Ru2(N,N'-dimethyl-3-methoxybenzamidinate)4(NO3)2 | 610784-53-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Ru2(N,N'-dimethyl-3-methoxybenzamidinate)4(NO3)2
• 英文别名: (O2NO)2Ru2(MeNCNMe(C6H4(3-MeO)))4
• CAS: 610784-53-7
• 化学式: C₄₀H₅₂N₁₀O₁₀Ru₂
• 分子量: 1035.05
• InChiKey: LCMCHHAUHRGTJW-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  1-ferrocenyl-6-(triethylsilyl)-1,3,5-hexatriyne 、 Ru2(N,N'-dimethyl-3-methoxybenzamidinate)4(NO3)2 在 K₂CO₃ 、 triethylamine 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 以90%的产率得到Ru2(N,N'-dimethyl-3-methoxybenzamidinate)4(6-ferrocenyl-1,3,5-hexatriynyl)2*3H2O
  参考文献：
  名称：

  Diruthenium Complexes of Axial Ferrocenyl−Polyynyl Ligands: The Cases of C₆Fc and C₈Fc

  摘要：

  Four Ru-2(Y-DMBA)(4)(C(2n)Fc)(2) type compounds with n = 3, 4 and Y-DMBA = N,N'-dimethylbenzamidinate, N,N'-dimethyl-3-methoxybenzamidinate were prepared using a weak-base protocol and characterized using voltammetry and single crystal X-ray, diffraction. Structural studies yielded Fc-Fc (edge-edge) separations of 22.0 and 27.1 angstrom for n = 3, 4, respectively. The potential differences between two Fc oxidation couples were determined via voltammetric studies as 0.24 and 0.22 V for n = 3, 4, respectively, implying the retention of strong interferrocene electronic couplings over extended distances.

  DOI：

  10.1021/om801227q

文献信息

• Linear Trimer of Diruthenium Linked by Butadiyn-Diyl Units: A Unique Electronic Wire
  作者：Jie-Wen Ying、Isiah Po-Chun Liu、Bin Xi、You Song、Charles Campana、Jing-Lin Zuo、Tong Ren

  DOI：10.1002/anie.200904674

  日期：2010.1.25

  Ru communicating? Butadiyn‐diyl bridges link three Ru2 moieties together to give a molecular wire (see structure, red Ru, green C, blue N, purple O). Voltammetric, spectroscopic, and magnetic data all point to extensive electronic delocalization across the linear trimer.

  茹沟通？Butadiyn-diyl桥将三个Ru 2部分连接在一起以形成分子线（参见结构，红色Ru，绿色C，蓝色N，紫色O）。伏安，光谱和磁数据都表明整个线性三聚体发生了广泛的电子离域。