5-t-butyloxycyclo-octene | 92617-20-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-t-butyloxycyclo-octene
• 英文别名: (1Z)-5-[(2-methylpropan-2-yl)oxy]cyclooctene
• CAS: 92617-20-4
• 化学式: C₁₂H₂₂O
• 分子量: 182.306
• InChiKey: LCXIVBFTLHZPJQ-PLNGDYQASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  5-t-butyloxycyclo-octene 在 溴 作用下， 以 四氯化碳 为溶剂， 反应 0.25h， 以5%的产率得到trans-2-bromo-9-oxabicyclo<3.3.1>nonane
  参考文献：
  名称：

  Bloodworth, A. J.; Eggelte, Henny J., Journal of the Chemical Society. Perkin transactions I, 1984, # 5, p. 1009 - 1012

  摘要：

  DOI：
• 作为产物：
  描述：

  1,5-cis,cis-cyclooctadiene 、 叔丁醇 在 sodium hydroxide 、 sodium tetrahydroborate 、 mercury(II) trifluoroacetate 作用下， 生成 5-t-butyloxycyclo-octene
  参考文献：
  名称：

  Bloodworth, A. J.; Eggelte, Henny J., Journal of the Chemical Society. Perkin transactions I, 1984, # 5, p. 1009 - 1012

  摘要：

  DOI：

文献信息

• Process for producing a hydrogenated polymer
  申请人：Kuraray Co., Ltd.

  公开号：EP1241189A1

  公开（公告）日：2002-09-18

  The present invention provides an industrially advantageous process for producing a hydrogenated polymer comprising subjecting a polymer having an olefinic carbon-carbon double bond and hydroxy group and/or a functional group which is convertible into hydroxy group or convertible into hydroxymethyl group to hydrogenation under the presence of palladium on a basic activated carbon and/or platinum on a basic activated carbon. The process of the present invention can produce a hydrogenated polymer having hydroxy group and/or a functional group which is convertible into hydroxy group or convertible into hydroxymethyl group with high retention of a functional group and can achieve a high hydrogenation ratio together with good hydrogenation rate.

  本发明提供了一种生产氢化聚合物的具有工业优势的工艺，该工艺包括在碱性活性炭上的钯和/或碱性活性炭上的铂存在下，使具有烯烃碳碳双键和羟基和/或可转化为羟基或可转化为羟甲基的官能团的聚合物进行氢化。本发明的工艺可以生产出具有羟基和/或可转化为羟基或可转化为羟甲基的官能团的氢化聚合物，且官能团保留率高，氢化率高，氢化速率好。
• NOVEL POLYMER AND PROCESS FOR PRODUCING THE SAME
  申请人：KURARAY CO., LTD.

  公开号：EP1598384A1

  公开（公告）日：2005-11-23

  A polymer consisting mainly of structural units represented by the general formula (1), wherein the total molar amount of terminal aldehyde groups and acetal groups is 0.6 mol% or smaller based on the total molar amount of the structural units represented by the general formula (1). -[-(-CHR1-)n-CX1R2-CX2R3-]-(1) (In the formula, n is an integer of 2 to 10; X1 and X2 each represents -H, -OH, or a functional group capable of being converted into -OH, provided that at least one of X1 and X2 is hydroxy or a functional group capable of being converted into hydroxy; and R1, R2 and R3 each represents -H or C1-5 alkyl, aryl, aralkyl, or heteroaryl and the two or more R1's may be different).

  一种主要由通式(1)所代表的结构单元组成的聚合物，其中末端醛基和缩醛基的摩尔总量占通式(1)所代表的结构单元摩尔总量的 0.6 摩尔%或更小。-[-(-CHR1-)n-CX1R2-CX2R3-]-(1) （式中，n 为 2-10 的整数；X1 和 X2 各自代表-H、-OH 或可转化为-OH 的官能团，条件是 X1 和 X2 中至少有一个是羟基或可转化为羟基的官能团；R1、R2 和 R3 各自代表-H 或 C1-5 烷基、芳基、芳烷基或杂芳基，两个或多个 R1 可以不同）。
• POLYMER, AND SOLAR CELL SEALANT USING SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2781531A1

  公开（公告）日：2014-09-24

  Provided is a polymer from which an encapsulant excellent in weather resistance and processability can be obtained when being used for an encapsulant for a solar cell. The polymer that has a main chain comprising repeating units represented by formula (1) and repeating units represented by formula (2) and satisfies requirements (a1), (a2), and (a3), (a1) : the ratio of the number of the repeating units represented by formula (2) to the total number of the carbon atoms that constitute the main chain of the polymer is from 3.8% to 7.5%; (a2) : the ratio X represented by formula (3) is from 82% to 100%; X=100×A/B (a3) : the polymer has a melting point of 42°C to 90°C as measured with a differential scanning calorimeter.

  本发明提供了一种聚合物，用它制成的封装剂在用于太阳能电池的封装剂时可获得优异的耐候性和加工性。该聚合物的主链由式（1）表示的重复单元和式（2）表示的重复单元组成，并满足（a1）、（a2）和（a3）的要求、 (a1) 式(2)代表的重复单元数与构成聚合物主链的碳原子总数之比为 3.8%至 7.5%； (a2) 式(3)代表的比率 X 为 82%至 100%；X=100×A/B (a3) : 用差示扫描量热计测量，聚合物的熔点为 42°C 至 90°C。
• Novel polymer and process for producing the same
  申请人：Arimoto Kikuo

  公开号：US20060149009A1

  公开（公告）日：2006-07-06

  A polymer consisting mainly of structural units represented by the general formula (1), wherein the total molar amount of terminal aldehyde groups and acetal groups is 0.6 mol % or smaller based on the total molar amount of the structural units represented by the general formula (1). —[—(—CHR 1 —) n —CX 1 R 2 —CX 2 R 3 -]— (1) (In the formula, n is an integer of 2 to 10; X 1 and X 2 each represents —H, —OH, or a functional group capable of being converted into —OH, provided that at least one of X 1 and X 2 is hydroxy or a functional group capable of being converted into hydroxy; and R 1 , R 2 , and R 3 each represents —H or C 1-5 alkyl, aryl, aralkyl, or heteroaryl and the two or more R 1 's may be different.)

  一种主要由通式(1)所代表的结构单元组成的聚合物，其中末端醛基和缩醛基的摩尔总量占通式(1)所代表的结构单元摩尔总量的 0.6 摩尔%或更小。-[-(-CHR 1 -) n -CX 1 R 2 -CX 2 R 3 -]-(1)（式中，n 为 2 至 10 的整数；X 1 和 X 2 各自代表-H、-OH 或可转化为-OH 的官能团，条件是 X 1 和 X 2 是羟基或可转化为羟基的官能团；以及 R 1 , R 2 和 R 3 各自代表-H 或 C 1-5 烷基、芳基、芳烷基或杂芳基，而两个或多个 R 1 可以不同）。
• BLOODWORTH, A. J.;EGGELTE, H. J., J. CHEM. SOC. PERKIN TRANS., 1984, N 5, 1009-1012
  作者：BLOODWORTH, A. J.、EGGELTE, H. J.

  DOI：——

  日期：——