2-chloro-4-methyl-6-methoxyphenylacetic acid methyl ester | 866386-39-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-chloro-4-methyl-6-methoxyphenylacetic acid methyl ester
• 英文别名: Methyl 2-chloro-4-methyl-6-methoxyphenylacetate；methyl 2-(2-chloro-6-methoxy-4-methylphenyl)acetate
• CAS: 866386-39-2
• 化学式: C₁₁H₁₃ClO₃
• 分子量: 228.675
• InChiKey: YCBKYDLZNGGSPS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-chloro-4-methyl-6-methoxyphenylacetic acid methyl ester 在 甲醇 、 氢氧化钾 、 水 作用下， 反应 12.0h， 以90%的产率得到2-chloro-4-methyl-6-methoxyphenylacetic acid
  参考文献：
  名称：

  [DE] 2,4,6-PHENYLSUBSTITUIERTE CYCLISCHE KETOENOLE
  [EN] 2,4,6-PHENYLSUBSTITUTED CYCLIC KETOENOLES
  [FR] CETOENOLS CYCLIQUES 2,4,6-PHENYLSUBSTITUES

  摘要：

  公开号：

  WO2005092897A3
• 作为产物：
  描述：

  methyl 2-bromo-6-chloro-4-methylphenylacetate 、 乙酸甲酯 在 sodium methylate 、 copper(I) bromide 作用下， 反应 12.0h， 以91%的产率得到2-chloro-4-methyl-6-methoxyphenylacetic acid methyl ester
  参考文献：
  名称：

  [DE] 2,4,6-PHENYLSUBSTITUIERTE CYCLISCHE KETOENOLE
  [EN] 2,4,6-PHENYLSUBSTITUTED CYCLIC KETOENOLES
  [FR] CETOENOLS CYCLIQUES 2,4,6-PHENYLSUBSTITUES

  摘要：

  公开号：

  WO2005092897A3

文献信息

• 2,4,6-Phenyl-Substituted Cyclic Ketoenols
  申请人：Bretschneider Thomas

  公开号：US20070298968A1

  公开（公告）日：2007-12-27

  The invention relates to novel 2,4,6-phenyl-substituted cyclic ketoenols of the formula (I), in which CKE, W, X and Y are as defined above, to a plurality of processes and intermediates for their preparation and to their use as pesticides and/or herbicides, and also to selective herbicidal compositions comprising firstly the 2,4,6-phenyl-substituted cyclic ketoenols and secondly at least one compound which improves crop plant tolerance.

  该发明涉及公式（I）中新颖的2,4,6-苯基取代的环状酮烯醇，其中CKE，W，X和Y如上所定义，以及其制备的多种过程和中间体，以及它们作为杀虫剂和/或除草剂的用途，还涉及选择性除草剂组合物，包括第一种是2,4,6-苯基取代的环状酮烯醇，第二种是至少一种改善作物植物耐受性的化合物。
• 2,4,6-phenyl-substituted cyclic ketoenols
  申请人：Bayer CropScience AG

  公开号：US07947704B2

  公开（公告）日：2011-05-24

  The invention relates to novel 2,4,6-phenyl-substituted cyclic ketoenols of the formula (I), in which CKE, W, X and Y are as defined above, to a plurality of processes and intermediates for their preparation and to their use as pesticides and/or herbicides, and also to selective herbicidal compositions comprising firstly the 2,4,6-phenyl-substituted cyclic ketoenols and secondly at least one compound which improves crop plant tolerance.

  该发明涉及公式(I)的新型2,4,6-苯基取代的环状酮烯醇，其中CKE、W、X和Y如上所定义，以及用于它们的制备的多种过程和中间体，以及它们作为杀虫剂和/或除草剂的用途，还涉及选择性除草剂组合物，包括第一种2,4,6-苯基取代的环状酮烯醇和第二种至少一种提高作物植物耐受性的化合物。
• 2,4,6-PHENYLSUBSTITUIERTE CYCLISCHE KETOENOLE
  申请人：Bayer CropScience AG

  公开号：EP1732930B1

  公开（公告）日：2012-05-02
• 2,4,6-Phenyl-Substituted Derivatives
  申请人：BRETSCHNEIDER Thomas

  公开号：US20110213160A1

  公开（公告）日：2011-09-01

  The invention relates to novel 2,4,6-phenyl-substituted cyclic ketoenols of the formula (I), in which CKE, W, X and Y are as defined above, to a plurality of processes and intermediates for their preparation and to their use as pesticides and/or herbicides, and also to selective herbicidal compositions comprising firstly the 2,4,6-phenyl-substituted cyclic ketoenols and secondly at least one compound which improves crop plant tolerance.
• US7947704B2
  申请人：——

  公开号：US7947704B2

  公开（公告）日：2011-05-24