ammonia*2(carbon dioxide) | 35701-49-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: ammonia*2(carbon dioxide)
• 英文别名: Ammonia carbon dioxide
• CAS: 35701-49-6
• 化学式: 2CO₂*H₃N
• 分子量: 105.05
• InChiKey: ZEYWAHILTZGZBH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.42
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  35.1
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  硬脂酸 、 ammonia*2(carbon dioxide) 、 氨 、 二氧化碳 、 锌 反应 18.0h， 生成 硬脂酸铵 、 ZINC stearate
  参考文献：
  名称：

  Metal Carboxylate Clays, Derivatives of Metal Carboxylate Clays, Methods for Making the Same, and Compositions Containing the Same

  摘要：

  本发明揭示了锌羧酸盐粘土和锌羧酸盐有机改性粘土的制备方法以及包含它们的组合物。该方法包括将锌粘土组合物与羧酸混合，或将羧酸与锌氨络合物溶液混合，然后将得到的锌羧酸盐与可离子交换粘土的浆料或悬浮液结合，以制备锌羧酸盐粘土。这些粘土可以进一步插层季铵盐，制成锌羧酸盐有机改性粘土。本发明的粘土可用于组合物中和/或作为橡胶和塑料配方和产品以及催化剂配方中的添加剂。

  公开号：

  US20120276316A1
• 作为产物：
  描述：

  二氧化碳 、 氨 以 gaseous matrix 为溶剂， 生成 氨基甲酸 、 (ammonia)2*carbon dioxide 、 ammonia*2(carbon dioxide)
  参考文献：
  名称：

  VUV irradiation of carbon dioxide (CO2) and ammonia (NH3) complexes in argon matrix

  摘要：

  In this study, we characterized by FTIR spectroscopy the 1:1 and 2:1 molecular complexes between NH3 and CO2 in argon matrix at low temperature. In addition we tentatively identified the 1:2 molecular complex. The structures of the complexes were established from B3LYP calculations. Moreover, we showed that the VUV irradiation of the 1:1 complex forms the NH2OH:CO complex. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.chemphys.2008.10.026

文献信息

• Metal Carboxylate Clays, Derivatives of Metal Carboxylate Clays, Methods for Making the Same, and Compositions Containing the Same
  申请人：NIP Raymond L.

  公开号：US20120276316A1

  公开（公告）日：2012-11-01

  Zinc carboxylate clays and zinc carboxylate organoclays, methods for their preparation, and compositions containing the same are disclosed. The methods comprise either mixing a zinc clay composition with a carboxylic acid, or mixing a carboxylic acid with a zinc ammonia complex solution, then combining the resulting zinc carboxylate salt with a slurry or suspension of a cation-exchangeable clay, to prepare the zinc carboxylate clay. These clays can be further intercalated with quaternary ammonium salts to make zinc carboxylate organoclays. The present clays may be used in compositions and/or as additives in rubber and plastic formulations and products and in catalyst formulations.

  本发明揭示了锌羧酸盐粘土和锌羧酸盐有机改性粘土的制备方法以及包含它们的组合物。该方法包括将锌粘土组合物与羧酸混合，或将羧酸与锌氨络合物溶液混合，然后将得到的锌羧酸盐与可离子交换粘土的浆料或悬浮液结合，以制备锌羧酸盐粘土。这些粘土可以进一步插层季铵盐，制成锌羧酸盐有机改性粘土。本发明的粘土可用于组合物中和/或作为橡胶和塑料配方和产品以及催化剂配方中的添加剂。
• VUV irradiation of carbon dioxide (CO2) and ammonia (NH3) complexes in argon matrix
  作者：J.B. Bossa、F. Duvernay、P. Theulé、F. Borget、T. Chiavassa

  DOI：10.1016/j.chemphys.2008.10.026

  日期：2008.12

  In this study, we characterized by FTIR spectroscopy the 1:1 and 2:1 molecular complexes between NH3 and CO2 in argon matrix at low temperature. In addition we tentatively identified the 1:2 molecular complex. The structures of the complexes were established from B3LYP calculations. Moreover, we showed that the VUV irradiation of the 1:1 complex forms the NH2OH:CO complex. (c) 2008 Elsevier B.V. All rights reserved.
• Metal carboxylate clays, derivatives of metal carboxylate clays, methods for making the same, and compositions containing the same
  申请人：Nip Raymond L.

  公开号：US08470727B2

  公开（公告）日：2013-06-25

  Zinc carboxylate clays and zinc carboxylate organoclays, methods for their preparation, and compositions containing the same are disclosed. The methods comprise either mixing a zinc clay composition with a carboxylic acid, or mixing a carboxylic acid with a zinc ammonia complex solution, then combining the resulting zinc carboxylate salt with a slurry or suspension of a cation-exchangeable clay, to prepare the zinc carboxylate clay. These clays can be further intercalated with quaternary ammonium salts to make zinc carboxylate organoclays. The present clays may be used in compositions and/or as additives in rubber and plastic formulations and products and in catalyst formulations.

  本发明公开了锌羧酸盐黏土和锌羧酸盐有机改性黏土的制备方法以及包含它们的组合物。该方法包括将锌黏土组成物与羧酸混合，或将羧酸与锌氨络合物溶液混合，然后将得到的锌羧酸盐与可离子交换黏土的浆液或悬浮液混合，制备锌羧酸盐黏土。这些黏土可以进一步插层季铵盐以制备锌羧酸盐有机改性黏土。本发明的黏土可用于组合物中和/或作为橡胶和塑料配方和产品以及催化剂配方中的添加剂。