N-{(2S,3R,4R,5S,6R)-2-[(1S,2R,3S)-1-((R)-1,2-Dimethoxy-ethyl)-2,4-dimethoxy-3-(methyl-propionyl-amino)-butoxy]-4,5-dimethoxy-6-methoxymethyl-tetrahydro-pyran-3-yl}-N-methyl-propionamide | 110920-89-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: N-{(2S,3R,4R,5S,6R)-2-[(1S,2R,3S)-1-((R)-1,2-Dimethoxy-ethyl)-2,4-dimethoxy-3-(methyl-propionyl-amino)-butoxy]-4,5-dimethoxy-6-methoxymethyl-tetrahydro-pyran-3-yl}-N-methyl-propionamide
• CAS: 110920-89-3
• 化学式: C₂₇H₅₂N₂O₁₁
• 分子量: 580.717
• InChiKey: RCDPNYLJKJTAQZ-ZCPHWGFMSA-N

反应信息

• 作为产物：
  描述：

  methylated di-N-acetylchitobi-itol 、 碘甲烷 在 dimsyl potassium 作用下， 生成 N-{(2S,3R,4R,5S,6R)-2-[(1S,2R,3S)-3-(Acetyl-methyl-amino)-1-((R)-1,2-dimethoxy-ethyl)-2,4-dimethoxy-butoxy]-4,5-dimethoxy-6-methoxymethyl-tetrahydro-pyran-3-yl}-N-methyl-propionamide 、 N-{(2S,3R,4R,5S,6R)-2-[(1S,2R,3S)-1-((R)-1,2-Dimethoxy-ethyl)-2,4-dimethoxy-3-(methyl-propionyl-amino)-butoxy]-4,5-dimethoxy-6-methoxymethyl-tetrahydro-pyran-3-yl}-N-methyl-propionamide 、 N-{(1S,2R,3S,4R)-3-[(2S,3R,4R,5S,6R)-4,5-Dimethoxy-6-methoxymethyl-3-(methyl-propionyl-amino)-tetrahydro-pyran-2-yloxy]-2,4,5-trimethoxy-1-methoxymethyl-pentyl}-N-methyl-isobutyramide 、 N-{(2S,3R,4R,5S,6R)-2-[(1S,2R,3S)-1-((R)-1,2-Dimethoxy-ethyl)-2,4-dimethoxy-3-(methyl-propionyl-amino)-butoxy]-4,5-dimethoxy-6-methoxymethyl-tetrahydro-pyran-3-yl}-N-methyl-isobutyramide
  参考文献：
  名称：

  2-deoxy-1,3,4,5,6-penta-O-methyl-2-(N-methylacetamido)-d-glucitol and derivatives undergo C-emthylation at the N-methylacetamido group on repeated hakomori methylation

  摘要：

  DOI：

  10.1016/s0008-6215(00)90289-1