4,4'-bis(6-(acryloyloxy)-hexyloxy)biphenyl | 125337-31-7

• 物质功能分类: 化学试剂 - 有机试剂 - 酯类
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-bis(6-(acryloyloxy)-hexyloxy)biphenyl
• 英文别名: ([1,1'-Biphenyl]-4,4'-diylbis(oxy))bis(hexane-6,1-diyl) diacrylate；6-[4-[4-(6-prop-2-enoyloxyhexoxy)phenyl]phenoxy]hexyl prop-2-enoate
• CAS: 125337-31-7
• 化学式: C₃₀H₃₈O₆
• 分子量: 494.628
• InChiKey: KDDDBOTWRRILGO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  36
• 可旋转键数：
  21
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-(丙氨基)乙醇 、 4,4'-bis(6-(acryloyloxy)-hexyloxy)biphenyl 以 乙醇 为溶剂， 生成 6-[4-[4-(6-Prop-2-enoyloxyhexoxy)phenyl]phenoxy]hexyl 3-[2-hydroxyethyl(propyl)amino]propanoate
  参考文献：
  名称：

  Reactive mesogen and liquid crystal composition including the same

  摘要：

  提供了一种反应性介质，可改善液晶显示器的显示质量，以及包括该反应性介质的液晶组合物。该反应性介质由以下公式表示：其中，A1、A2和A3分别独立地表示取代或未取代的双价碳氢环或取代或未取代的双价杂环，L1和L2分别独立地表示直接连接、-O-、-S-、-CO-、-COO-、-OCOO-、-O(CH2)k1-、-S(CH2)k1-、-O(CF2)k1-、-S(CF2)k1-、-(CH2)k1-、-CF2CH2-、-(CF2)k1-、-CH═CH-、-CF═CF-、-C≡C-、-CH═CH-COO-或-(CH2)k1-COO-(CH2)k2-O-，Z1和Z2分别独立地表示直接连接、-O-、-S-、-CO-、-COO-、-OCOO-、-O(CH2)m1-、-S(CH2)m1-、-O(CF2)m1-、-S(CF2)m1-、-(CH2)m1-、-CF2CH2-、-(CF2)m1-、-CH═CH-、-CF═CF-、-C≡C-、-CH═CH-COO-、-(CH2)m1-COO-或-(CH2)m1-COO-(CH2)m2-O-，Pa是一种可聚合的基团，B是一个未取代的杂环、取代或未取代的冠醚基团，或其中T1和T2分别独立地表示-OH、-CH3、-CF3、-CHF2、-CH2F、-CH2Br、-CHBr2、-CHCl2或-CH2Cl。

  公开号：

  US10344213B2
• 作为产物：
  描述：

  4,4'-二羟基联苯 在 三乙胺 、 sodium hydroxide 作用下， 以 四氢呋喃 为溶剂， 生成 4,4'-bis(6-(acryloyloxy)-hexyloxy)biphenyl
  参考文献：
  名称：

  Reactive mesogen and liquid crystal composition including the same

  摘要：

  提供了一种反应性介质，可改善液晶显示器的显示质量，以及包括该反应性介质的液晶组合物。该反应性介质由以下公式表示：其中，A1、A2和A3分别独立地表示取代或未取代的双价碳氢环或取代或未取代的双价杂环，L1和L2分别独立地表示直接连接、-O-、-S-、-CO-、-COO-、-OCOO-、-O(CH2)k1-、-S(CH2)k1-、-O(CF2)k1-、-S(CF2)k1-、-(CH2)k1-、-CF2CH2-、-(CF2)k1-、-CH═CH-、-CF═CF-、-C≡C-、-CH═CH-COO-或-(CH2)k1-COO-(CH2)k2-O-，Z1和Z2分别独立地表示直接连接、-O-、-S-、-CO-、-COO-、-OCOO-、-O(CH2)m1-、-S(CH2)m1-、-O(CF2)m1-、-S(CF2)m1-、-(CH2)m1-、-CF2CH2-、-(CF2)m1-、-CH═CH-、-CF═CF-、-C≡C-、-CH═CH-COO-、-(CH2)m1-COO-或-(CH2)m1-COO-(CH2)m2-O-，Pa是一种可聚合的基团，B是一个未取代的杂环、取代或未取代的冠醚基团，或其中T1和T2分别独立地表示-OH、-CH3、-CF3、-CHF2、-CH2F、-CH2Br、-CHBr2、-CHCl2或-CH2Cl。

  公开号：

  US10344213B2

文献信息

• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, OPTICAL MATERIAL, OPTICAL ELEMENT AND OPTICAL HEAD DEVICE
  申请人：Arishima Hiroyuki

