N,N'-hexanediyl-bis-maleamic acid | 10193-37-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: N,N'-hexanediyl-bis-maleamic acid
• 英文别名: N,N'-Hexandiyl-bis-maleamidsaeure；(Z)-4-[6-[[(Z)-3-carboxyprop-2-enoyl]amino]hexylamino]-4-oxobut-2-enoic acid
• CAS: 10193-37-0
• 化学式: C₁₄H₂₀N₂O₆
• 分子量: 312.323
• InChiKey: WPUBWLUSKQXZNQ-SFECMWDFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  22
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  133
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N,N'-hexanediyl-bis-maleamic acid 在 N-甲基吗啉 、 1-丙基磷酸酐 作用下， 以 乙酸乙酯 为溶剂， 以51%的产率得到N,N’-(hexane-1,6-diyl)-bis-maleic acid isoimide
  参考文献：
  名称：

  Propanephosphonic Acid Anhydride–Mediated Cyclodehydration of Maleic Acid Monoamides

  摘要：

  Propanephosphonic acid anhydride (T3P) has been proposed as a novel reagent for the preparation of maleic acid isoimides from the corresponding monoamides. A series of substituted aromatic and aliphatic isoimides have been prepared in good yields. The main advantage of this synthetic method is the use of environmentally benign, cost-efficient reagents and solvents, which are also safer to handle than the ones employed previously. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.

  DOI：

  10.1080/00397911.2012.727060
• 作为产物：
  描述：

  马来酸酐 、 1,6-己二胺 生成 N,N'-hexanediyl-bis-maleamic acid
  参考文献：
  名称：

  Cross-linking of Polymers with Dimaleimides¹

  摘要：

  DOI：

  10.1021/ja01514a043

文献信息

• Imide-crosslinked ethylenic polymer resin foams and method of making
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0001666A2

  公开（公告）日：1979-05-02

  Resin foam products which are infusible and insoluble in usual solvents and resist ignition and burning in air are prepared from unsaturated imides such as 4,4'-methylenedianiline- bis-maleimide, unsaturated amic acids such as bis-maleamic acid and mixtures of unsaturated anhydrides such as maleic anhydride and poly(primary amines). The resin foams are made by heating to resin-forming- foaming temperature a reaction mixture containing such starting material, surfactant and blowing agent.

  不饱和酰亚胺（如 4,4'-亚甲基二苯胺-双马来酰亚胺）、不饱和胺基酸（如双马来酰亚胺酸）以及不饱和酸酐（如马来酸酐和聚（伯胺））的混合物可制备可浸润、不溶于普通溶剂且不易在空气中点燃和燃烧的树脂泡沫产品。将含有此类起始材料、表面活性剂和发泡剂的反应混合物加热至树脂发泡温度，即可制成树脂泡沫。
• Polyolefines reinforced with glass fibres and their use
  申请人：Montedison S.p.A.

  公开号：EP0008703A1

  公开（公告）日：1980-03-19

  Blends consisting of: (a) 50-90% by weight of a crystalline polyolefin, such as polyethylene or polypropylene, and (b) 50-10% by weight of glass fibers, characterized in that said blends contain from 0.5 to 5% by weight, with respect to the polyolefin, of a bis-maleamic acid coupling agent such as N.N'-hexamethylene- or N.N'- dodecamethylene- bis-maleamic acid. Glass fiber-reinforced polyolefins are also claimed.

  由以下物质组成的混合物：(a) 50-90%（按重量计）的结晶聚烯烃，如聚乙烯或聚丙烯，和(b) 50-10%（按重量计）的玻璃纤维，其特征在于，所述混合物含有 0.5-5%（按重量计）的双马来酰亚胺酸偶联剂，如 N.N'-六亚甲基-或 N.N'-十二亚甲基-双马来酰亚胺酸。 还要求获得玻璃纤维增强聚烯烃。
• Glass fibres for the reinforcement of polyolefins and reinforced polyolefin compositions obtained therefrom
  申请人：Montedison S.p.A.

  公开号：EP0036097A2

  公开（公告）日：1981-09-23

  Glass fibres for the production of reinforced polymers, characterized in that said fibres have a coating comprising, besides a film forming agent of polyolefinic kind and a silane, also a bis-maleamic acid such as N.N'-hexamethylene-bis-maleamic acid, N.N'-dodecamethylene-bis-maleamic acid or N.N'-isophoron-bis-maleamic acid. The invention also concerns blends consisting of 50-90% by weight of a crystalline polyolefin (e,g, polypropylene) and 50-10%by weight of glass fibres coated as indicated above.

  用于生产增强聚合物的玻璃纤维，其特征在于所述纤维有一层涂层，除了聚烯烃类成膜剂和硅烷外，还包括双马来酸，如 N.N'-六亚甲基双马来酸、N.N'-十二亚甲基双马来酸或 N.N'-异佛尔酮双马来酸。 本发明还涉及由 50-90%（按重量计）的结晶聚烯烃（如聚丙烯）和 50-10%（按重量计）的涂有上述涂层的玻璃纤维组成的混合物。
• Method and composition for diene rubber treatment
  申请人：MONSANTO COMPANY

  公开号：EP0080451A1

  公开（公告）日：1983-06-01

  Improved tack, green strength or non-black filler interaction capability are realized in a treated diene rubber. The method of treating diene rubberto achieve the improvements is shown, together with a composition in which maleamic acid or derivatives of maleamic acid are combined with sulfur or an organic sulfur compound capable of generating a thiyl radical.

  在经过处理的二烯烃橡胶中，粘性、生坯强度或非黑色填料相互作用能力都得到了改善。 图中展示了为实现上述改善而对二烯烃橡胶进行处理的方法，以及马来酰胺酸或马来酰胺酸衍生物与硫或能够生成硫基的有机硫化合物结合的组合物。
• Reinforced polyolefinic thermoplastic composition
  申请人：ENICHEM S.p.A.

  公开号：EP0614937A1

  公开（公告）日：1994-09-14

  Reinforced polyolefinic thermoplastic composition comprising a polyolefin, a carbonate of a metal appertaining to IIa Group of the Periodic System and a maleamic silane having general formula: wherein R and R₁ are hydrogen or an alkyl radical; R₂ is a alkoxy hydrolysable group or a halogen atom; R₃ is an alkyl radical having from 1 to 8 carbon atoms; X may be a radical of formula: or an aromatic, cycloaliphatic o heterocyclic divalent radical.

  增强聚烯烃热塑性塑料组合物，由聚烯烃、元素周期系 IIa 族金属的碳酸盐和具有通式的顺丁烯二酸硅烷组成： 其中 R 和 R₁ 是氢或烷基；R₂ 是可水解的烷氧基或卤素原子；R₃ 是具有 1 至 8 个碳原子的烷基；X 可以是式中的基： 或芳香族、环脂族或杂环族二价基。