trans-{Ru(NH3)4(triethylphosphine)(pyrazine)}(2+) | 115862-41-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: trans-{Ru(NH3)4(triethylphosphine)(pyrazine)}(2+)
• CAS: 115862-41-4
• 化学式: C₁₀H₃₁N₆PRu
• 分子量: 367.44
• InChiKey: TVLIKIFPHXPWKD-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  吡嗪 、 trans-{Ru(NH3)4(triethylphosphine)(H2O)}(2+) 以 三氟乙酸 为溶剂， 生成 trans-{Ru(NH3)4(triethylphosphine)(pyrazine)}(2+)
  参考文献：
  名称：

  Ruthenium(II) tetraammines, a useful model to compare trans-effect and trans-influence of phosphanes

  摘要：

  DOI：

  10.1016/s0020-1693(00)82016-2

文献信息

• Trans-effect and trans-influence series for phosphanes in octahedral environment: A guide for design of new catalysts
  作者：José Cardoso do Nascimento Filho、Joacy Batista de Lima、Benedito dos Santos Lima Neto、Douglas Wagner Franco

  DOI：10.1016/0304-5102(94)00018-2

  日期：1994.6

  By a kinetic approach, the trans-effects and trans-influences of nineteen tertiary phosphane ligands were evaluated for a hexacoordinated d6-low spin metal center. Plots of specific rate constants versus formal potentials for Ru(III)/Ru(II) couples provide a simple, reliable and efficient method to predict phosphane reactivity and are useful as a guide for design of new catalysts.