N-(2,5-Dimethyl-phenyl)-succinimid | 88612-25-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: N-(2,5-Dimethyl-phenyl)-succinimid
• 英文别名: N-(2,6-Dimethyl-phenyl)-succinimid；N-(2,5-dimethyl-phenyl)-succinimide；1-(2,5-Dimethylphenyl)-2,5-pyrrolidinedione；1-(2,5-dimethylphenyl)pyrrolidine-2,5-dione
• CAS: 88612-25-3
• 化学式: C₁₂H₁₃NO₂
• mdl: MFCD00158663
• 分子量: 203.241
• InChiKey: UFVNFMKPUKKMQU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.333
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-(2,5-Dimethyl-phenyl)-succinimid 在 tetraphosphorus decasulfide 作用下， 生成 甲醛,聚合(氯甲基)噁丙环,4,4-(1-甲基亚乙基)二(苯酚)和2-甲基苯酚,2-甲基-2-丙烯酸酯
  参考文献：
  名称：

  轴向手性单硫代琥珀酰亚胺向1，1-二苯基乙烯的非对映选择性光环加成。

  摘要：

  在二苯乙烯存在下，轴向手性单硫代琥珀酰亚胺的光解有效地产生了螺硫杂环丁烷，其中通过邻位取代基在苯环上的空间效应，非对映选择性地进行环加成反应。

  DOI：

  10.1039/b304435a
• 作为产物：
  描述：

  丁二酸 、 2,5-二甲基苯胺 生成 N-(2,5-Dimethyl-phenyl)-succinimid
  参考文献：
  名称：

  Miolati; Lotti, Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1896, vol. <5> 5 I, p. 90

  摘要：

  DOI：

文献信息

• OPTICAL FILM, CIRCULARLY POLARIZING PLATE, AND IMAGE DISPLAY DEVICE
  申请人：Fujisawa Rie

  公开号：US20150247963A1

  公开（公告）日：2015-09-03

  A optical film includes a thermoplastic resin and a compound wherein: (1) the absorption spectrum of said compound in solution has at least two absorption maxima in the 200-350 nm wavelength range; (2) letting λmax 1 represent the wavelength of a first absorption maximum (one of the aforementioned absorption maxima) and letting λmax 2 represent the wavelength of a second absorption maximum (another of the aforementioned absorption maxima) at a shorter wavelength than the first absorption maximum, (λmax 1 −λmax 2 ) is at least 20 nm; (3) the aspect ratio of the molecules of the compound is at least 1.70; (4) each molecule of the compound has a non-aromatic hydrocarbon ring, a non-aromatic heterocycle, or an aromatic heterocycle; (5) the in-plane-retardation increase sensitivity of the compound is at least 0.1; 110 nm≦R 0 (550)≦170 nm; 0.72≦R 0 (450)/R 0 (550)≦0.96; and 0.83≦R 0 (550)/R 0 (650)≦0.97.
• US9500790B2
  申请人：——

  公开号：US9500790B2

  公开（公告）日：2016-11-22
• Diastereoselective photocycloaddition of axially chiral monothiosuccinimides to 1,1-diphenylethylene
  作者：Masami Sakamoto、Masaki Shigekura、Ayako Saito、Tomoko Ohtake、Takashi Mino、Tsutomu Fujita

  DOI：10.1039/b304435a

  日期：——

  Photolysis of axially chiral monothiosuccinimides in the presence of diphenylethylene gave spirothietanes effectively, where the cycloaddition took place diastereoselectively by way of the steric effect of the ortho-substituent on the phenyl ring.

  在二苯乙烯存在下，轴向手性单硫代琥珀酰亚胺的光解有效地产生了螺硫杂环丁烷，其中通过邻位取代基在苯环上的空间效应，非对映选择性地进行环加成反应。
• Miolati; Lotti, Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1896, vol. <5> 5 I, p. 90
  作者：Miolati、Lotti

  DOI：——

  日期：——