4-(2-methylbutyl)phenol | 130976-88-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(2-methylbutyl)phenol
• 英文别名: (+)4-(2'-Methylbutyl)phenol
• CAS: 130976-88-4
• 化学式: C₁₁H₁₆O
• 分子量: 164.247
• InChiKey: WNLHHAAYHRAAKQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-(2-methylbutyl)phenol 在 rhodium on alumina chromium(VI) oxide 、 氢气 、 magnesium 、 1,2-二溴乙烷 作用下， 反应 3.0h， 生成 4-(2-Methyl-butyl)-1-(4-trifluoromethyl-phenyl)-cyclohexanol
  参考文献：
  名称：

  Liang, Jason C.; Kumar, Satyendra, Molecular Crystals and Liquid Crystals (1969-1991), 1987, vol. 142, p. 77 - 84

  摘要：

  DOI：
• 作为产物：
  描述：

  4-(2-甲基-丁基)-苯甲醚 在 氢溴酸 作用下， 以 水 、 溶剂黄146 为溶剂， 生成 4-(2-methylbutyl)phenol
  参考文献：
  名称：

  Liquid crystal compounds

  摘要：

  揭示了一种新型液晶化合物，这些化合物是基于苯酚的手性酯。典型的例子包括：和这些化合物的混合物具有螺旋螺距，使得当用普通光照射时，混合物反射特定波长的光，并且螺距对温度敏感，因此这些混合物可以用于温度指示装置。给出了具体的例子，以及可以用于相变电光显示装置的混合物样品。

  公开号：

  US04195916A1

文献信息

• Oligomeric hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same
  申请人：——

  公开号：US20020087000A1

  公开（公告）日：2002-07-04

  Oligomeric compounds and methods of making the compound having the formula: T&Parenopenst;E-F&Parenclosest; i &Parenopenst;E-F′&Parenclosest; j &Parenopenst;E′-F&Parenclosest; k &Parenopenst;E′-F′&Parenclosest; l S  (II) wherein i, j, k, and l are integers from about 0 to 300 and the sum of i, j, k, and l is greater than 2, wherein the units F, F′ and T are derived from one or more multi-functional carbonyl compounds of general structure DO—CO—CR a R b —(—CR c R d —) n —NH—(Y) m —CO—OD  (IV) wherein n is an integer from 1 to 15, m is either 0 or 1; R a , R b , R c , and R d , are each a hydrogen or a hydrocarbyl group; Y is CO—(CR e R f ) p , wherein R e and R f are each a hydrogen or hydrocarbyl group and p is zero or an integer from 1 to 20 or CO—C 6 H 4 —, wherein the substitution pattern on the phenylene group is an ortho, meta, or para substitution pattern, and one or more of the hydrogens of the phenylene group may be substituted by a hydrocarbyl group or a functional group; and D is a hydrocarbyl group and the units E, E′ and S are derived from one or more 1-substituted piperidin-4-ol or 4-aminopiperidines of general structure 1 wherein Z is OH or NHG, wherein G is H or C 1 -C 12 alkyl, R 1 is —(CH 2 ) s —OH, —(CH 2 ) s —NH 2 , C 1 -C 18 hydroxyalkoxy or C 5 -C 12 hydroxycycloalkoxy; wherein s is an integer from 1 to 10; R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 , R 4 , R 5 , and R 6 are each a hydrogen, C 1 -C 8 alkyl, benzyl or phenethyl, or two geminal R moieties, which together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl. The compounds are useful for stabilizing polymer compositions against photo- and thermal degradation.

