phthalonitrile-o-naphthalene | 175235-09-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: phthalonitrile-o-naphthalene
• 英文别名: 3-(1-naphthoxy)phthalonitrile；2-Cyano-3-(1-naphthyloxy)phenyl cyanide；3-naphthalen-1-yloxybenzene-1,2-dicarbonitrile
• CAS: 175235-09-3
• 化学式: C₁₈H₁₀N₂O
• 分子量: 270.29
• InChiKey: KGKLHQYMMGOOSZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  56.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  萘酚 、 3-硝基邻苯二腈 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以96.7%的产率得到phthalonitrile-o-naphthalene
  参考文献：
  名称：

  一种颜料衍生物及其制备方法、包含其的颜料组合物及其应用

  摘要：

  本发明公开了一种颜料衍生物，具有通式I所示结构，其中，M代表2H或金属原子，取代基团Q‑Ar表示刚性结构单元，Ar代表未取代的或者由烷基、烷氧基取代的芳香环、芳香杂环，Ar为刚性单元，Q代表刚性连接基团，X1‑X15代表氢原子、氯原子、溴原子或者Q‑Ar取代基团。本发明还提供了颜料衍生物的制备方法，含其的颜料组合物及其应用。本发明能够有效抑制颜料粒径团聚，且制得的颜料组合物具有粒径分布窄、易分散的优点，制成的色浆具有优异的透明性、着色性以及耐热性能。

  公开号：

  CN113755023A

文献信息

• The synthesis and fluorescence behaviour of phthalocyanines unsymmetrically substituted with naphthol and carboxy groups
  作者：Nolwazi Nombona、Edith Antunes、Tebello Nyokong

  DOI：10.1016/j.dyepig.2009.11.010

  日期：2010.6

  Unsymmetrically substituted phthalocyanines 8,15,22-tris-(naphtho)-2-(carboxy)phthalocyanine, [8,15,22-tris-(naphtho)-2-(carboxy)phthalocyanato]zinc(ii), 8,15,22-tris-(naphtho)-4,5-(3-carboxy-1,2-dioxyphenyl)phthalocyanine and [8,15,22-tris-(naphtho)-4,5-(3-carboxy-1,2-dioxyphenoxy)phthalocyanato]zinc(II) were prepared using the mixed phthalonitrile cyclotetramerization of 3-(1-naphthoxy) phthalonitrile with a carboxylic acid phthalonitrile. The phthalocyanines were separated using column chromatography employing a mixture of THF, ammonia and water. The novel compounds were characterized using UV-Vis, IR, H-1 NMR and mass spectrometry as well as elemental analysis. Fluorescence quantum yields were found to range from 0.05 to 0.16. (C) 2009 Elsevier Ltd. All rights reserved.
• RESIN BLENDS CONTAINING A PHTHALONITRILE REACTIVE DILUENT AND A DIPHTHALONITRILE RESIN, PREPREGS, AND ARTICLES
  申请人：3M Innovative Properties Company

  公开号：EP3601215A1

  公开（公告）日：2020-02-05
• [EN] RESIN BLENDS CONTAINING A PHTHALONITRILE REACTIVE DILUENT AND A DIPHTHALONITRILE RESIN, PREPREGS, AND ARTICLES<br/>[FR] MÉLANGES DE RÉSINES CONTENANT UN DILUANT RÉACTIF DE PHTALONITRILE ET UNE RÉSINE DE DIPHTALONITRILE, PRÉIMPRÉGNÉS ET ARTICLES
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2018175025A1

  公开（公告）日：2018-09-27

  The present disclosure provides a resin blend. The resin blend includes at least one diluent containing a single phthalonitrile functional group and at least one diphthalonitrile resin. Also provided are prepregs including the resin blend impregnated into continuous reinforcing fibers or a cloth. Similarly, the present disclosure provides a molding compound including chopped reinforcing fibers distributed in the resin blend. An article is also provided, which includes polymerization product of the resin blend. An alternative article includes a substrate and a layer of the resin blend disposed on the substrate. The diluent typically improves processability of the resin blend and lowers the softening temperature of the polymerization product of the resin blend.