2-(((1-phenyl-1H-tetrazol-5-yl)thio)methyl)isoindoline-1,3-dione | 83307-97-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 2-(((1-phenyl-1H-tetrazol-5-yl)thio)methyl)isoindoline-1,3-dione
• 英文别名: 1H-Isoindole-1,3(2H)-dione, 2-[[(1-phenyl-1H-tetrazol-5-yl)thio]methyl]-；2-[(1-phenyltetrazol-5-yl)sulfanylmethyl]isoindole-1,3-dione
• CAS: 83307-97-5
• 化学式: C₁₆H₁₁N₅O₂S
• 分子量: 337.362
• InChiKey: QEYKHGJBUOQEEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  106
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1-苯基-5-巯基四氮唑 、 O-phthalimidomethyl trichloroacetamidate 以 四氢呋喃 为溶剂， 以78%的产率得到2-(((1-phenyl-1H-tetrazol-5-yl)thio)methyl)isoindoline-1,3-dione
  参考文献：
  名称：

  Alkylation of thiols with trichloroacetimidates under neutral conditions

  摘要：

  Trichloroacetimidates are displaced with thiols to form the corresponding sulfides without the need for an added acid or base by simply heating the reactants in refluxing THF. This operationally simple procedure provides the corresponding sulfides in excellent yields with only the formation of the neutral trichloroacetamide as the side product. The imidate may also be formed in situ, allowing for a direct method for the formation of sulfides from alcohols. This reaction provides a general method for the synthesis of a variety of sulfides from inexpensive and readily available alcohol starting materials. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.12.042

文献信息

• Photographic elements and film units containing imidomethyl blocked
  申请人：Eastman Kodak Company

  公开号：US04350752A1

  公开（公告）日：1982-09-21

  Imidomethyl blocked photographic reagents are useful in photographic elements, film units and processes. The blocked photographic reagents have the structure: ##STR1## wherein: J represents ##STR2## X represents the atoms to complete a 5- or 6-membered ring or ring system; R represents hydrogen, alkyl or 1 to 4 carbon atoms or aryl of 6 to 12 carbon atoms; and PR represents the residue of an organic photographic reagent containing a heteroatom through which it is joined to the imidomethyl blocking group.

  Imidomethyl阻断的照相试剂在照相元素、胶片单元和过程中非常有用。这些阻断的照相试剂具有以下结构：##STR1##其中：J代表##STR2## X代表原子，以完成5-或6-成员环或环系统；R代表氢、烷基或1到4个碳原子或6到12个碳原子的芳基；PR代表有机照相试剂的残基，其含有一个杂原子，通过它与imidomethyl阻断基连接。
• Photographic elements containing blocked photographic reagents and processes employing same
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0056444A2

  公开（公告）日：1982-07-28

  lmidomethyl blocked photographic reagents are useful in photographic elements and processes. The blocked photographic reagents have the structure: wherein X represents the atoms to complete a 5- or 6- membered ring or ring system; R represents hydrogen, alkyl of 1 to 4 carbon atoms or aryl of 6 to 12 carbon atoms; and PR represents the residue of an organic photographic reagent containing a heteroatom through which it is joined to the imidomethyl blocking group.

  亚胺甲基封端感光试剂可用于感光元件和工艺中。 封端感光试剂具有以下结构：其中 X 代表原子，以完成 5 或 6 个成员的环或环系统；R 代表氢、1 至 4 个碳原子的烷基或 6 至 12 个碳原子的芳基；PR 代表含有杂原子的有机感光试剂的残留物，通过杂原子与亚胺甲基封端基团连接。
• Photographic element containing a 4-hydroxyalkyl-substituted 1-phenyl-3-pyrazolidinone electron transfer agent
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0134695A1

  公开（公告）日：1985-03-20

  Photographic elements, film units, processes and alkaline processing compositions are described wherein certain 4-hydroxyalkyl-substituted 1-phenyl-3-pyrazolidinones are employed as electron transfer agents in color image transfer materials. The silver halide electron transfer agents of precursors thereof have the formula: wherein: n is 1 or 2, R' represents an unsubstituted alkyl group of 1 to 6 carbon atoms, an unsubstituted or substituted aryl group of 6 to 10 carbon atoms, or an aralkyl group of 6 to 10 carbon atoms, R2 and R3 each independently represents hydrogen, an unsubstituted or substituted alkyl group of 1 to 6 carbon atoms, an unsubstituted or substituted aryl group of 6 to 10 carbon atoms, or an aralkyl group of 6 to 10 carbon atoms, R4 represents hydrogen or one or more alkyl or alkoxy groups having from 1 to 4 carbon atoms, methylenedioxy groups or ethylenedioxy groups, and R5 represents hydrogen or a hydrolyzable moiety.

  描述了摄影元件、胶片单元、工艺和碱性处理组合物，其中某些 4-羟基烷基取代的 1-苯基-3-吡唑烷酮被用作彩色图像转移材料中的电子转移剂。卤化银电子转移剂及其前体具有以下式子： 其中 n 是 1 或 2、 R' 代表 1 至 6 个碳原子的未取代烷基、6 至 10 个碳原子的未取代或取代芳基或 6 至 10 个碳原子的芳烷基、 R2 和 R3 各自独立地代表氢、1 至 6 个碳原子的未取代或取代的烷基、6 至 10 个碳原子的未取代或取代的芳基或 6 至 10 个碳原子的芳烷基、 R4 代表氢或一个或多个具有 1 至 4 个碳原子的烷基或烷氧基、亚甲基二氧基或亚乙基二氧基，以及 R5 代表氢或可水解基团。
• US4350752A
  申请人：——

  公开号：US4350752A

  公开（公告）日：1982-09-21
• US4471045A
  申请人：——

  公开号：US4471045A

  公开（公告）日：1984-09-11