palladium(II) 3,7,13,17-tetramethyl-2,8,12,18-tetrabutyl-5,15-di(4-bromophenyl)porphyrinate | 1186419-35-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: palladium(II) 3,7,13,17-tetramethyl-2,8,12,18-tetrabutyl-5,15-di(4-bromophenyl)porphyrinate
• CAS: 1186419-35-1
• 化学式: C₅₂H₅₈Br₂N₄Pd
• 分子量: 1005.29
• InChiKey: UAJQMBWIJZMXNI-ZQHHVVFUSA-N

反应信息

• 作为反应物：
  描述：

  palladium(II) 3,7,13,17-tetramethyl-2,8,12,18-tetrabutyl-5,15-di(4-bromophenyl)porphyrinate 、 nickel dichloride 以 N,N-二甲基甲酰胺 为溶剂， 反应 0.05h， 以75%的产率得到nickel(II) 3,7,13,17-tetramethyl-2,8,12,18-tetrabutyl-5,15-bis(4bromophenyl)porphyrinate
  参考文献：
  名称：

  Synthesis and spectral properties of meso-substituted Ni2+ octaalkylporphyrinates

  摘要：

  Nickel(II) 3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrinate and its 5,15-diaza, -diphenyl, and -di(4-bromophenyl) derivatives have been synthesized by the reaction of nickel(II) chloride with corresponding tetrapyrrole ligands in dimethylformamide.

  DOI：

  10.1134/s0036023613050069
• 作为产物：
  描述：

  3,7,13,17-tetramethyl-2,8,12,18-tetrabutyl-5,15-di(4-bromophenyl)porphyrine 、 palladium dichloride 以 N,N-二甲基甲酰胺 为溶剂， 以76%的产率得到palladium(II) 3,7,13,17-tetramethyl-2,8,12,18-tetrabutyl-5,15-di(4-bromophenyl)porphyrinate
  参考文献：
  名称：

  Palladium(II) octaalkylporphyrinates: Synthesis and spectral properties

  摘要：

  Palladium 3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrinate (I) and its 5,15-diaza (II), diphenyl (III), and di(4-bromophenyl) (IV) derivatives were synthesized by the complex formation reaction of palladium(II) chloride with corresponding tetrapyrrole ligands in dimethylformamide, and their spectral properties were studied.

  DOI：

  10.1134/s003602360809009x