2-Methyl-acrylic acid 2-ethyl-2-methyl-[1,3]dioxolan-4-ylmethyl ester | 60262-67-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-Methyl-acrylic acid 2-ethyl-2-methyl-[1,3]dioxolan-4-ylmethyl ester
• 英文别名: (2-Ethyl-2-methyl-1,3-dioxolan-4-yl)methyl 2-methyl-2-propenoate；(2-ethyl-2-methyl-1,3-dioxolan-4-yl)methyl 2-methylprop-2-enoate
• CAS: 60262-67-1
• 化学式: C₁₁H₁₈O₄
• 分子量: 214.262
• InChiKey: XUSCPDAWOTWGBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲基丙烯酸缩水甘油酯 、 丁酮 在 三氯化铁 作用下， 以 正己烷 为溶剂， 反应 0.67h， 生成 2-Methyl-acrylic acid 2-ethyl-2-methyl-[1,3]dioxolan-4-ylmethyl ester
  参考文献：
  名称：

  Shevchuk; Gorokhova; Podgornova, Russian Journal of Applied Chemistry, 2000, vol. 73, # 5, p. 909 - 911

  摘要：

  DOI：

文献信息

• POLYSILANE COMPOUND AND SYNTHESIS METHOD, ULTRAVIOLET-RAY CURABLE INK COMPOSITION, INKJET RECORDING METHOD AND APPARATUS, AND INK CONTAINER
  申请人：NAKAZAWA Chiyoshige

  公开号：US20080200635A1

  公开（公告）日：2008-08-21

  The invention relates to a polysilane compound having a structure represented by the following formula 1 and an ultraviolet ray-curable ink composition containing the polysilane compound. Also, an inkjet recording method using the ultraviolet ray-curable ink composition and an ink container and an inkjet recording apparatus each containing the ultraviolet ray-curable ink composition therein are disclosed.

  本发明涉及一种具有以下式1表示的结构的聚硅烷化合物和含有该聚硅烷化合物的紫外线固化油墨组合物。此外，本发明还公开了使用该紫外线固化油墨组合物的喷墨记录方法，以及分别包含该紫外线固化油墨组合物的油墨容器和喷墨记录设备。
• Modeling Material For Forming Photofabrication Model In Ink-Jet Three Dimensional Printing, Supporting Material For Supporting The Shape Of Photofabrication Model On Photofabrication And Production Method Of Photofabrication Model
  申请人：KEYENCE CORPORATION

  公开号：US20130234370A1

  公开（公告）日：2013-09-12

  The present invention aims to provide a supporting material for supporting the shape of a photofabrication model on photofabrication in ink-jet three dimensional printing method in which the photocured product is excellent in solubility in water and is easy to remove after photofabrication, and the like. A modeling material for forming a photofabrication model in ink-jet three dimensional printing method containing a curable resin component with a weighted average of SP value of 9.0 to 10.3; and a supporting material for supporting the shape of a photofabrication model on photofabrication in ink-jet three dimensional printing method containing a water-soluble monofunctional ethylenically unsaturated monomer (F), polyoxypropylene glycol with a number average molecular weight of 100 to 5,000 and/or water (G), and a photopolymerization initiator (D).

  本发明旨在提供一种支撑材料，用于在喷墨三维打印中支撑光固化产物的形状，其中光固化产物在水中溶解性优异且易于在制造后移除。一种建模材料，用于在喷墨三维打印中形成光制造模型，包含具有SP值加权平均值在9.0至10.3之间的可固化树脂组分；和一种支撑材料，用于在喷墨三维打印中支撑光制造模型的形状，包含水溶性单官能团乙烯基不饱和单体（F）、分子量在100至5,000之间的聚氧丙烯醚醇和/或水（G）以及光聚合引发剂（D）。
• PROCESS FOR PRODUCING CONTACT LENS WITH HYDROPHILIC SURFACE AND CONTACT LENS OBTAINED THEREBY
  申请人：MENICON CO., LTD.

