bicycloprop-1,2'-enyl | 77160-46-4

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: bicycloprop-1,2'-enyl
• 英文别名: 1-Cycloprop-2-en-1-ylcyclopropene
• CAS: 77160-46-4
• 化学式: C₆H₆
• 分子量: 78.1136
• InChiKey: YPIAVOCSMDTUCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  6
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  环戊二烯 、 bicycloprop-1,2'-enyl 反应 3.0h， 生成 (1R,2R,4R,5S,1'S,2'R,3'R,4'S,5'R)-[2,3']Bi[tricyclo[3.2.1.0^2,4]octyl]-6,6'-diene
  参考文献：
  名称：

  Synthesis of the bicyclopropenyls

  摘要：

  Bicyclopropenyls 1-3 have been synthesized by the vacuum gas-phase elimination of beta-halocyclopropylsilane precursors over solid fluoride. Bicycloprop-2-enyl 1 and bicycloprop-1,2'-enyl 2 were isolated and characterized using standard spectroscopic techniques whereas bicycloprop-1-enyl 3 could only be generated in situ and trapped by cyclopentadiene.

  DOI：

  10.1016/s0040-4020(01)89261-9
• 作为产物：
  描述：

  1-(2-chloro-1-trimethylsilyl-1-cyclopropyl)-2-chloro-3-trimethylsilylcyclopropane 在 四丁基氟化铵 作用下， 25.0 ℃ 、2.67 Pa 条件下， 生成 bicycloprop-1,2'-enyl
  参考文献：
  名称：

  Synthesis of the bicyclopropenyls

  摘要：

  Bicyclopropenyls 1-3 have been synthesized by the vacuum gas-phase elimination of beta-halocyclopropylsilane precursors over solid fluoride. Bicycloprop-2-enyl 1 and bicycloprop-1,2'-enyl 2 were isolated and characterized using standard spectroscopic techniques whereas bicycloprop-1-enyl 3 could only be generated in situ and trapped by cyclopentadiene.

  DOI：

  10.1016/s0040-4020(01)89261-9

文献信息

• Billups, Edward W.; Haley, Michael M., Angewandte Chemie, 1989, vol. 101, # 12, p. 1735 - 1737
  作者：Billups, Edward W.、Haley, Michael M.

  DOI：——

  日期：——
• Billups W. E., Haley Michael M., Boese Roland, Blaeser Dieter, Tetrahedron, 50 (1994) N 36, S 10693-10700
  作者：Billups W. E., Haley Michael M., Boese Roland, Blaeser Dieter

  DOI：——

  日期：——
• Synthesis of the bicyclopropenyls
  作者：W.E. Billups、Michael M. Haley、Roland Boese、Dieter Bläser

  DOI：10.1016/s0040-4020(01)89261-9

  日期：1994.1

  Bicyclopropenyls 1-3 have been synthesized by the vacuum gas-phase elimination of beta-halocyclopropylsilane precursors over solid fluoride. Bicycloprop-2-enyl 1 and bicycloprop-1,2'-enyl 2 were isolated and characterized using standard spectroscopic techniques whereas bicycloprop-1-enyl 3 could only be generated in situ and trapped by cyclopentadiene.