  公开号：US20110310721A1

  公开（公告）日：2011-12-22

  A polymerizable compound represented by the following formula (1): wherein A is a hydrogen atom or a group selected from the following formulae (2) to (5): V w H (3-W) C—  (2) Ph x Y (3-x) Si—  (3) J-(CH 2 ) m1 —CH l (CH 3 ) (2-l) —  (4) J-(CH 2 ) n1 —SiPh p1 (CH 3 ) (2-p1) —  (5); B is a group selected from the following formulae (6) and (7): J-(CH 2 ) m2 —CH k (CH 3 ) (2-k) —  (6) J-(CH 2 ) n2 —SiPh p2 (CH 3 ) (2-p2) —  (7); w is an integer of from 0 to 3; V is a methyl group or an ethyl group, provided that when w is from 2 to 3, a plurality of V's may be different groups, x is an integer of from 0 to 3, Y is a group selected from a methyl group, a cyclohexyl group, a tert-butyl group, a sec-butyl group and an isopropyl group, provided that when x is 0 or 1, a plurality of Y's may be different groups, J is a group selected from CH 2 ═CR—COO—, an epoxy group, a vinyl group and a vinyl ether group, R is a hydrogen atom or a methyl group, I is an integer of from 0 to 1, k is an integer of from 0 to 2, provided that when A is a hydrogen atom, k is not 2, each of m 1 and m 2 which are independent of each other, is from 0 to 12, each of n 1 and n 2 which are independent of each other, is from 1 to 12, and each of p 1 and p 2 which are independent of each other, is from 0 to 2; provided that some or all of hydrogen atoms in the substituent V in the formula (2), the phenyl group and the substituent Y in the formula (3) and the alkylene group in the formulae (4) to (7) may be substituted by a methyl group, a methoxy group or a fluorine atom, and some or all of hydrogen atoms in the biphenyl group or the biphenylene group may be substituted by a methyl group, a methoxy group or a fluorine atom.

  以下是由公式（1）表示的可聚合化合物：其中A是氢原子或从公式（2）至（5）选择的组：VwH(3-W)C—  (2)PhxY(3-x)Si—  (3)J-(CH2)m1—CHl(CH3)(2-l)—  (4)J-(CH2)n1—SiPhp1(CH3)(2-p1)—  (5);B是从公式（6）和（7）选择的组：J-(CH2)m2—CHk(CH3)(2-k)—  (6)J-(CH2)n2—SiPhp2(CH3)(2-p2)—  (7);w是0到3之间的整数；V是甲基或乙基组，前提是当w为2至3时，多个V可以是不同的组，x是0到3之间的整数，Y是甲基组、环己基组、叔丁基组、仲丁基组和异丙基组中选择的组，前提是当x为0或1时，多个Y可以是不同的组，J是CH2═CR—COO—、环氧基、乙烯基和乙烯基醚组中选择的组，R是氢原子或甲基组，I是0到1之间的整数，k是0到2之间的整数，前提是当A是氢原子时，k不是2，m1和m2都是独立的，从0到12，n1和n2都是独立的，从1到12，p1和p2都是独立的，从0到2；前提是一些或全部的V中的氢原子在公式（2）中，苯基和Y在公式（3）中的取代基和公式（4）至（7）中的亚烷基可以被甲基组、甲氧基或氟原子取代，并且一些或全部的双苯基或双亚苯基中的氢原子可以被甲基组、甲氧基或氟原子取代。
• Fabrication and characterization of imprinted photonic crystalline polymer matrices via multiple UV polymerizations
  作者：Chih-Chieh Chien、Jui-Hsiang Liu、A. V. Emelyanenko

  DOI：10.1039/c2jm35151j

  日期：——

  A photonic polymer network was imprinted using multiple UV-induced polymerizations in the presence of cholesteric liquid crystals (CLCs). Here, the imprinted polymer matrices provided a chiral environment due to the chirality of the polymer networks. The fabricated cell exhibited Bragg reflections even in the absence of anisotropic materials. Moreover, a phototunable liquid crystal cell was fabricated with photosensitive liquid crystalline ethyl 4-[4-(11-acryloyloxy undecyloxy) phenyl azobenzoyl-oxyl] benzoate. The tuning properties of the cells were examined as a function of the irradiation time and concentration of the photosensitive material. Both the tuning rate and dark relaxation of E–Z photoisomerization of the embedded LCs in the polymer network were also examined.

