Zn(II)-5,15-bis(4-hydroxyphenyl)-10,20-bis(4-cyanophenyl)porphyrin | 1252590-45-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Zn(II)-5,15-bis(4-hydroxyphenyl)-10,20-bis(4-cyanophenyl)porphyrin
• CAS: 1252590-45-6
• 化学式: C₄₆H₂₆N₆O₂Zn
• 分子量: 760.141
• InChiKey: XXSUJBHQVWKZSX-XZWYRLAVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Zn(II)-5,15-bis(4-hydroxyphenyl)-10,20-bis(4-cyanophenyl)porphyrin 、 三乙二醇单对甲苯磺酸酯 在 caesium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 26.0h， 以57.5%的产率得到Zn(II)-5,15-bis(4-(2-(2-(2-hydroxyethoxy)ethoxy)ethoxy)phenyl)-10,20-bis(4-cyanophenyl)porphyrin
  参考文献：
  名称：

  Boronic Acid Porphyrin Receptor for Ginsenoside Sensing

  摘要：

  Ginsenoside detection was pursued through the design of a porphyrin receptor containing two boronic acid units. This receptor was found to undergo different degrees of fluorescence quenching with five ginsenoside guests and an acylated derivative. The trends in the 1:1 binding constants, as well as ESI-HRMS analysis, support a binding mode in which the ginsenoside sugar units are bound to the boronic acid groups, while the steroid core and porphyrin ring participate in hydrophobic interactions.

  DOI：

  10.1021/ol1019647
• 作为产物：
  描述：

  在 zinc diacetate 作用下， 以 甲醇 、 氯仿 为溶剂， 反应 0.5h， 以421.5 mg的产率得到Zn(II)-5,15-bis(4-hydroxyphenyl)-10,20-bis(4-cyanophenyl)porphyrin
  参考文献：
  名称：

  Boronic Acid Porphyrin Receptor for Ginsenoside Sensing

  摘要：

  Ginsenoside detection was pursued through the design of a porphyrin receptor containing two boronic acid units. This receptor was found to undergo different degrees of fluorescence quenching with five ginsenoside guests and an acylated derivative. The trends in the 1:1 binding constants, as well as ESI-HRMS analysis, support a binding mode in which the ginsenoside sugar units are bound to the boronic acid groups, while the steroid core and porphyrin ring participate in hydrophobic interactions.

  DOI：

  10.1021/ol1019647