1-ferrocenyl-6-(triethylsilyl)-1,3,5-hexatriyne | 1141934-50-0

• 英文名称: 1-ferrocenyl-6-(triethylsilyl)-1,3,5-hexatriyne
• CAS: 1141934-50-0
• 化学式: C₂₂H₂₄FeSi
• 分子量: 372.365
• InChiKey: KJXJHFRLBFDNEG-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  Ru₂(N,N′-dimethylbenzamidinate)₄(NO₃)₂ 、 1-ferrocenyl-6-(triethylsilyl)-1,3,5-hexatriyne 在 K₂CO₃ 、 triethylamine 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 以96%的产率得到Ru2(N,N'-dimethylbenzamidinate)4(6-ferrocenyl-1,3,5-hexatriynyl)2
  参考文献：
  名称：

  Diruthenium Complexes of Axial Ferrocenyl−Polyynyl Ligands: The Cases of C₆Fc and C₈Fc

  摘要：

  Four Ru-2(Y-DMBA)(4)(C(2n)Fc)(2) type compounds with n = 3, 4 and Y-DMBA = N,N'-dimethylbenzamidinate, N,N'-dimethyl-3-methoxybenzamidinate were prepared using a weak-base protocol and characterized using voltammetry and single crystal X-ray, diffraction. Structural studies yielded Fc-Fc (edge-edge) separations of 22.0 and 27.1 angstrom for n = 3, 4, respectively. The potential differences between two Fc oxidation couples were determined via voltammetric studies as 0.24 and 0.22 V for n = 3, 4, respectively, implying the retention of strong interferrocene electronic couplings over extended distances.

  DOI：

  10.1021/om801227q