4-acryloyloxymethyl-2-cyclohexyl-1,3-dioxolane | 97773-09-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-acryloyloxymethyl-2-cyclohexyl-1,3-dioxolane
• 英文别名: (1,4-Dioxaspiro[4.5]decan-2-yl)methyl prop-2-enoate；1,4-dioxaspiro[4.5]decan-3-ylmethyl prop-2-enoate
• CAS: 97773-09-6
• 化学式: C₁₂H₁₈O₄
• 分子量: 226.273
• InChiKey: PBZQCLTYWHSQDF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,4-二氧杂螺(4.5)癸基-3-甲醇 、 丙烯酰氯 在 三乙胺 作用下， 以 氯仿 为溶剂， 以44 g的产率得到4-acryloyloxymethyl-2-cyclohexyl-1,3-dioxolane
  参考文献：
  名称：

  一种超低体积收缩的丙烯酸酯类单体和应用

  摘要：

  本发明涉及一种超低体积收缩的丙烯酸酯类单体，其特征在于，具有如下任意一类中的一种化学结构：其中，R1为氢或甲基；R2与R3分别独立的是甲基、苯基中的一种，或者R2与R3构成环烷基、含氧杂环、含氮杂环中的一种。以上结构化合物以甘油、三羟甲基丙烷、季戊四醇、DL‑木糖、DL‑阿拉伯糖醇为原料，通过与不同结构的环状酮如环戊酮、环己酮、四氢呋喃甲基酮、苯乙酮、N‑甲基‑4‑哌啶酮等，利用酮与羟基的酮叉反应，将多羟基中的部分羟基形成缩酮，剩余的羟基则通过酯化反应生成本发明一系列丙烯酸酯类单体。本发明获得的丙烯酸酯类单体在固化后具有较低体积收缩率。

  公开号：

  CN116640113A

文献信息

• INK COMPOSITION, INKJET RECORDING METHOD AND PROCESS FOR PRODUCING MOLDED PRINTED MATERIAL
  申请人：MOCHIZUKI Kyohei

  公开号：US20110242191A1

  公开（公告）日：2011-10-06

  An ink composition is provided that includes (Component a) an open-chain and/or cyclic ether bond-containing monofunctional (meth)acrylate, (Component b) one or more monofunctional ethylenically unsaturated compounds selected from the group consisting of a polycyclic aliphatic group-containing monofunctional (meth)acrylate and N-vinyl-2-caprolactam, (Component c) a polymerization initiator, (Component e) a polyfunctional (meth)acrylate at no greater than 10 wt % relative to the ink composition, and (Component f) a fluorine-substituted hydrocarbon group- or siloxane structure-containing polymer, the ratio by weight of (Component a)/(Component b) being 0.7 to 1.9. There are also provided an inkjet recording method that includes (a 1 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method and (b 1 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a cured image above the recording medium, and a process for producing a molded printed material that includes (a 2 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method, (b 2 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a printed material having a cured image above the recording medium, and (c 2 ) a molding step of molding the printed material.

  提供了一种墨水组合物，包括（组分a）一种开链和/或环状醚键含有单官能基（甲基）丙烯酸酯，（组分b）一种或多种单官能基乙烯基不饱和化合物，所述化合物选自包含多环脂肪族基的单官能基（甲基）丙烯酸酯和N-乙烯基-2-己内酰胺的群组，（组分c）一种聚合引发剂，（组分e）一种多官能基（甲基）丙烯酸酯，相对于墨水组合物不大于10重量％，以及（组分f）一种含有氟代烃基或硅氧烷结构的聚合物，其中（组分a）/（组分b）的重量比为0.7到1.9。还提供了一种喷墨记录方法，包括（a1）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤和（b1）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得固化图像，以及一种生产模塑印刷材料的过程，包括（a2）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤，（b2）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得具有固化图像的印刷材料，以及（c2）模塑印刷材料的模塑步骤。
• Ink composition, inkjet recording method and process for producing molded printed material
  申请人：Fujifilm Corporation

  公开号：EP2371910A1

  公开（公告）日：2011-10-05

  An ink composition is provided that includes (Component a) an open-chain and/or cyclic ether bond-containing monofunctional (meth)acrylate, (Component b) one or more monofunctional ethylenically unsaturated compounds selected from the group consisting of a polycyclic aliphatic group-containing monofunctional (meth)acrylate and N-vinyl-2-caprolactam, (Component c) a polymerization initiator, (Component e) a polyfunctional (meth)acrylate at no greater than 10 wt % relative to the ink composition, and (Component f) a fluorine-substituted hydrocarbon group- or siloxane structure-containing polymer, the ratio by weight of (Component a)/(Component b) being 0.7 to 1.9. There are also provided an inkjet recording method that includes (a1) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method and (b1) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a cured image above the recording medium, and a process for producing a molded printed material that includes (a2) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method, (b2) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a printed material having a cured image above the recording medium, and (c2) a molding step of molding the printed material.

