Nonacyclo[14.6.6.65,12.02,15.04,13.06,11.017,22.023,28.029,34]tetratriaconta-2,4(13),6,8,10,14,17,19,21,23,25,27,29,31,33-pentadecaene-3,14-diamine | 1233942-09-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: Nonacyclo[14.6.6.65,12.02,15.04,13.06,11.017,22.023,28.029,34]tetratriaconta-2,4(13),6,8,10,14,17,19,21,23,25,27,29,31,33-pentadecaene-3,14-diamine
• CAS: 1233942-09-0
• 化学式: C₃₄H₂₄N₂
• 分子量: 460.578
• InChiKey: PNORHSCQHNZHGC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  36
• 可旋转键数：
  0
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Nonacyclo[14.6.6.65,12.02,15.04,13.06,11.017,22.023,28.029,34]tetratriaconta-2,4(13),6,8,10,14,17,19,21,23,25,27,29,31,33-pentadecaene-3,14-diamine 在 亚硝酸特丁酯 、 potassium iodide 作用下， 以 乙腈 为溶剂， 反应 16.0h， 以55%的产率得到3,14-Diiodononacyclo[14.6.6.65,12.02,15.04,13.06,11.017,22.023,28.029,34]tetratriaconta-2,4(13),6,8,10,14,17,19,21,23,25,27,29,31,33-pentadecaene
  参考文献：
  名称：

  Pentiptycene Building Blocks Derived from Nucleophilic Aromatic Substitution of Pentiptycene Triflates and Halides

  摘要：

  The nucleophilic aromatic substitution (S(N)Ar) reactions of the nitro-substituted pentiptycene triflate 15 with LiBr and LiI and the resulting halides 18 and 19 with N(3)(-), CN(-), and ArS(-) in DMF provide an efficient route toward pentiptycene halides and dihalides and other new pentiptycene building blocks. The reactivity of diaminopentiptycene in Pd-catalyzed C-N coupling reactions is also demonstrated.

  DOI：

  10.1021/jo100812z
• 作为产物：
  描述：

  14-Nitrononacyclo[14.6.6.65,12.02,15.04,13.06,11.017,22.023,28.029,34]tetratriaconta-2,4(13),6,8,10,14,17,19,21,23,25,27,29,31,33-pentadecaen-3-amine 在 盐酸 、 tin(II) chloride dihdyrate 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 12.0h， 以93%的产率得到Nonacyclo[14.6.6.65,12.02,15.04,13.06,11.017,22.023,28.029,34]tetratriaconta-2,4(13),6,8,10,14,17,19,21,23,25,27,29,31,33-pentadecaene-3,14-diamine
  参考文献：
  名称：

  Pentiptycene Building Blocks Derived from Nucleophilic Aromatic Substitution of Pentiptycene Triflates and Halides

  摘要：

  The nucleophilic aromatic substitution (S(N)Ar) reactions of the nitro-substituted pentiptycene triflate 15 with LiBr and LiI and the resulting halides 18 and 19 with N(3)(-), CN(-), and ArS(-) in DMF provide an efficient route toward pentiptycene halides and dihalides and other new pentiptycene building blocks. The reactivity of diaminopentiptycene in Pd-catalyzed C-N coupling reactions is also demonstrated.

  DOI：

  10.1021/jo100812z

文献信息

• Iptycene substitution enhances the electrochemical activity and stability of polyanilines
  作者：Wei Shyang Tan、Ting-Yin Lee、Ying-Feng Hsu、Shing-Jong Huang、Jye-Shane Yang

  DOI：10.1039/c8cc02387e

  日期：——

  The clipping effect of pentiptycene cavities provides a significant improvement in pseudocapacitance and charge–discharge stability for pentiptycene-incorporated polyanilines.

  五苯脲腔的剪切效应显著提高了五苯脲共聚物中的假电容和充放电稳定性。
• Pentiptycene Building Blocks Derived from Nucleophilic Aromatic Substitution of Pentiptycene Triflates and Halides
  作者：Sandip Kumar Kundu、Wei Shyang Tan、Jyu-Lun Yan、Jye-Shane Yang

  DOI：10.1021/jo100812z

  日期：2010.7.2

  The nucleophilic aromatic substitution (S(N)Ar) reactions of the nitro-substituted pentiptycene triflate 15 with LiBr and LiI and the resulting halides 18 and 19 with N(3)(-), CN(-), and ArS(-) in DMF provide an efficient route toward pentiptycene halides and dihalides and other new pentiptycene building blocks. The reactivity of diaminopentiptycene in Pd-catalyzed C-N coupling reactions is also demonstrated.