  含有以下公式的化合物的寡聚体化合物及其制备方法：T&Parenopenst;E-F&Parenclosest;i&Parenopenst;E-F′&Parenclosest;j&Parenopenst;E′-F&Parenclosest;k&Parenopenst;E′-F′&Parenclosest;lS  (II)，其中i、j、k和l为约0至300的整数，且i、j、k和l的总和大于2，其中单位F、F′和T来源于一个或多个具有一般结构DO—CO—CRaRb—(—CRcRd—)n—NH—(Y)m—CO—OD  (IV)的多功能羰基化合物，其中n为1至15的整数，m为0或1；Ra、Rb、Rc和Rd分别为氢或烃基团；Y为CO—(CReRf)p，其中Re和Rf分别为氢或烃基团，p为0或1至20的整数，或CO—C6H4—，苯环基上的取代模式为邻位、间位或对位取代模式，苯环基的一个或多个氢原子可被烃基团或功能基团取代；D为烃基团，单位E、E′和S来源于一个或多个具有一般结构1的1-取代哌啶-4-醇或4-氨基哌啶，其中Z为OH或NHG，G为H或C1-C12烷基，R1为—(CH2)s—OH、—(CH2)s—NH2、C1-C18羟基烷氧基或C5-C12羟基环烷氧基，其中s为1至10的整数；R2代表氢、C1-C8烷基或苄基；R3、R4、R5和R6分别为氢、C1-C8烷基、苄基或苯乙基，或两个伪生R基团，它们与它们附着的碳形成C5-C10环烷基。这些化合物可用于稳定聚合物组合物对光和热降解的作用。
• Hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same
  申请人：——

  公开号：US20020099218A1

  公开（公告）日：2002-07-25

  Compounds and methods of preparing compounds of the formula: RZ—CO—CR a R b —(CR c R d ) n —NH—(Y) m —CO—A  (I) wherein n is an integer from 1 to 15, m is either 0 or 1; R a , R b , R c , and R d are each a hydrogen or a hydrocarbyl group; Y is CO—(CR e R f ) p , wherein R e and R f are each a hydrogen or hydrocarbyl group and p is zero or an integer from 1 to 20 or CO—C 6 H 4 —, wherein the substitution pattern on the phenylene group is an ortho, meta, or para substitution pattern and one or more of the hydrogens of the phenylene group may be substituted by a hydrocarbyl group or a functional group; Z is —O— or —NG—, wherein G is H, C 1 -C 12 alkyl or the radical R; wherein R is 1 wherein R 1 is hydrogen, C 1 -C 18 alkyl, O, OH, CH 2 CN, C 1 -C 18 alkoxy, C-C 18 hydroxyalkoxy, C 5 -C 12 cycloalkoxy, C 5 -C 12 hydroxycycloalkoxy, C 3 -C 6 alkenyl, C 1 -C 18 alkynyl, C 7 -C 9 phenylalkyl, unsubstituted or substituted on the phenyl with 1, 2 or 3 C 1 -C 4 alkyls, or an aliphatic C 1 -C 8 acyl; R 2 is hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 , R 4 , R 5 , and R 6 are each a hydrogen, C 1 -C 8 alkyl, benzyl or phenethyl, or two geminal R moieties, which together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; and A is either ZR or a hydrocarbyl group, which are useful for stabilizing polymer compositions against photo- and thermal degradation.

  该公式的化合物及其制备方法：RZ—CO—CRaRb—(CRcRd)n—NH—(Y)m—CO—A（I）其中n是1到15之间的整数，m为0或1；Ra、Rb、Rc和Rd分别是氢或烃基团；Y是CO—(CReRf)p，其中Re和Rf分别是氢或烃基团，p为0或1到20之间的整数，或CO—C6H4—，其中苯环上的取代模式为邻位、间位或对位取代模式，苯环的一个或多个氢原子可能被烃基团或功能基团取代；Z是—O—或—NG—，其中G是H、C1-C12烷基或基团R；其中R是1其中R1是氢、C1-C18烷基、O、OH、CH2CN、C1-C18甲氧基、C-C18羟基甲氧基、C5-C12环氧基、C5-C12羟基环氧基、C3-C6烯基、C1-C18炔基、C7-C9苯基烷基，苯基上未取代或取代1、2或3个C1-C4烷基，或脂肪族C1-C8酰基；R2是氢、C1-C8烷基或苄基；R3、R4、R5和R6分别是氢、C1-C8烷基、苄基或苯乙基，或两个共轭的R基，与它们附着的碳形成C5-C10环烷基；A是ZR或烃基团，可用于稳定聚合物组合物对光和热降解的影响。
• Process For Producing Phosphonitrilic Acid Ester
  申请人：Kuwata Kotaro

