1,3-dimethoxy-2-methylimidazolium bis(trifluoromethylsulfonyl)imide | 951020-83-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1,3-dimethoxy-2-methylimidazolium bis(trifluoromethylsulfonyl)imide
• 英文别名: 1,3-dimethoxy-2-methylimidazolium bis(trifluoromethylsulfonyl)imine；1,3-dimethoxy-2-methylimidazolium；1,3-Dimethoxy-2-methylimidazol-1-ium；1,3-dimethoxy-2-methylimidazol-1-ium
• CAS: 951020-83-0
• 化学式: C₆H₁₁N₂O₂
• 分子量: 143.166
• InChiKey: UZHFEDQOACUXGG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  27.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-hydroxy-2-methylimidazole 3-oxide 、 硫酸二甲酯 在 碳酸氢钠 作用下， 反应 13.0h， 生成 1,3-dimethoxy-2-methylimidazolium bis(trifluoromethylsulfonyl)imide
  参考文献：
  名称：

  N,N'-Di(alkyloxy)imidazolium Salts: New Patent-free Ionic Liquids and NHC Precatalysts

  摘要：

  1-羟基咪唑-3-氧化物（2-羟基，2-甲基）与（RO）2SO2（R = Me，Et）发生烷基化反应，形成新的1,3-二（烷氧基）咪唑阳离子，作为六氟磷酸盐被分离出来。离子交换产生了新的疏水性离子液体（双（三氟甲磺酰）亚胺，三（五氟乙基）三氟磷酸盐）。溴化反应得到2-溴衍生物，通过氧化插入转化为Ni和Pd N-杂环卡宾配合物。通过X射线衍射确定了十五个晶体结构。N-烷氧基团扭曲出咪唑环平面，并在固态中采用syn或anti构象。

  DOI：

  10.1515/znb-2007-0301

文献信息

• LIQUID CONTAINING LAYERED-SUBSTANCE AND METHOD FOR PRODUCING SAME
  申请人：Adeka Corporation

  公开号：EP3272813A1

  公开（公告）日：2018-01-24

  A solution containing an ionic liquid, a polymer compound including at least one of a hydrolyzable polymer compound and a thermally-decomposable polymer compound, and a laminate of layered substances is irradiated with at least one of sonic waves and radio waves. Alternatively, a solution containing an ionic liquid, a polymer compound including at least one of a hydrolyzable polymer compound and a thermally-decomposable polymer compound, and a laminate of layered substances is heated.

  用声波和无线电波中的至少一种对含有离子液体、聚合物化合物（包括可水解聚合物化合物和可热分解聚合物化合物中的至少一种）和分层物质层压板的溶液进行辐照。或者，加热含有离子液体、聚合物化合物（包括可水解聚合物化合物和可热分解聚合物化合物中的至少一种）和层状物质薄片的溶液。
• SOLUTION CONTAINING LAYERED SUBSTANCE, AND METHOD FOR PRODUCING SAME
  申请人：Adeka Corporation

  公开号：EP3556811A1

  公开（公告）日：2019-10-23

  A solution is prepared that contains (A) a polymer compound that includes at least one of a hydrolyzable polymer compound or a thermally-decomposable polymer compound, (B) an oxoacid-based compound that includes at least one of a phosphate-based compound, a sulfate-based compound, a sulfonate-based compound, or a perchlorate-based compound, and (C) a laminate of layered substances, and the solution is irradiated with at least one of sonic waves or radio waves, or the solution is heated.

