1'-hydroxybicyclohexyl-2,3,2'-trione | 1007230-17-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1'-hydroxybicyclohexyl-2,3,2'-trione
• 英文别名: 3-(1-Hydroxy-2-oxocyclohexyl)cyclohexane-1,2-dione；3-(1-hydroxy-2-oxocyclohexyl)cyclohexane-1,2-dione
• CAS: 1007230-17-2
• 化学式: C₁₂H₁₆O₄
• 分子量: 224.257
• InChiKey: YZILVGJZVDQBMP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  71.4
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  二氯甲烷 、 1,2-环己二酮 在 四乙基氯化铵 作用下， 以42%的产率得到spiro[6,7-dihydro-5H-1,3-benzodioxine-4,2'-cyclohexane]-1',8-dione
  参考文献：
  名称：

  Electron transfer in the cathodic reduction of α-dicarbonyl compounds

  摘要：

  Electron transfer processes take place during the cathodic reduction, under an argon atmosphere, of different alpha-dicarbonyl substrates. Carboxylic acids or methylene diesters are obtained from benzil or furil after electron transfer to the oxygen in the air, during the workup, or after electron transfer to the solvent. Involving an electron transfer to dichloromethane, 2-hydroxy-2-hydroxymethyl-2H-acenaphtylen-1-one or benzo[1,3]dioxin-8-one are formed when acenaphthenequinone or 1,2-cyclohexanedione are, respectively, reduced. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2007.11.102

文献信息

• Electron transfer in the cathodic reduction of α-dicarbonyl compounds
  作者：Belén Batanero、Fructuoso Barba

  DOI：10.1016/j.tet.2007.11.102

  日期：2008.2

  Electron transfer processes take place during the cathodic reduction, under an argon atmosphere, of different alpha-dicarbonyl substrates. Carboxylic acids or methylene diesters are obtained from benzil or furil after electron transfer to the oxygen in the air, during the workup, or after electron transfer to the solvent. Involving an electron transfer to dichloromethane, 2-hydroxy-2-hydroxymethyl-2H-acenaphtylen-1-one or benzo[1,3]dioxin-8-one are formed when acenaphthenequinone or 1,2-cyclohexanedione are, respectively, reduced. (C) 2007 Elsevier Ltd. All rights reserved.