1-propylimidazolium iodide | 133743-41-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-propylimidazolium iodide
• 英文别名: 1-Propylimidazole;hydroiodide
• CAS: 133743-41-6
• 化学式: C₆H₁₀N₂*HI
• 分子量: 238.071
• InChiKey: RNHUYBMAVXTLOP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.91
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  17.8
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  、 1-propylimidazolium iodide 以 水 为溶剂， 反应 8.0h， 以87%的产率得到[pmim]{[H(CF2)2O(CF2)2SO2]2N}
  参考文献：
  名称：

  双(氟烷磺)酰胺基离子液体的合成及理化性质

  摘要：

  由氟代烷磺酰胺与氟代烷基磺酰氟反应，以良好的收率合成了一系列双（氟代烷磺）酰胺。基于这些酰胺阴离子和咪唑鎓阳离子的离子液体显示出高密度和液态的宽温度范围。

  DOI：

  10.1002/ejic.201000171

文献信息

• Method for producing haloalkanes from alcohols
  申请人：Stegmann Viet

  公开号：US20070055084A1

  公开（公告）日：2007-03-08

  The invention relates to a process for preparing haloalkanes by reaction of alcohol with hydrogen halide, wherein the reaction of the alcohol with the hydrogen halide occurs in the presence of an ionic liquid at a temperature which is above 100° C. for at least part of the time and, at least at the time of the commencement of the reaction, the water content is not more than 25 mol % based on the amount of liquid, where the ionic liquid is not octyltrimethylammonium chloride.

  该发明涉及一种通过醇与氢卤化物反应制备卤代烷的方法，其中醇与氢卤化物的反应在存在离子液体的条件下进行，反应温度在100°C以上至少一部分时间，并且至少在反应开始时，水含量不超过液体总量的25摩尔％，其中所述离子液体不是辛基三甲基铵氯化物。
• COMPOUNDS FOR USE IN ELECTROLYTE FOR SOLAR CELL, METHOD FOR PREPARING THE SAME, AND ELECTROLYTE AND SOLAR CELL HAVING THE SAME
  申请人：Lee Yu-Hui

  公开号：US20130056075A1

  公开（公告）日：2013-03-07

  Provided is a compound of formula (I): wherein A is C 2-3 alkylene; m is an integer ranging from 2 to 25; and n is an integer ranging from 3 to 10. An electrolyte for a dye-sensitized solar cell having the compound of formula (I) and/or a compound of formula (II) is further provided for increasing photoelectric conversion efficiency.

  提供的是化合物的公式(I)：其中A是C2-3烷基; m是一个范围在2到25之间的整数; n是一个范围在3到10之间的整数。进一步提供了一种用于增加光电转换效率的染料敏化太阳能电池的电解质，其中包含公式(I)和/或公式(II)的化合物。
• PYRIDINE-TYPE METAL COMPLEX, PHOTOELECTRODE COMPRISING THE METAL COMPLEX, AND DYE-SENSITIZED SOLAR CELL COMPRISING THE PHOTOELECTRODE
  申请人：Sharp Kabushiki Kaisha

  公开号：EP2275494A1

  公开（公告）日：2011-01-19

  A pyridine type metal complex having a partial structure represented by the formula (I) or (I'): wherein, M is a transition metal atom; Ds, which may be the same or different, respectively represent specific conjugated chains; Rs, which may be the same or different, respectively represent a halogen atom, a hydrogen atom, or an alkyl group having 1 to 20 carbon atoms, an alkenyl or alkynyl group having 2 to 10 carbon atoms, an aryl or heteroaryl group having 6 to 10 carbon atoms or an arylalkyl or heteroarylalkyl group having 7 to 13 carbon atoms which may have a substituent group.

