6,11-Dihexoxy-7,10-diiodo-3-methoxytriphenylen-2-ol | 1133161-36-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 6,11-Dihexoxy-7,10-diiodo-3-methoxytriphenylen-2-ol
• CAS: 1133161-36-0
• 化学式: C₃₁H₃₆I₂O₄
• 分子量: 726.433
• InChiKey: QJEGSXVRAXIQFU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.4
• 重原子数：
  37
• 可旋转键数：
  13
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  47.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-ethynyl-6,11-bis(hexyloxy)-3-methoxytriphenylene 、 6,11-Dihexoxy-7,10-diiodo-3-methoxytriphenylen-2-ol 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 三乙胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 21.0h， 以41%的产率得到7,10-Bis[2-(6,11-dihexoxy-3-methoxytriphenylen-2-yl)ethynyl]-6,11-dihexoxy-3-methoxytriphenylen-2-ol
  参考文献：
  名称：

  Synthesis and optical properties of triphenylene-based conjugated dendrons

  摘要：

  Conjugated dendrons based on triphenylene building blocks have been synthesized. Such dendrons exhibit broader absorption wavelength range and higher absorption coefficients than their phenyl analogs. They also possess extended excited state lifetimes and high fluorescence quantum yields in dilute Solutions. In the solid state, these dendrons are highly aggregated, resulting in significantly broadened and red-shifted emissions, whose decay transients depend strongly on the detection wavelength. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.12.017
• 作为产物：
  描述：

  2,7-Dihexoxy-3,6-diiodo-10-methoxy-11-propan-2-yloxytriphenylene 在 9-溴-9-硼杂双环-[3.3.1]壬烷 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以72%的产率得到6,11-Dihexoxy-7,10-diiodo-3-methoxytriphenylen-2-ol
  参考文献：
  名称：

  Synthesis and optical properties of triphenylene-based conjugated dendrons

  摘要：

  Conjugated dendrons based on triphenylene building blocks have been synthesized. Such dendrons exhibit broader absorption wavelength range and higher absorption coefficients than their phenyl analogs. They also possess extended excited state lifetimes and high fluorescence quantum yields in dilute Solutions. In the solid state, these dendrons are highly aggregated, resulting in significantly broadened and red-shifted emissions, whose decay transients depend strongly on the detection wavelength. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.12.017