3,5-bis-(p-t-butylphenyl)pyrazole | 152503-09-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 3,5-bis-(p-t-butylphenyl)pyrazole
• CAS: 152503-09-8
• 化学式: C₂₃H₂₈N₂
• 分子量: 332.489
• InChiKey: KUUNBZLXSVAQHD-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  3,5-bis-(p-t-butylphenyl)pyrazole 以 水 为溶剂， 生成
  参考文献：
  名称：

  The synthesis of [HB]3,5-(Butph)2pz]3]− (Butph = p-C6H4But), a new tris(pyrazolyl)hydroborato ligand: the crystal and molecular structure of Tl{η3-HB[3,5-(Butph)2pz]3}

  摘要：

  The synthesis of a new sterically demanding tris(pyrazolyl)hydroborato ligand, [HB[3,5-(Bu(t)ph)2pz]3]- (Bu(t)ph = para-C6H4Bu(t)), is reported. The potassium derivative is prepared by the direct reaction of KBH4 with 3,5-bis(para-tert-butylphenyl)pyrazole. Metathesis with TlNO3 Converts the potassium derivative to the thallium complex Tl{eta3-HB[3,5-)Bu(t)ph)2pz]3}. The crystal and molecular structures of the pyrazole derivative [3,5-(Bu(t)ph)2pz]2ZnI2 and the thallium derivative Tl{eta3-HB[3,5-(Bu(t)ph)2pz]3} have been determined.

  DOI：

  10.1016/s0277-5387(00)83081-8