2-cyclohexylethyl acrylate | 111166-34-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-cyclohexylethyl acrylate
• 英文别名: 2-Cyclohexylethyl prop-2-enoate
• CAS: 111166-34-8
• 化学式: C₁₁H₁₈O₂
• 分子量: 182.263
• InChiKey: VZFZCAUMZFZJRS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-cyclohexylethyl acrylate 、 N-(3-methoxyphenyl)isobutyramide 在 tetrakis(acetonitrile)palladium(II) tetrafluoroborate 、 silver nitrate 、 对苯醌 作用下， 以 水 为溶剂， 反应 20.0h， 以77%的产率得到
  参考文献：
  名称：

  室温下阳离子 Pd(II)-催化的 Fujiwara-Moritani 反应在水中

  摘要：

  Pd II催化的藤原-森谷反应可以在室温和水作为唯一介质的情况下在没有外部酸的情况下进行。高活性阳离子 Pd II催化剂 [Pd(MeCN) 4 ](BF 4 ) 2 可轻松激活芳香族 C-H 键，从而以良好的收率生产富含电子的肉桂酸酯。

  DOI：

  10.1021/ol100331h

文献信息

• Acrylic-based adhesive composition
  申请人：——

  公开号：US20040013614A1

  公开（公告）日：2004-01-22

  An Adhesive composition for us in surgery, especially ophthalmic surgery, comprises a mixture of a cyanoacrylate of general formula (I) and an acrylate compound of formula (II) where R4 is an alkylene group and Y is a cycloalkyl group or Y═OR where R═H or acryloyl. It is found that compositions of this type have a number of advantages over simple cyanoacrylate adhesives, including: (a) a longer cure time, allowing easier handling of the joint; (b) a more flexible cured product; (c) a tendency for the cured to come away from the tissue after a month or so thus facilitating healing; and (d) a substantially non-exothermic curing reaction, thereby avoiding thermal damage to the tissue. 1

  一种用于手术，特别是眼科手术的粘合剂组合物，包括一种通式（I）的氰基丙烯酸酯和一种式（II）的丙烯酸酯化合物的混合物，其中R4是一种烷基基团，Y是一个环烷基团或Y═OR，其中R═H或丙烯酰基。发现这种类型的组合物比单纯的氰基丙烯酸酯粘合剂具有许多优点，包括：（a）较长的固化时间，使接头更易于处理；（b）固化后的产品更具有弹性；（c）固化后易于从组织中脱离，从而促进愈合；和（d）固化反应基本上是非放热的，从而避免对组织的热损伤。1
• CURABLE COMPOSITION FOR IMPRINTS, PATTERNING METHOD AND PATTERN
  申请人：Kodama Kunihiko

  公开号：US20110236595A1

  公开（公告）日：2011-09-29

  Provided is a curable composition for imprints having good patternability and dry etching resistance. Disclosed is a curable composition for imprints comprising a polymerizable monomer (Ax) having a substituent having an aromatic group and having a molecular weight of 100 or more, and a photopolymerization initiator.

  提供了一种可治愈的组合物，用于具有良好图案性和干法蚀刻抵抗力的印迹。公开了一种可治愈的印迹组合物，包括具有芳香基取代基并具有分子量为100或更高的聚合单体（Ax）和光聚合引发剂。
• Tertiary-butyl acrylate polymers and their use in photoresist compositions
  申请人：Arch Specialty Chemicals, Inc.

  公开号：EP1152295A1

  公开（公告）日：2001-11-07

  A photosensitive resist composition comprising: a polymer of tertiary-butyl acrylate having monomeric units of: where 0.5≤a≤0.7; 0.15≤b≤0.3; 0.1≤c≤0.2; 0.3

  一种光敏抗蚀剂组合物，包括 一种丙烯酸叔丁酯聚合物，其单体单元包括 其中 0.5≤a≤0.7; 0.15≤b≤0.3; 0.1≤c≤0.2; 0.3四氢呋喃基团 光酸发生器 溶剂；以及 可选的碱性化合物。
• HIGH VISCOSITY INDEX COMB POLYMER VISCOSITY MODIFIERS AND METHODS OF MODIFYING LUBRICANT VISCOSITY USING SAME
  申请人：Infineum International Limited

  公开号：EP3839017A1

  公开（公告）日：2021-06-23

  A comb copolymer viscosity modifier may be made by polymerization comprising at least, or consisting essentially of, the following monomers: (a) a hydrogenated polybutadiene-based (alk)acrylate ester macromonomer (which repeat units may comprise from 7.0 wt% to 18 wt% of the repeat units of the comb copolymer viscosity modifier); (b) a C3-C8 alkyl (alk)acrylate ester monomer (which repeat units may comprise from 40 wt% to 71 wt% or from 45 wt% to 64 wt% of the repeat units of the comb copolymer viscosity modifier); and (c) a C12-C24 alkyl (alk)acrylate ester monomer, wherein repeat units based on the C12-C24 alkyl (alk)acrylate ester monomer comprise at least 21.0 wt% (and optionally up to 35.0 wt%) of repeat units of the comb copolymer viscosity modifier. Lubricant compositions comprising the comb copolymer viscosity modifier, as well as uses thereof and methods for modifying viscosity, are also contemplated herein.

  梳状共聚物粘指剂可通过聚合制成，至少或主要由以下单体组成：(a) 氢化聚丁二烯基（烷基）丙烯酸酯大单体（其重复单元可占梳状共聚物粘指剂重复单元的 7.0 wt% 至 18 wt%）；(b) C3-C8 烷基（烷基）丙烯酸酯单体（其重复单元可占梳状共聚物粘指剂重复单元的 7.(b) C3-C8 烷基(烷基)丙烯酸酯单体(其重复单元可占梳状共聚物粘指剂重复单元的 40% 至 71% 或 45% 至 64%)；(c) C12-C24 烷基(烷基)丙烯酸酯单体，其中基于 C12-C24 烷基(烷基)丙烯酸酯单体的重复单元占至少 21.0 wt%（可选最多 35.0 wt%）的组合共聚物粘指剂重复单元。本文还考虑了包含梳状共聚物粘指剂的润滑剂组合物及其用途和粘度调节方法。
• High refractive index, high Abbe number intraocular lens materials
  申请人：NOVARTIS AG

  公开号：US10408974B2

  公开（公告）日：2019-09-10

  Disclosed are high refractive index, hydrophobic, acrylic materials. These materials have both high refractive index and a high Abbe number. This combination means the materials have a low refractive index dispersion and thus are especially suitable for use as intraocular lens materials. The materials are also suitable for use in other implantable ophthalmic devices, such as keratoprostheses, corneal rings, corneal implants, and corneal inlays.

  所公开的是高折射率、疏水性丙烯酸材料。这些材料同时具有高折射率和高阿贝数。这种组合意味着材料具有低折射率分散性，因此特别适合用作眼内透镜材料。这些材料还适用于其他植入式眼科设备，如角膜假体、角膜环、角膜植入物和角膜嵌体。