  在有胆甾液晶（CLC）存在的情况下，利用多次紫外线诱导聚合对光子聚合物网络进行了压印。在这里，由于聚合物网络的手性，压印聚合物基质提供了手性环境。即使在没有各向异性材料的情况下，制造出的电池也能产生布拉格反射。此外，还利用光敏液晶 4-[4-（11-丙烯酰氧基十一烷氧基）苯基偶氮苯甲酰基氧]苯甲酸乙酯制造出了光可调谐液晶电池。研究人员考察了电池的调谐特性与照射时间和光敏材料浓度的函数关系。此外，还研究了聚合物网络中嵌入的低聚物的 E-Z 光异构化的调谐速率和暗弛豫。
• Polymer-stabilized bistable dual-frequency cholesteric liquid crystal devices assisted by a predesigned chiral dopant
  作者：Chun-Yen Liu、Chi-Feng Yen、Yi-Hua Hung、Chia-Min Tu、Guan-Yi Wu、Hung-Yi Chen

  DOI：10.1039/d1tc04354d

  日期：——

  Fabricated polymer-stabilized bistable cholesteric liquid crystal devices show a stable opaque focal conic state and a stable transparent planar state without any energy consumption once they are turned.

  使用聚合物稳定的双稳态胆甾液晶器件，一旦开启，可以呈现稳定的不耗能的不透明焦锥态和稳定的透明平面态。
• POLYMERIZABLE LIQUID CRYSTAL COMPOSITION, POLARIZED LIGHT-EMITTING COATING MATERIAL, NOVEL NAPHTHOLACTAM DERIVATIVE NOVEL COUMARIN DERIVATIVE, NOVEL NILE RED DERIVATIVE, AND NOVEL ANTHRACENE DERIVATIVE
  申请人：Kubota Yusuke

  公开号：US20130334461A1

  公开（公告）日：2013-12-19

  Provided are a polymerizable liquid crystal composition, a coating material, a medium, and a polarizing device each produced using a polymerizable liquid crystal compound and a colorant and each capable of producing polarized light suitable for polarizing devices, and also a novel naphtholactam derivative, a novel coumarin derivative, a novel Nile Red derivative, and a novel anthracene derivative each suitable for use as the colorant. Specifically provided are a polymerizable liquid crystal composition containing (A) at least one liquid crystal compound having a polymerizable functional group, (B) at least one colorant, and (C) a polymerization initiator, and a novel naphtholactam derivative of formula (IV′), a novel coumarin derivative of formula (VI′), a novel Nile Red derivative of formula (VII′), and a novel anthracene derivative of formula (VIII′) each suitable for use as the colorant (B).

  提供了一种可聚合的液晶组合物、涂料材料、介质和极化装置，每种都使用了聚合液晶化合物和颜料，并且能够产生适合于极化装置的偏振光，还提供了一种新型萘内酰胺衍生物、一种新型香豆素衍生物、一种新型尼罗红衍生物和一种新型蒽衍生物，每种都适用于用作颜料。具体提供了一种聚合液晶组合物，包含（A）至少一种具有聚合功能基团的液晶化合物，（B）至少一种颜料，和（C）聚合引发剂，以及一种适用于用作颜料（B）的新型萘内酰胺衍生物（IV′）, 一种新型香豆素衍生物（VI′）, 一种新型尼罗红衍生物（VII′）和一种新型蒽衍生物（VIII′）。
• LIQUID CRYSTAL ALIGNMENT AGENT, LIQUID CRYSTAL ALIGNMENT FILM, AND LIQUID CRYSTAL DISPLAY ELEMENT
  申请人：Chi Mei Corporation

  公开号：US20160122651A1

  公开（公告）日：2016-05-05

  A liquid crystal alignment agent capable of forming a liquid crystal display element having good resistance to ultraviolet decay and no mura effect, a liquid crystal alignment film, and a liquid crystal display element having the same are provided. The liquid crystal alignment agent includes a polymer (A), a polysiloxane (B), a photopolymerizable compound (C), and a solvent (D). The polymer (A) is obtained by reacting a mixture. The mixture includes a tetracarboxylic dianhydride component (a1) and a diamine component (a2). The polysiloxane (B) contains a polymerizable unsaturated group, wherein the polymerizable unsaturated group includes a group represented by formula (1-1), a group represented by formula (1-2), or a combination of the two.

  提供一种液晶取向剂，能够形成具有良好抗紫外线衰减和无条纹效应的液晶显示元件，以及具有该液晶取向剂的液晶取向膜和液晶显示元件。该液晶取向剂包括聚合物（A）、聚硅氧烷（B）、光聚合性化合物（C）和溶剂（D）。聚合物（A）是通过反应混合物得到的，该混合物包括四羧酸二酐组分（a1）和二胺组分（a2）。聚硅氧烷（B）含有可聚合的不饱和基团，其中可聚合的不饱和基团包括由式（1-1）表示的基团、由式（1-2）表示的基团或两者的组合。