5-methylhex-5-ene-1,4-diol | 100590-28-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 5-methylhex-5-ene-1,4-diol
• CAS: 100590-28-1
• 化学式: C₇H₁₄O₂
• 分子量: 130.187
• InChiKey: VGHPWUOREZZOPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5-methylhex-5-ene-1,4-diol 在 咪唑 、 正丁基锂 、 氯化亚砜 、 正己烷 、 水 、 calcium carbonate 、 碘甲烷 作用下， 以 四氯化碳 、 N,N-二甲基甲酰胺 为溶剂， 生成 (E)-12-(tert-Butyl-diphenyl-silanyloxy)-8-methyl-1-{2-[2-(2-methyl-[1,3]dioxolan-2-yl)-ethyl]-[1,3]dioxolan-2-yl}-dodec-8-en-4-yn-6-ol
  参考文献：
  名称：

  Rate enhancement of biomimetic polyene cyclizations by a cation-stabilizing auxiliary

  摘要：

  DOI：

  10.1021/ja00253a048

文献信息

• JOHNSON, WILLIAM S.;LINDELL, STEPHEN D.;STEELE, JOHN, J. AMER. CHEM. SOC., 109,(1987) N 19, 5852-5853
  作者：JOHNSON, WILLIAM S.、LINDELL, STEPHEN D.、STEELE, JOHN

  DOI：——

  日期：——
• [EN] RESIN COMPOSITION FOR OPTICAL PACKAGING MATERIAL AND PROCESS FOR PREPARING THE SAME, AND OPTICAL PACKAGING MATERIAL, OPTICAL PACKAGING COMPONENT, AND OPTICAL MODULE<br/>[FR] COMPOSITION DE RÉSINE POUR MATÉRIAU D'EMBALLAGE OPTIQUE ET PROCÉDÉ DE FABRICATION DE LADITE COMPOSITION, ET MATÉRIAU D'EMBALLAGE OPTIQUE, COMPOSANT D'EMBALLAGE OPTIQUE ET MODULE OPTIQUE
  申请人：NIPPON CATALYTIC CHEM IND

  公开号：WO2006038735A1

  公开（公告）日：2006-04-13

  To provide to a resin composition for an optical packaging material having a coefficient of thermal expansion approximately same as that of quartz and Pyrex (registered trade name) and capable of providing an optical packaging material exhibiting excellent flame retardancy and an optical packaging component, and an optical module and its production method. A molded body, an optical packaging component and an optical module having a low coefficient of thermal expansion and excellent flame retardancy can be obtained using a resin composition for an optical packaging material comprising a resin and inorganic fine particles which are made of a hydrolyzed condensate compound of an alkoxide compound and/or a carboxylic acid salt compound and have an average radius of gyration of 50 nm or smaller.
• Rate enhancement of biomimetic polyene cyclizations by a cation-stabilizing auxiliary
  作者：William S. Johnson、Stephen D. Lindell、John Steele

  DOI：10.1021/ja00253a048

  日期：1987.9