(E)-10-十八碳烯酸甲酯 | 13038-45-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: (E)-10-十八碳烯酸甲酯
• 英文名称: methyl (E)-octadec-10-enoate
• CAS: 13038-45-4
• 化学式: C₁₉H₃₆O₂
• 分子量: 296.5
• InChiKey: HHZIOLLKZWLCOX-MDZDMXLPSA-N

物化性质

• 沸点：
  368.6±11.0 °C(Predicted)
• 密度：
  0.873±0.06 g/cm3(Predicted)
• 溶解度：
  可溶于氯仿（少许）、甲醇（少许）
• 保留指数：
  2100;2110;348.32

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  21
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.84
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2916190090

反应信息

• 作为反应物：
  描述：

  (E)-10-十八碳烯酸甲酯 、 重水 以55%的产率得到
  参考文献：
  名称：

  ANDERSSON, B. A.;DINGER, F.;DINH-NGUYEN, NGUYEN, CHEM. SCR., 1981, 18, N 5, 197-201

  摘要：

  DOI：

文献信息

• Catalytic osmium-assisted oxidative cleavage of olefins
  申请人：Board of Trustees of MICHIGAN STATE UNIVERSITY

  公开号：US20030149299A1

  公开（公告）日：2003-08-07

  An osmium-assisted process for the oxidative cleavage of oxidizable organic compounds such as unsaturated organic compounds, including alkenes and olefins into aldehydes, carboxylic acids, esters, or ketones. The process uses a metal catalyst comprising osmium and a peroxy compound selected from the group consisting of peroxymonosulfuric acid and salts thereof to oxidatively cleave the oxidizable organic compound. In particular, the process enables aldehydes, carboxylic acids, esters, or ketones to be selectively produced from the corresponding mono-, 1,1-di-, 1,2-di-, tri-, or tetra-substituted olefins in a reaction that produces the result of ozonolysis but with fewer problems. The present invention further provides a process for oxidizing an aldehyde alone or with the osmium in an interactive solvent to produce an ester or carboxylic acid.

  一种以铼辅助的过程，用于氧化裂解可氧化的有机化合物，如不饱和有机化合物，包括烯烃和烯烃，生成醛、羧酸、酯或酮。该过程使用包含铼和过氧化物化合物的金属催化剂，所述过氧化物化合物选自过硫酸单酯和其盐组成的组中，以氧化裂解可氧化的有机化合物。具体而言，该过程使得能够从相应的单取代、1,1-二取代、1,2-二取代、三取代或四取代烯烃中选择性地产生醛、羧酸、酯或酮，在产生臭氧裂解结果但问题较少的反应中。本发明还提供了一种氧化醛的过程，单独或与铼在交互溶剂中产生酯或羧酸。
• SYSTEMS AND METHODS FOR PRODUCING FUELS FROM BIOMASS
  申请人：McNeff Clayton V.

  公开号：US20100170147A1

  公开（公告）日：2010-07-08

  The present invention relates to systems and methods for producing fuels. In an embodiment, the invention includes a method of producing a diesel-equivalent fuel, including pyrolyzing biomass to form a pyrolysis oil and contacting the pyrolysis oil and an alcohol with a metal oxide catalyst at a temperature of greater than about 60 degrees Celsius. In an embodiment, the invention includes a method of refining pyrolysis oil including contacting pyrolysis oil and an alcohol with a metal oxide catalyst at a temperature of greater than about 60 degrees Celsius. In an embodiment, the invention includes a system for processing biomass into fuel including a pyrolysis chamber defining an interior volume; a first heating element configured to heat the pyrolysis chamber; a refining chamber in selective fluid communication with the pyrolysis chamber, the refining chamber defining an interior volume, a metal oxide catalyst disposed within the interior volume; and a second heating element configured to heat the refining chamber. Other embodiments are also described herein.
• US6787671B2
  申请人：——

  公开号：US6787671B2

  公开（公告）日：2004-09-07
• US9102877B2
  申请人：——

  公开号：US9102877B2

  公开（公告）日：2015-08-11
• [EN] CATALYTIC OSMIUM-ASSISTED OXIDATIVE CLEAVAGE OF OLEFINS<br/>[FR] CLIVAGE OXYDATIF CATALYTIQUE D'OLEFINES ASSISTE PAR OSMIUM
  申请人：UNIV MICHIGAN STATE

  公开号：WO2003060852A2

  公开（公告）日：2003-07-24

  An osmium-assisted process for the oxidative cleavage of oxidizable organic compounds such as unsaturated organic coumpounds, including alkenes and olefins into aldehydes, carboxylic acids, esters, or ketones. The process uses a metal catalyst comprising osmium and a peroxy compound selected from the group consisting of peroxymonosulfuric acid and salts thereof to oxidatively cleave the oxidizable organic compound. In particular, the process enables aldehydes, carboxylic acids, esters, or ketones to be selectively produced from the corresponding mono-, 1,1-di-, 1,2-di-, tri-, or tetra-substituted olefins in a reaction that produces the result of ozonolysis but with fewer problems. The present invention further provides a process for oxidizing an aldehyde alone or with the osmium in an interactive solvent to produce an ester or carboxylic acid.