3-chloro-2-pentene | 26423-60-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 3-chloro-2-pentene
• 英文别名: (Z)-3-Chloro-2-pentene；(Z)-3-chloropent-2-ene
• CAS: 26423-60-9
• 化学式: C₅H₉Cl
• 分子量: 104.579
• InChiKey: VSQKJRIDGSFPSI-HYXAFXHYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  6
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3-chloro-2-pentene 、 三甲基硅烷 生成 (E)-1-Ethyl-1-(trimethylsilyl)-1-propene
  参考文献：
  名称：

  DAVIS A. P.; HUGHES G. J.; LOWNDES P. R.; ROBBINS C. M.; THOMAS E. J.; WH+, J. CHEM. SOC. PERKIN TRANS., 1981, PART 1, NO 7, 1934-1941

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2-二氯-2-丁烯 以60%的产率得到
  参考文献：
  名称：

  MKRYAN, G. M.;MKRTCHYAN, A. M.;AVAKYAN, S. P.;KAPLANYAN, EH. E., ARM. XIM. ZH., 1981, 34, N 10, 847-853

  摘要：

  DOI：

文献信息

• First Catalytic and Green Synthesis of Aryl-(<i>Z</i>)-vinyl Chlorides and Its Plausible Addition−Elimination Mechanism
  作者：Weike Su、Can Jin

  DOI：10.1021/ol062991c

  日期：2007.3.1

  mol %)/benzoyl chloride (5 mol %), aromatic ketones were treated with bis(trichloromethyl) carbonate (BTC) to afford aryl-(Z)-vinyl chlorides. All metal triflates tested in the reaction showed highly catalytic activity. A plausible addition-elimination mechanism was proposed. The present work describes the first catalytic and green route to the synthesis of aryl-(Z)-vinyl chlorides. [reaction: see

  通过在三氟甲磺酸scan（2 mol％）/ DMF（1 mol％）/苯甲酰氯（5 mol％）存在下的催化循环，将芳族酮用碳酸二（三氯甲基）酯（BTC）处理，得到芳基-（Z ）-氯乙烯。反应中测试的所有金属三氟甲磺酸盐均显示出高催化活性。提出了一种合理的加除机制。本工作描述了合成芳基-（Z）-氯乙烯的第一个催化途径和绿色途径。[反应：看文字]
• [EN] IMPROVED PROCESS FOR PREPARING CHLOROALKANES AND/OR CHLOROFLUOROALKANES<br/>[FR] PROCÉDÉ AMÉLIORÉ DE PRÉPARATION DE CHLOROALCANES ET/OU DE CHLOROFLUOROALCANES
  申请人：BLUE CUBE IP LLC

  公开号：WO2019195258A1

  公开（公告）日：2019-10-10

  The present invention provides processes for the production of chloroalkanes, chlorofluoroalkanes, or combinations thereof from one or more alkenes, chlorinated alkenes, fluorinated alkenes, or combinations thereof.

  本发明提供了一种从一个或多个烯烃，氯代烯烃，氟代烯烃或其组合物中生产氯代烷烃，氯氟代烷烃或其组合物的过程。
• METHOD FOR IMPROVING THE PRODUCTION OF A CHLORINATED ALKANE BY CHLORINATION OF A CHLOROALKENE USING A DILUENT
  申请人：BLUE CUBE IP LLC

  公开号：US20190300459A1

  公开（公告）日：2019-10-03

  The present invention provides improved processes for the production of a chlorinated alkane by chlorination of a chloroalkene in the presence of a diluent.

  本发明提供了一种在稀释剂存在下通过氯化氯烯烃的氯化反应来生产氯化烷的改进工艺。
• Substituted thiopene derivative and plant disease control agent comprising the same as active ingredient
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0841336A1

  公开（公告）日：1998-05-13

  A novel substituted thiophene derivatives represented by the formula (1) in the invention: wherein R is a straight or branched alkyl group having 3-12 carbon atoms, straight or branched halogenoalkyl group having 3-12 carbon atoms, straight or branched alkenyl group having 3-10 carbon atoms, straight or branched halogenoalkenyl group having 3-10 carbon atoms, or cycloalkyl group having 3-10 carbon atoms, the cycloalkyl group being unsubstituted or substituted with an alkyl group having 1-4 carbon atoms, R and -NHCOAr are adjacent to each other, and Ar is a heterocyclic group; have excellent control activity on various plant disease such as Gray mold, Powdery mildew, Blast and Rust, and are useful as a plant disease control agent due to outstanding residual effect on Botrytis cinerea and excellent effect on Gibberella zeae.

  一种由本发明中式(1)代表的新型取代噻吩衍生物： 其中 R 是具有 3-12 个碳原子的直链或支链烷基、具有 3-12 个碳原子的直链或支链卤代烷基、具有 3-10 个碳原子的直链或支链烯基、具有 3-10 个碳原子的直链或支链卤代烯基或具有 3-10 个碳原子的环烷基，环烷基未被取代或被具有 1-4 个碳原子的烷基取代，R 和 -NHCOAr 相邻，Ar 是杂环基团； 对灰霉病、白粉病、疫病和锈病等多种植物病害具有优异的防治活性，由于对灰霉病菌（Botrytis cinerea）具有突出的残留效果，对赤霉病菌（Gibberella zeae）具有优异的效果，因此可用作植物病害防治剂。
• Luk'yanov, S. M.; Borodaev, S. V.; Zubkova, O. V., Russian Journal of Organic Chemistry, 1995, vol. 31, # 7, p. 921 - 926
  作者：Luk'yanov, S. M.、Borodaev, S. V.、Zubkova, O. V.

  DOI：——

  日期：——