  公开号：US20080091050A1

  公开（公告）日：2008-04-17

  A process for producing a cyclic and/or linear phosphonitrilic acid ester from a cyclic and/or linear phosphonitrile dichloride is provided, wherein the reaction time is shorter and the content of monochloro phosphazenes is very small. When phosphonitrile dichloride is reacted with a metal arylolate and/or a metal alcoholate in the presence of a reaction solvent, a metal arylolate and/or a metal alcoholate composed of at least two different metals having different ionization energies is used and also a specific compound is used as a catalyst.

  解决的问题：提供一种从环状和/或线性磷酸腈二氯化物制备环状和/或线性磷氮酸酯的方法，其中反应时间较短，单氯磷氮烷的含量非常小。 解决方案：当磷酸腈二氯化物与金属芳酚醇盐和/或金属醇盐在反应溶剂存在下反应时，使用由至少两种具有不同电离能的金属组成的金属芳酚醇盐和/或金属醇盐，并且还使用特定化合物作为催化剂。
• METHODS FOR PRODUCING POLYCYCLIC AROMATIC AMINOPHENOL COMPOUND AND RESIN COMPOSITION, AND POLYCYCLIC AROMATIC AMINOPHENOL COMPOUND, RESIN COMPOSITION, AND CURED PRODUCT
  申请人：DIC Corporation

  公开号：US20190144372A1

  公开（公告）日：2019-05-16

  A task is to provide a method for producing a polycyclic aromatic aminophenol compound through a reduced number of steps at a low cost with high safety. The method for producing a polycyclic aromatic aminophenol compound includes the step of reacting a compound represented by the general formula (1) below and an aromatic amino compound with each other: Wherein n represents an integer of 1 to 8, Ar represents a benzene ring optionally having a substituent, or a naphthalene ring optionally having a substituent, each of R 1 and R 2 independently represents a hydrogen atom, a hydrocarbon group having 1 to 6 carbon atoms and optionally having a substituent, or an aromatic group optionally having a substituent, and R 3 represents a hydroxyl group, a methoxy group, or a halogen atom.

  一项任务是提供一种以较少步骤、低成本且高安全性生产多环芳香氨基酚化合物的方法。生产多环芳香氨基酚化合物的方法包括以下步骤：将由下述通式（1）表示的化合物与芳香胺化合物相互反应：其中n代表1到8之间的整数，Ar代表一个苯环，可选地具有取代基，或一个萘环，可选地具有取代基，R1和R2各自独立地代表氢原子，具有1到6个碳原子且可选地具有取代基的烃基，或可选地具有取代基的芳香基，R3代表羟基、甲氧基或卤素原子。
• Polymerizable liquid crystal compound, composition and polymer
  申请人：Itoh Maiko

  公开号：US20100076171A1

  公开（公告）日：2010-03-25

  A polymerizable liquid crystal compound that has a wide liquid crystal phase temperature range and has a sterol ferulate skeleton, and a liquid crystal composition containing the compound are provided. A polymer that is excellent in various characteristics, and a molded article having optical anisotropy produced with the polymer are obtained with the polymerizable liquid crystal compound. The compound is represented by formula (1): wherein R represents a sterol moiety derived from vegetable organisms; P represents one of polymerizable groups represented by formulae (P1) to (P8); X, Z, X 0 and Z 0 each represent a bonding group; and A represents a divalent group having a cyclic structure.

  提供了一种具有广泛液晶相温度范围和具有甾醇酰基骨架的可聚合液晶化合物以及含有该化合物的液晶组合物。使用可聚合液晶化合物制备出在各种特性方面均优异的聚合物和具有光学各向异性的成型品。该化合物由式（1）表示：其中R代表来自植物有机体的甾醇基团；P代表由式（P1）至（P8）表示的可聚合基团之一；X、Z、X0和Z0各代表结合基团；A代表具有环状结构的二价基团。