2-((quinolin-8-yloxy)methyl)benzimidazole | 21054-64-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2-((quinolin-8-yloxy)methyl)benzimidazole
• 英文别名: 8-(1H-benzimidazol-2-ylmethoxy)quinoline
• CAS: 21054-64-8
• 化学式: C₁₇H₁₃N₃O
• 分子量: 275.31
• InChiKey: ZDSIGETWGZSWBK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  50.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-喹啉-8-氧乙酸 、 邻苯二胺 在 盐酸 作用下， 以 水 为溶剂， 反应 5.0h， 以9.81 g的产率得到2-((quinolin-8-yloxy)methyl)benzimidazole
  参考文献：
  名称：

  Syntheses, structures, and properties of copper and cadmium complexes with quinoline-based benzimidazole

  摘要：

  A new tridentate ligand 2-((quinolin-8-yloxy)methyl)benzimidazole (L) and three coordination compounds, [CuLCl2] (1), [CuL(H2O)(SO4) center dot 2H2O]n (2), and {[Cd2L2Cl4][CdLCl2(H2O)]2} center dot H2O (3), have been synthesized and characterized. Single crystal structure analyses reveal extensive intermolecular hydrogen bonding, resulting in generation of 1-D-3-D supramolecular networks. Compounds 1 and 2 constitute the first examples of Cu complexes containing both 8-hydroxyquinoline and benzimidazole, while 3 represents the first Cd complex bearing this ligand. Complexes 1-3 show similar quasi-reversible electrochemical behaviors. Complex 2 exhibits a predominantly ferromagnetic interaction between copper centers, and 3 has good fluorescence and can be used as an optical material.

  DOI：

  10.1080/00958972.2010.548862

文献信息

• Syntheses, structures, and properties of copper and cadmium complexes with quinoline-based benzimidazole
  作者：Yong-Hong Wen、Xing-Lei Xie、Lei Wang

  DOI：10.1080/00958972.2010.548862

  日期：2011.2.10

  A new tridentate ligand 2-((quinolin-8-yloxy)methyl)benzimidazole (L) and three coordination compounds, [CuLCl2] (1), [CuL(H2O)(SO4) center dot 2H2O]n (2), and [Cd2L2Cl4][CdLCl2(H2O)]2} center dot H2O (3), have been synthesized and characterized. Single crystal structure analyses reveal extensive intermolecular hydrogen bonding, resulting in generation of 1-D-3-D supramolecular networks. Compounds 1 and 2 constitute the first examples of Cu complexes containing both 8-hydroxyquinoline and benzimidazole, while 3 represents the first Cd complex bearing this ligand. Complexes 1-3 show similar quasi-reversible electrochemical behaviors. Complex 2 exhibits a predominantly ferromagnetic interaction between copper centers, and 3 has good fluorescence and can be used as an optical material.