, (2) an acid, (3) an acid and then an alkaline (earth) metal hydroxide, or (4) an acid and then an alkaline (earth) metal salt of carboxylic acid; and a process for preparing a tetrakis(fluoroaryl) borate derivative (Ar4BZ) which comprises reacting the treated Ar4BMgX with a compound capable of generating monovalent cationic species. The above purification method permits separation and removal of impurities contained in Ar4 BMgX in an efficient and simple manner. The invention also provides a tetrakis(fluoroaryl) borate/ether complex, a process for preparing the same, and a process for preparing a tetrakis(fluoroaryl) borate derivative (Ar4BZ) by using the ether complex and the compound capable of generating monovalent cationic species as starting compounds. The ether complex can be easily purified to a high purity and hence is suitable as an intermediate for the preparation of various tetrakis(fluoroaryl) borate derivatives.

  一种提纯 Ar4 BMgX 的方法，包括用(1)羧酸的碱(土)金属盐、(2)酸、(3)酸然后碱(土)金属氢氧化物或(4)酸然后羧酸的碱(土)金属盐处理四(氟芳基)硼酸盐/卤化镁(Ar4BMgX)；以及制备四（氟芳基）硼酸酯衍生物（Ar4BZ）的工艺，包括将处理过的 Ar4BMgX 与能够生成一价阳离子物种的化合物反应。上述纯化方法可以高效、简单地分离和去除 Ar4 BMgX 中所含的杂质。本发明还提供了一种四(氟芳基)硼酸酯/醚络合物、制备四(氟芳基)硼酸酯/醚络合物的工艺，以及以醚络合物和能够生成一价阳离子种类的化合物为起始化合物制备四(氟芳基)硼酸酯衍生物(Ar4BZ)的工艺。醚络合物很容易提纯到高纯度，因此适合用作制备各种四（氟芳基）硼酸酯衍生物的中间体。
• Tetrakis(fluoroaryl) borate/ether complexes and process for preparing the same
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP1400524A1

  公开（公告）日：2004-03-24

  The invention provides a tetrakis(fluoroaryl) borate/ether complex, and the process for preparing the same, The ether complex can be easily purified to a high purity and hence is suitable as an intermediate for the preparation of various tetrakis(fluoroaryl)borate derivatives.

  本发明提供了一种四(氟芳基)硼酸酯/醚络合物及其制备方法，该醚络合物很容易提纯到高纯度，因此适合作为制备各种四(氟芳基)硼酸酯衍生物的中间体。
• Process for preparing tetrakis (fluoroaryl) borate derivatives
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP1400525A1

  公开（公告）日：2004-03-24

  The invention provides a tetrakis(fluoroaryl) borate/ether complex, a process for preparing the same, and a process for preparing a tetrakis(fluoroaryl)borate derivative (Ar4BZ) by using the ether complex and the compound capable of generating monovalent cationic species as starting compounds. The ether complex can be easily purified to a high purity and hence is suitable as an intermediate for the preparation of various tetrakis(fluoroaryl)borate derivatives.

  本发明提供了一种四(氟芳基)硼酸酯/醚络合物、制备该络合物的工艺，以及使用该醚络合物和能够生成一价阳离子物种的化合物作为起始化合物制备四(氟芳基)硼酸酯衍生物(Ar4BZ)的工艺。醚络合物很容易提纯到高纯度，因此适合用作制备各种四（氟芳基）硼酸酯衍生物的中间体。