3-tert-butyldioxycarbonylacrylic acid | 1931-62-0

• 物质功能分类: 化学试剂 - 有机试剂 - 酯类
• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-tert-butyldioxycarbonylacrylic acid
• 英文别名: Tert-butyl peroxymaleic acid；4-tert-butylperoxy-4-oxobut-2-enoic acid
• CAS: 1931-62-0；24491-54-1
• 化学式: C₈H₁₂O₅
• 分子量: 188.18
• InChiKey: RQHGZNBWBKINOY-UHFFFAOYSA-N

物化性质

• 熔点：
  130-131 °C
• 沸点：
  260.8±42.0 °C(Predicted)
• 密度：
  1.185±0.06 g/cm3(Predicted)
• LogP：
  0.9 at 30℃
• 物理描述：
  This solid peroxide is sensitive to heat. Storage of this material must be done so with stringent temperature control measures. Its explosion hazard is also mitigated by mixing the peroxide with an inert solid.

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  72.8
• 氢给体数：
  1
• 氢受体数：
  5

安全信息

• 危险等级：
  5.2
• 危险品标志：
  O,Xn
• 危险类别码：
  R7
• 危险品运输编号：
  UN 3102
• 海关编码：
  2918990090
• 包装等级：
  II
• 危险类别：
  5.2
• 安全说明：
  S14A,S26,S3/7,S36/37/39

反应信息

• 作为反应物：
  描述：

  1,3-脱氢金刚烷 、 3-tert-butyldioxycarbonylacrylic acid 以 乙醚 为溶剂， 反应 0.67h， 以67%的产率得到1-adamantyl 3-tert-butyldioxycarbonylacrylate
  参考文献：
  名称：

  No; Butov; Mokhov, Russian Journal of Organic Chemistry, 1998, vol. 34, # 10, p. 1505 - 1506

  摘要：

  DOI：

文献信息

• LUBRICATING THERMOPLASTIC RESIN COMPOSITION, AND MOLDED PRODUCT THEREOF
  申请人：UMG ABS, Ltd.

  公开号：EP2837656A1

  公开（公告）日：2015-02-18

  [Object] To provide lubricating thermoplastic resin compositions that can give formed articles exhibiting excellent lubricating properties and surface appearance and maintaining the lubricating properties permanently. [Solution] The lubricating thermoplastic resin composition includes an acid-modified copolymer (A) of a monomer mixture including an aromatic vinyl and a vinyl cyanide, the copolymer having a carboxyl group in the molecular chain, and a functionalized lubricant (B) having, in the molecule, a functional group (B1) capable of reacting with the carboxyl group and a lubricating segment (B2) having lubricating properties. The composition may further include a graft copolymer (C) and/or an additional thermoplastic resin (D) other than the acid-modified copolymer (A).

  [目的]提供润滑性热塑性树脂组合物，该组合物可以使成形物品具有优异的润滑性能和表面外观，并能永久保持润滑性能。 [解决方案] 润滑热塑性树脂组合物包括一种酸改性共聚物（A），该共聚物的单体混合物包括芳香族乙烯基和乙烯基氰化物，共聚物的分子链中含有一个羧基，以及一种官能化润滑剂（B），该润滑剂的分子中含有一个能与羧基反应的官能团（B1）和一个具有润滑性能的润滑段（B2）。组合物还可进一步包括接枝共聚物 (C) 和/或除酸改性共聚物 (A) 之外的其他热塑性树脂 (D)。
• CLEANING COMPOSITIONS WITH AMPHIPHILIC GRAFT POLYMERS BASED ON POLYALKYLENE OXIDES AND VINYL ESTERS
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP2024479A1

  公开（公告）日：2009-02-18
• AMPHIPHILIC GRAFT POLYMERS BASED ON POLYALKYLENE OXIDES AND VINYL ESTERS
  申请人：BASF SE

  公开号：EP2029645A1

  公开（公告）日：2009-03-04
• STABILIZATION OF PARTICLES COATED WITH NON-AMPHOTERIC, QUATERNIZABLE AND WATER-SOLUBLE POLYMERS USING A DISPERSING COMPONENT
  申请人：BASF SE

  公开号：EP3557992A1

  公开（公告）日：2019-10-30
• LUBRICATING THERMOPLASTIC RESIN COMPOSITION AND FORMED ARTICLE THEREOF
  申请人：UMG ABS, LTD.,

  公开号：US20150057201A1

  公开（公告）日：2015-02-26

  [Object] To provide lubricating thermoplastic resin compositions that can give formed articles exhibiting excellent lubricating properties and surface appearance and maintaining the lubricating properties permanently. [Solution] The lubricating thermoplastic resin composition includes an acid-modified copolymer (A) of a monomer mixture including an aromatic vinyl and a vinyl cyanide, the copolymer having a carboxyl group in the molecular chain, and a functionalized lubricant (B) having, in the molecule, a functional group (B1) capable of reacting with the carboxyl group and a lubricating segment (B2) having lubricating properties. The composition may further include a graft copolymer (C) and/or an additional thermoplastic resin (D) other than the acid-modified copolymer (A).