  制备含有以下物质的溶液：(A) 包括可水解聚合物化合物或可热分解聚合物化合物中至少一种的聚合物化合物；(B) 包括磷酸盐基化合物、硫酸盐基化合物、磺酸盐基化合物或高氯酸盐基化合物中至少一种的氧酸基化合物；(C) 层状物质的层压板。
• Conversion of sugars to ionic liquids
  申请人：NATIONAL TECHNOLOGY & ENGINEERING SOLUTIONS OF SANDIA, LLC

  公开号：US10934568B2

  公开（公告）日：2021-03-02

  Disclosed herein are methods for preparing sugar compositions. The methods include: i) forming a mixture including polysaccharide biomass and an ionic liquid solution, wherein the ionic liquid solution contains water and an ionic liquid, and the ionic liquid contains a) a cation and b) a sugar acid anion or a ketoacid anion; ii) maintaining the mixture under conditions sufficient to dissolve at least a portion of the polysaccharide present in the polysaccharide biomass; iii) adding at least one glycoside hydrolase to the mixture; and iv) maintaining the mixture containing the glycoside hydrolase under conditions sufficient to hydrolyze at least a portion of the dissolved polysaccharide, thereby forming the sugar compositions. The sugar compositions contain at least one monosaccharide or oligosaccharide. New sugar-based ionic liquids are also described.

  本文公开了制备糖组合物的方法。这些方法包括i) 形成包括多糖生物质和离子液体溶液的混合物，其中离子液体溶液包含水和离子液体，且离子液体包含 a) 阳离子和 b) 糖酸阴离子或酮酸阴离子； ii) 在足以溶解多糖生物质中存在的至少一部分多糖的条件下保持该混合物；iii) 向混合物中加入至少一种苷水解酶；以及 iv) 将含有苷水解酶的混合物保持在足以水解至少一部分溶解多糖的条件下，从而形成糖组合物。糖组合物至少含有一种单糖或寡糖。还介绍了新的糖基离子液体。
• Layered-substance-containing solution and method of manufacturing same
  申请人：ADEKA CORPORATION

  公开号：US10946360B2

  公开（公告）日：2021-03-16

  A solution containing an ionic liquid, a polymer compound including at least one of a hydrolyzable polymer compound and a thermally-decomposable polymer compound, and a laminate of layered substances is irradiated with at least one of sonic waves and radio waves. Alternatively, a solution containing an ionic liquid, a polymer compound including at least one of a hydrolyzable polymer compound and a thermally-decomposable polymer compound, and a laminate of layered substances is heated.

  用声波和无线电波中的至少一种对含有离子液体、聚合物化合物（包括可水解聚合物化合物和可热分解聚合物化合物中的至少一种）和分层物质层压板的溶液进行辐照。或者，加热含有离子液体、聚合物化合物（包括可水解聚合物化合物和可热分解聚合物化合物中的至少一种）和层状物质薄片的溶液。
• Switchable ionic liquids for biomass pretreatment and enzymatic hydrolysis
  申请人：National Technology & Engineering Solutions of Sandia, LLC

  公开号：US11118204B2

  公开（公告）日：2021-09-14

  In one aspect, the present invention provides a method for preparing a sugar composition. The method includes: forming a mixture including polysaccharide biomass and an ionic liquid solution, wherein the ionic liquid solution contains water and an ionic liquid, and wherein the ionic liquid contains a dicarboxylic acid anion and a cation. The pH of the mixture is greater than or equal to about 10, and the molar ratio of the dicarboxylic acid anion to the cation is at least about 1:2. The method further includes: maintaining the mixture under conditions sufficient to dissolve at least a portion of the polysaccharide present in the polysaccharide biomass; reducing the pH of the mixture containing the dissolved polysaccharide to at least about 7; adding at least one glycoside hydrolase to the mixture having the reduced pH.

  一方面，本发明提供了一种制备糖组合物的方法。该方法包括：形成包括多糖生物质和离子液体溶液的混合物，其中离子液体溶液包含水和离子液体，离子液体包含二羧酸阴离子和阳离子。混合物的 pH 值大于或等于约 10，二羧酸阴离子与阳离子的摩尔比至少约为 1:2。该方法进一步包括：将混合物保持在足以溶解多糖生物质中存在的至少一部分多糖的条件下；将含有溶解多糖的混合物的pH值降低到至少约7；向pH值降低的混合物中加入至少一种糖苷水解酶。