  提供了一种油墨组合物，其中包括（组分 a）含开链和/或环醚键的单官能团（甲基）丙烯酸酯，（组分 b）一种或多种单官能团乙烯基不饱和化合物，这些化合物选自由含多环脂肪族单官能团（甲基）丙烯酸酯和 N-乙烯基-2-己内酰胺组成的组、(组分 c)聚合引发剂，(组分 e)多官能度(甲基)丙烯酸酯，相对于油墨组合物不大于 10 wt %，和(组分 f)含氟取代烃基或硅氧烷结构的聚合物，(组分 a)/(组分 b)的重量比为 0.7至1.9。还提供了一种喷墨记录方法，该方法包括：(a1) 图像形成步骤，即通过喷墨方法排放墨水组合物，在记录介质上方形成图像；(b1) 固化步骤，即通过用阳极辐射照射获得的图像，使墨水组合物固化，从而在记录介质上方获得固化图像、以及一种用于生产模制印刷材料的工艺，该工艺包括：(a2) 通过喷墨方法在记录介质上方排放墨水组合物以形成图像的图像形成步骤；(b2) 通过用阳极辐射照射获得的图像以固化墨水组合物从而获得在记录介质上方具有固化图像的印刷材料的固化步骤；(c2) 模制印刷材料的模制步骤。
• Radiation curable compositions for printing on glass
  申请人：AGFA GRAPHICS NV

  公开号：EP3034312A1

  公开（公告）日：2016-06-22

  A radiation curable composition containing a) a free radical polymerizable composition containing at least 95 wt% relative to the free radical polymerizable composition of one or more monofunctional (meth)acrylates, wherein at least 80 wt% of the one or more monofunctional (meth)acrylates consist of monofunctional (meth)acrylates including at least one five or six membered acetal ring in their structure; and b) at least one acetal containing polymer having a plurality of repeating units according to Formula (I): wherein R1 and R2 are independently selected from the group consisting of a hydrogen, an alkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an alkaryl group, an aryl group and a heteoraryl group.

  一种可辐射固化的组合物，其中含有 a) 可自由基聚合的组合物，相对于可自由基聚合的组合物，至少含有 95 wt%的一种或多种单官能团（甲基）丙烯酸酯，其中至少 80 wt%的一种或多种单官能团（甲基）丙烯酸酯由单官能团（甲基）丙烯酸酯组成，在其结构中至少包括一个五或六个成员的缩醛环；以及 b) 至少一种含缩醛的聚合物，其具有符合式（I）的多个重复单元： 其中 R1 和 R2 独立地选自氢、烷基、烯基、炔基、芳烷基、烷芳基、芳基和硬脂酰基组成的组。
• Radiation curable compositions
  申请人：AGFA NV

  公开号：US10752782B2

  公开（公告）日：2020-08-25

  A radiation curable composition including at least one organic silver salt, at least one reducing agent for the organic silver salt, and a polymerizable composition of at least one polymerizable compound, wherein the radiation curable composition is a radiation curable inkjet ink containing at least 50 wt % of a monofunctional polymerizable compound based on the total weight of the polymerizable composition. The radiation curable composition is especially useful for generating black UV light blocking borders in laminated safety glass for automotive applications.

  一种辐射固化组合物，包括至少一种有机银盐、至少一种有机银盐的还原剂和至少一种可聚合化合物的可聚合组合物，其中辐射固化组合物是一种辐射固化喷墨墨水，含有基于可聚合组合物总重量至少 50 wt % 的单官能团可聚合化合物。该辐射固化组合物尤其适用于在汽车用夹层安全玻璃中生成黑色紫外线阻挡边框。
• 5-METHYLENE-1,3-DIOXOLAN-4-ONE DERIVATIVES, PROCESS FOR THEIR PRODUCTION, POLYMERS OF THE DERIVATIVES, RESIST COMPOSITIONS, AND PATTERN FORMATION PROCESS
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP1447403B1

  公开（公告）日：2016-02-03