N,N-diethyl-N',N'-dimethyl-4,4'-[5-(2-chloro-phenyl)-oxazole-2,4-diyl]-bis-aniline | 10004-31-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: N,N-diethyl-N',N'-dimethyl-4,4'-[5-(2-chloro-phenyl)-oxazole-2,4-diyl]-bis-aniline
• 英文别名: 4-[5-(2-chlorophenyl)-2-[4-(diethylamino)phenyl]-1,3-oxazol-4-yl]-N,N-dimethylaniline
• CAS: 10004-31-6
• 化学式: C₂₇H₂₈ClN₃O
• 分子量: 445.992
• InChiKey: BDQMFBXOQYLWQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  32
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  32.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N,N-diethyl-N',N'-dimethyl-4,4'-[5-(2-chloro-phenyl)-oxazole-2,4-diyl]-bis-aniline 生成 2-[4-(diethylamino)phenyl]-N,N-dimethylphenanthro[10,9-d][1,3]oxazol-6-amine
  参考文献：
  名称：

  SHI, XIAO-DONG, GANGUAN KEHSYUEH YUJ GUAGXUASYUEH ,(1990) N, S. 230-232

  摘要：

  DOI：

文献信息

• ARYLAMINE COMPOUND AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR
  申请人：WANG Yahui

  公开号：US20080153019A1

  公开（公告）日：2008-06-26

  An arylamine compound represented by formula (1): wherein R1 to R4 each independently represents a linear alkyl group or an arylalkenyl group, provided that when all of R1 to R4 represent linear alkyl groups, at least one of R1 to R4 represents a linear alkyl group having a carbon number of 3 or more; and an electrophotographic photoreceptor.

  一种芳胺化合物，其化学式表示为（1）：其中R1到R4各自独立地表示线性烷基或芳基烯基基团，但当R1到R4全部表示线性烷基时，至少有一个R1到R4表示具有3个或更多碳原子的线性烷基；以及一种电子照相光导体。
• Oxazole derivatives, process for production thereof and use thereof as photoconductive material
  申请人：Hitachi Chemical Co., Ltd.

  公开号：EP0129059A1

  公开（公告）日：1984-12-27

  An oxazole derivative of the formula: wherein R is an alkyl group having 1 to 3 carbon atoms is stable for ultraviolet light without decomposition when exposed thereto and can be used as a photoconductive material, for example, in electrophotographic plate.

  式中的噁唑衍生物 其中 R 是具有 1 至 3 个碳原子的烷基，在紫外线照射下稳定而不分解，可用作光电导材料，例如用于电子照相制版。
• Alpha-type titanyl phthalocyanine composition, method for production thereof, and electrophotographic sensitive material using same
  申请人：MITA INDUSTRIAL CO. LTD.

  公开号：EP0314100A2

  公开（公告）日：1989-05-03

  The first aspect of this invention resides in providing an α-type titanyl phthalocyanine composition comprising an α-type titanyl phthalocyanine and metal-­free phthalocyanine. This α-type titanyl phthalocyanine composition is stable, wide in range of absorption wavelengths, and high in spectral sensitivity because it contains an α-type titanyl phthalocyanine in combination with metal-free phthalocyanine. The second aspect of this invention resides in providing a method for the production of an α-type titanyl phthalocyanine composition comprising an α-type titanyl phthalocyanine and a metal-free phthalocyanine, which method comprises pigmenting a concentrated sulfuric acid solution containing at least titanyl phthalocyanine by the acid paste process consisting in pouring said concentrated sulfuric acid solution into water. By this method, an α-type titanyl phthalocyanine composition stable to withstand the impact of aging can be easily produced. The third aspect of this invention resides in providing an electrophotographic sensitive material having superposed on an electroconductive substrate a sensitive layer comprising an α-type titanyl phthalo­cyanine and a metal-free phthalocyanine. This electro­ photographic sensitive material excels in charging property and dark attenuation property and exhibits high sensitivity and sparing residual potential. The fourth aspect of this invention resides in providing an electrophotographic sensitive material having superposed on an electroconductive substrate a sensitive layer comprising an α-type titanyl phthalocyanine composition and an electric charge transferring material exhibiting oxidation potential in the range of 0.45 to 0.65 eV. This electrophotographic sensitive material enjoys high sensitivity and shows sparing residual potential.

