N,N'-dinitro-N,N'-bis(2-nitroxyethyl)-1,2,4,5-tetrazine-3,6-diamine | 1588874-01-4

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: N,N'-dinitro-N,N'-bis(2-nitroxyethyl)-1,2,4,5-tetrazine-3,6-diamine
• CAS: 1588874-01-4
• 化学式: C₆H₈N₁₀O₁₀
• 分子量: 380.191
• InChiKey: BCEMLTJMHQMQMS-UHFFFAOYSA-N

物化性质

• 沸点：
  648.9±65.0 °C(predicted)
• 密度：
  1.880±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

反应信息

• 作为反应物：
  描述：

  N,N'-dinitro-N,N'-bis(2-nitroxyethyl)-1,2,4,5-tetrazine-3,6-diamine 在 水 作用下， 以 氘代二甲亚砜 为溶剂， 生成 2-[nitro(6-{[2-(nitroxy)ethyl]amino}-1,2,4,5-tetrazin-3-yl)amino]ethyl nitrate
  参考文献：
  名称：

  Synthesis and Properties of Alkylnitramino-1,2,4,5-Tetrazines

  摘要：

  The peculiarities of the nitration reaction under acidic conditions were studied for a series of alkylamino-1,2,4,5-tetrazines. It was found that the extent of N,N'-dialkyl-1,2,4,5-tetrazine-3,6-diamine nitration was determined by the concentration of nitric acid and the selection of alkyl substituents at the exocyclic nitrogen atom. A new method was developed for the preparation of unsymmetrically substituted N,N'-dialkyl-1,2,4,5-tetrazine-3,6-diamines from N-nitro derivatives of N-alkyl-1,2,4,5-tetrazin-3-amines.

  DOI：

  10.1007/s10593-014-1448-9
• 作为产物：
  描述：

  3,6-bis(hydroxyethylamino)-1,2,4,5-tetrazine 在 硝酸 作用下， 以45%的产率得到N,N'-dinitro-N,N'-bis(2-nitroxyethyl)-1,2,4,5-tetrazine-3,6-diamine
  参考文献：
  名称：

  Synthesis and Properties of Alkylnitramino-1,2,4,5-Tetrazines

  摘要：

  The peculiarities of the nitration reaction under acidic conditions were studied for a series of alkylamino-1,2,4,5-tetrazines. It was found that the extent of N,N'-dialkyl-1,2,4,5-tetrazine-3,6-diamine nitration was determined by the concentration of nitric acid and the selection of alkyl substituents at the exocyclic nitrogen atom. A new method was developed for the preparation of unsymmetrically substituted N,N'-dialkyl-1,2,4,5-tetrazine-3,6-diamines from N-nitro derivatives of N-alkyl-1,2,4,5-tetrazin-3-amines.

  DOI：

  10.1007/s10593-014-1448-9