ent-(1¹¹S,5R)-1¹β,1⁶α,1¹⁴-triacetoxy-1⁹β-(2-acetoxy-2-methyl-propionyloxy)-1^5,11-epoxy-1²β,1⁴,1⁸β-trihydroxy-5r,6t-dimethyl-(1³βH,1⁷βH)-2,8-dioxa-1(12,3)-eudesmana-4(3,2)-pyridina-cyclooctaphane-3,7-dione | 73257-66-6

• 分子结构分类: 有机化合物 - 生物碱及其衍生物
• 英文名称: ent-(1¹¹S,5R)-1¹β,1⁶α,1¹⁴-triacetoxy-1⁹β-(2-acetoxy-2-methyl-propionyloxy)-1^5,11-epoxy-1²β,1⁴,1⁸β-trihydroxy-5r,6t-dimethyl-(1³βH,1⁷βH)-2,8-dioxa-1(12,3)-eudesmana-4(3,2)-pyridina-cyclooctaphane-3,7-dione
• 英文别名: O⁹-(2-acetoxy-2-methyl-propionyl)-8α-hydroxy-O²,O⁹-dideacetyl-8-deoxo-evonine
• CAS: 73257-66-6
• 化学式: C₃₈H₄₉NO₁₈
• 分子量: 807.803
• InChiKey: LXVNRTHBMHPEGQ-UIQLGXSOSA-N

物化性质

• 沸点：
  864.0±65.0 °C(Predicted)
• 密度：
  1.42±0.1 g/cm3(Predicted)

反应信息

• 作为产物：
  描述：

  ent-(1¹¹S,5R)-1¹β,1⁶α,1⁸β,1¹⁴-tetraacetoxy-1⁹β-(2-acetoxy-2-methyl-propionyloxy)-1^5,11-epoxy-1²β,1⁴-dihydroxy-5r,6t-dimethyl-(1³βH,1⁷βH)-2,8-dioxa-1(12,3)-eudesmana-4(3,2)-pyridina-cyclooctaphane-3,7-dione 在 甲醇 、 二乙胺 作用下， 生成 ent-(1¹¹S,5R)-1¹β,1⁶α,1¹⁴-triacetoxy-1⁹β-(2-acetoxy-2-methyl-propionyloxy)-1^5,11-epoxy-1²β,1⁴,1⁸β-trihydroxy-5r,6t-dimethyl-(1³βH,1⁷βH)-2,8-dioxa-1(12,3)-eudesmana-4(3,2)-pyridina-cyclooctaphane-3,7-dione
  参考文献：
  名称：

  Crombie,L. et al., Journal of the Chemical Society. Perkin transactions I, 1979, p. 2976 - 2981

  摘要：

  DOI：