  本发明的第一个方面是提供一种由α型钛酞菁和无金属酞菁组成的α型钛酞菁组合物。这种 α 型钛酞菁组合物稳定，吸收波长范围宽，光谱灵敏度高，因为它含有 α 型钛酞菁和无金属酞菁。 本发明的第二个方面是提供一种生产由 α 型钛酞菁和无金属酞菁组成的 α 型钛酞菁组合物的方法，该方法包括通过酸浆工艺将至少含有钛酞菁的浓硫酸溶液颜料化，酸浆工艺包括将所述浓硫酸溶液倒入水中。通过这种方法，可以很容易地生产出稳定的 α 型钛酞菁组合物，以抵御老化的影响。 本发明的第三个方面是提供一种电致发光感光材料，它在导电基底上叠加了由 α 型钛酞菁和无金属酞菁组成的感光层。这种电致发光感光材料具有优异的充电性能和暗衰减性能，并表现出高灵敏度和无残留电位。 本发明的第四个方面是提供一种电致发光感光材料，该材料在导电基底上叠加有感光层，感光层由 α 型钛酞菁成分和电荷转移材料组成，电荷转移材料的氧化电位在 0.45 至 0.65 eV 之间。这种电致发光感光材料灵敏度高，残留电位低。
• POLYCARBONATE POLYMER, PRODUCTION THEREOF, AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR MADE THEREFROM
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0582722A1

  公开（公告）日：1994-02-16

  A polycarbonate polymer wherein the repeating unit is a group represented by general formula (I) and the terminal group is a group represented by formulae (I), (II), (III), (IV) or (V). In formula (I) R¹ and R² represent each halogen, alkyl, cycloalkyl or aryl; a and b represent each independently an integer of 0 to 4; x represents a single bond, -O-, -CO-, -S-, -SO-, -SO₂-, -CR³R⁴-, 1,1-cycloalkylidene or α,ω-alkylene; in formulae (II), (III), (IV) and (V) R⁵ represents C₁-C₃₀ perfluoroalkyl which may be substituted; Y represents -CH₂; n represents and integer of 0 to 6; Z represents -O-, -CO-, -OCO-, -S-, -SO-, -SO₂-or -NHCO-; f represents 0 to 1; R⁶ represents halogen, alkyl, cycloalkyl or aryl; and c and d represent each an interger provided that c + d ≦ 5, c = 1 - 5 and d = 0 - 4. An electrophotographic photoreceptor containing the polycarbonate as one component of the photosensitive layer, which is free from the problem of clouding (gelation) of a coating fluid used for making the same, retains excellent mechanical strengths such a plate wear, and can maintain excellent electrophotographic characteristics, thus being practically excellent.

  一种聚碳酸酯聚合物，其中重复单元为通式 (I) 所代表的基团，末端基团为式 (I)、(II)、(III)、(IV) 或 (V) 所代表的基团。在式 (I) 中，R¹ 和 R² 各自代表卤素、烷基、环烷基或芳基；a 和 b 各自独立地代表 0 至 4 的整数；x 代表单键、-O-、-CO-、-S-、-SO-、-SO₂-、-CR³R⁴-、1,1-环烷基亚基或 α,ω-亚烷基；在式(II)、(III)、(IV)和(V)中，R⁵ 代表可能被取代的 C₁-C₃₀ 全氟烷基；Y代表-CH₂；n代表0至6的整数；Z代表-O-、-CO-、-OCO-、-S-、-SO-、-SO₂-或-NHCO-；f代表0至1；R⁶代表卤素、烷基、环烷基或芳基；以及c和d分别代表一个整数，条件是c+d≦5，c＝1-5，d＝0-4。含有聚碳酸酯作为感光层成分之一的电致发光感光体，不存在用于制造该感光体的涂布液混浊（凝胶化）的问题，可保持极佳的机械强度（如板磨损），并可保持极佳的电致发光特性，因此实际上是极佳的。
• New naphthalenetetracarboxylic acid diimides as electron transporting agents in photosensitive material for electrophotography
  申请人：MITA INDUSTRIAL CO. LTD.

  公开号：EP0962458A1

  公开（公告）日：1999-12-08

  Naphthalenetetracarboxylic acid diimide derivatives represented by the following general formula, wherein R is a hydrogen atom, an alkyl group, an alkoxyl group or a halogen atom, R1 and R2 are different from each other and may be a substituted or unsubstituted alkyl group, alkoxyl group or an aryl group, respectively, and R3 is a hydrogen atom, a substituted or unsubstituted alkyl group, an alkoxyl group or an aryl group. The derivatives exhibit excellent solubility in an organic solvent, excellent compatibility with a resin binder and excellent photosensitivity, and are very useful as an electron transporting agent for the electrophotosensitive material.

  由以下通式代表的萘四甲酸二亚胺衍生物、 其中 R 是氢原子、烷基、烷氧基或卤素原子，R1 和 R2 互不相同，可以分别是取代或未取代的烷基、烷氧基或芳基，R3 是氢原子、取代或未取代的烷基、烷氧基或芳基。 这些衍生物在有机溶剂中的溶解性极佳，与树脂粘合剂的相容性极佳，光敏性极佳，作为电致发光材料的电子传输剂非常有用。