  公开号：EP0892297A1

  公开（公告）日：1999-01-20

  A process for producing a contact lens having a hydrophilic surface comprising subjecting a contact lens material comprising a copolymer prepared by copolymerizing a monomer mixture containing a polymerizable monomer (A) which is at least one member selected from a sugar ketal-containing (meth)acrylate and a sugar glycerol ketal-containing (meth)acrylate, and a polymerizable monomer (B) which is copolymerizable with the polymerizable monomer (A) to acid treatment, wherein the polymerizable monomer (B) contains a hydrophobic monomer which is at least one member selected from a silicon-containing monomer, a fluorine-containing monomer and a silicon- and fluorine-containing monomer, and a contact lens which has high oxygen permeability and of which surface shows stably excellent hydrophilic property and which is excellent in deposit resistance at the same time.

  一种生产具有亲水性表面的隐形眼镜的工艺，包括将隐形眼镜材料进行酸处理，该隐形眼镜材料包含通过共聚单体混合物制备的共聚物，该单体混合物包含可聚合单体(A)和可聚合单体(B)，可聚合单体(A)是至少一种选自含糖酮基(甲基)丙烯酸酯和含糖甘油酮基(甲基)丙烯酸酯的成员，可聚合单体(B)可与可聚合单体(A)共聚、其中，可聚合单体（B）含有一种疏水性单体，该疏水性单体至少选自含硅、含氟和含硅、含氟单体中的一种。
• Organosilicon compound
  申请人：Chisso Corporation

  公开号：EP1686133A2

  公开（公告）日：2006-08-02

  Since the majority of conventional organic/inorganic composite materials are obtained by mechanical blending of a silsesquioxane and an organic polymer or other means, it was extremely difficult to control the structure of the composite as a molecular agglomerate. In order to solve such a problem, the invention is to provide a silicon compound represented by Formula (1). This novel silicon compound has a living radical polymerization initiating ability for addition polymerizable monomers of a wide range. In Formula (1), R1 is hydrogen, an alkyl, an aryl, or an arylalkyl; R2 is an alkyl, phenyl, or cyclohexyl; and A is a group having a polymerization initiating ability for addition polymerizable monomers.

  由于传统的有机/无机复合材料大多是通过硅倍半氧烷和有机聚合物的机械混合或其他方式获得的，因此要控制复合材料的分子团聚结构极为困难。为了解决这一问题，本发明提供了一种由式（1）表示的硅化合物。这种新型硅化合物对范围广泛的可加成聚合单体具有活自由基聚合引发能力。在式（1）中，R1 是氢、烷基、芳基或芳烷基；R2 是烷基、苯基或环己基；A 是对可加成聚合单体具有聚合引发能力的基团。
• Ink composition, inkjet recording method, printed material, method for producing planographic printing plate, and planographic printing plate
  申请人：Fujifilm Corporation

  公开号：EP1803784A2

  公开（公告）日：2007-07-04

  The invention provides an ink composition having at least (A) a polymerization initiator, (B) an ester or amide of (meth)acrylic acid having a 1,3-dioxolane ring skeleton or a 1,3-dioxane ring skeleton or (B') an ester or amide of (meth)acrylic acid having a 1,3-diketone structure, and (C) a colorant. The invention further provides an inkjet recording method and a method for producing a planographic printing plate, each of which includes at least (I) ejecting the ink composition onto a hydrophilic support and (II) curing the ink composition by irradiating the ejected ink composition with active radiation so as to form a hydrophobic image region on the hydrophilic support. The invention furthermore provides a planographic printing plate formed by the method for producing a planographic printing plate.

  本发明提供了一种墨水组合物，它至少具有(A)聚合引发剂，(B)具有 1，3-二氧戊环骨架或 1，3-二氧六环骨架的(甲基)丙烯酸酯或酰胺，或(B')具有 1，3-二酮结构的(甲基)丙烯酸酯或酰胺，以及(C)着色剂。本发明进一步提供了一种喷墨记录方法和一种平面印刷板的制作方法，其中每种方法都至少包括：(I) 将墨水组合物喷射到亲水性支撑物上；(II) 用活性辐射照射喷射出的墨水组合物，使墨水组合物固化，从而在亲水性支撑物上形成疏水性图像区域。此外，本发明还提供了一种由该方法形成的平版印刷板。