  一种具有由化学式（I）或（I'）表示的部分结构的吡啶型金属配合物，其中，M是过渡金属原子；Ds分别表示可能相同或不同的特定共轭链；Rs分别表示可能相同或不同的卤素原子、氢原子或具有1至20个碳原子的烷基基团、具有2至10个碳原子的烯基或炔基基团、具有6至10个碳原子的芳基或杂环芳基团或具有7至13个碳原子的芳基烷基或杂环芳基烷基基团，可能具有取代基。
• ORGANIC COMPOUND, SEMICONDUCTOR FILM ELECTRODE EMPLOYING THE ORGANIC COMPOUND, PHOTOELECTRIC CONVERSION ELEMENT EMPLOYING THE ORGANIC COMPOUND, AND PHOTOELECTROCHEMICAL SOLAR CELL EMPLOYING THE ORGANIC COMPOUND
  申请人：Koumura Nagatoshi

  公开号：US20100174095A1

  公开（公告）日：2010-07-08

  The present invention provides: an organic compound increasing an open circuit voltage, and showing high photoelectric conversion efficiency; a semiconductor film electrode employing the organic compound as a dye; a photoelectric conversion element employing the semiconductor film electrode; and a photoelectrochemical solar cell employing the photoelectric conversion element. The organic compound is represented by the following general formula: wherein A is a carbazole ring; L 1 is an electron transfer linking group having at least one heterocyclic ring selected from the group consisting of a thiophene ring, a furan ring, a pyrrole ring, and a condensed heterocyclic ring formed from any combinations of these rings; R is a substituent group bound to at least one electron transfer linking group selected from the group consisting of an alkyl group, an alkoxy group, and an aryl group; X is at least one electron withdrawing group selected from the group consisting of a cyano group, a carboxylic acid group, an ester group, an amide group, a trifluoromethyl group, a pentafluoroethyl group, a sulfonate group, and a trifluoromethanesulfonate group; M is a hydrogen atom or a salt-forming cation; and n is an integer of 1 to 12.

  本发明提供了一种有机化合物，可以增加开路电压并显示高光电转换效率；一种将该有机化合物作为染料的半导体薄膜电极；一种采用该半导体薄膜电极的光电转换元件；以及一种采用光电转换元件的光电化学太阳能电池。该有机化合物由下列通用式表示：其中A为咔唑环；L1为至少含有一种来自噻吩环、呋喃环、吡咯环和由这些环的任意组合形成的缩合杂环的杂环环的电子转移连接基团；R为与至少一种来自烷基、烷氧基和芳基的电子转移连接基团结合的取代基团；X为至少一种来自氰基、羧基、酯基、酰胺基、三氟甲基基团、五氟乙基基团、磺酸基团和三氟甲磺酸基团的电子提取基团；M为氢原子或形成盐的阳离子；n为1至12的整数。
• PYRIDINE TYPE METAL COMPLEX, PHOTOELECTRODE COMPRISING THE METAL COMPLEX, AND DYE-SENSITIZED SOLAR CELL COMPRISING THE PHOTOELECTRODE
  申请人：Shen Xiuliang

  公开号：US20110155238A1

  公开（公告）日：2011-06-30

  A pyridine type metal complex having a partial structure represented by the formula (I) or (I′): wherein, M is a transition metal atom; Ds, which may be the same or different, respectively represent specific conjugated chains; Rs, which may be the same or different, respectively represent a halogen atom, a hydrogen atom, or an alkyl group having 1 to 20 carbon atoms, an alkenyl or alkynyl group having 2 to 10 carbon atoms, an aryl or heteroaryl group having 6 to 10 carbon atoms or an arylalkyl or heteroarylalkyl group having 7 to 13 carbon atoms which may have a substituent group.

  具有由公式（I）或（I'）表示的部分结构的吡啶型金属配合物，其中，M是过渡金属原子；Ds分别表示特定的共轭链，可以相同也可以不同；Rs分别表示卤素原子、氢原子或具有1至20个碳原子的烷基、具有2至10个碳原子的烯基或炔基、具有6至10个碳原子的芳基或杂环芳基或具有7至13个碳原子的芳基烷基或杂环芳基烷基，可能具有取代基。